Layered Oxide Cathodes Promoted by Structure Modulation Technology for Sodium‐Ion Batteries

Considering the ever‐growing climatic degeneration, sustainable and renewable energy sources are needed to be effectively integrated into the grid through large‐scale electrochemical energy storage and conversion (EESC) technologies. With regard to their competent benefit in cost and sustainable sup...

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Vydané v:Advanced functional materials Ročník 30; číslo 30
Hlavní autori: Xiao, Yao, Abbasi, Nasir Mahmood, Zhu, Yan‐Fang, Li, Shi, Tan, Shuang‐Jie, Ling, Wei, Peng, Ling, Yang, Tingqiang, Wang, Lude, Guo, Xiao‐Dong, Yin, Ya‐Xia, Zhang, Han, Guo, Yu‐Guo
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Hoboken Wiley Subscription Services, Inc 01.07.2020
Predmet:
Cathodes
Commercialization
Degeneration
electrochemistry
Electrode materials
Energy storage
Ion currents
Kinetics
layered oxides
Lithium
Materials science
Modulation
Phase transitions
Rechargeable batteries
Renewable energy sources
Sodium-ion batteries
structure modulation
Transition metal oxides
ISSN:1616-301X, 1616-3028
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Abstract Considering the ever‐growing climatic degeneration, sustainable and renewable energy sources are needed to be effectively integrated into the grid through large‐scale electrochemical energy storage and conversion (EESC) technologies. With regard to their competent benefit in cost and sustainable supply of resource, room‐temperature sodium‐ion batteries (SIBs) have shown great promise in EESC, triumphing over other battery systems on the market. As one of the most fascinating cathode materials due to the simple synthesis process, large specific capacity, and high ionic conductivity, Na‐based layered transition metal oxide cathodes commonly suffer from the sluggish kinetics, multiphase evolution, poor air stability, and insufficient comprehensive performance, restricting their commercialization application. Here, this review summarizes the recent advances in layered oxide cathode materials for SIBs through different optimal structure modulation technologies, with an emphasis placed on strategies to boost Na+ kinetics and reduce the irreversible phase transition as well as enhance the store stability. Meanwhile, a thorough and in‐depth systematical investigation of the structure–function–property relationship is also discussed, and the challenges as well as opportunities for practical application electrode materials are sketched. The insights brought forward in this review can be considered as a guide for SIBs in next‐generation EESC. The recent research progress of structure modulation technology on layered transition metal oxide cathodes for sodium‐ion batteries is summarized, concentrating especially on morphology design, coating technology, phase transition, ordering‐disordering, air stability, and composite structure to boost Na+ kinetics, suppress the irreversible phase transition, enhance the storage stability, improve the overall performance, and further realize sodium‐ion battery commercialization for market applications.
AbstractList Considering the ever‐growing climatic degeneration, sustainable and renewable energy sources are needed to be effectively integrated into the grid through large‐scale electrochemical energy storage and conversion (EESC) technologies. With regard to their competent benefit in cost and sustainable supply of resource, room‐temperature sodium‐ion batteries (SIBs) have shown great promise in EESC, triumphing over other battery systems on the market. As one of the most fascinating cathode materials due to the simple synthesis process, large specific capacity, and high ionic conductivity, Na‐based layered transition metal oxide cathodes commonly suffer from the sluggish kinetics, multiphase evolution, poor air stability, and insufficient comprehensive performance, restricting their commercialization application. Here, this review summarizes the recent advances in layered oxide cathode materials for SIBs through different optimal structure modulation technologies, with an emphasis placed on strategies to boost Na+ kinetics and reduce the irreversible phase transition as well as enhance the store stability. Meanwhile, a thorough and in‐depth systematical investigation of the structure–function–property relationship is also discussed, and the challenges as well as opportunities for practical application electrode materials are sketched. The insights brought forward in this review can be considered as a guide for SIBs in next‐generation EESC. The recent research progress of structure modulation technology on layered transition metal oxide cathodes for sodium‐ion batteries is summarized, concentrating especially on morphology design, coating technology, phase transition, ordering‐disordering, air stability, and composite structure to boost Na+ kinetics, suppress the irreversible phase transition, enhance the storage stability, improve the overall performance, and further realize sodium‐ion battery commercialization for market applications.
Considering the ever‐growing climatic degeneration, sustainable and renewable energy sources are needed to be effectively integrated into the grid through large‐scale electrochemical energy storage and conversion (EESC) technologies. With regard to their competent benefit in cost and sustainable supply of resource, room‐temperature sodium‐ion batteries (SIBs) have shown great promise in EESC, triumphing over other battery systems on the market. As one of the most fascinating cathode materials due to the simple synthesis process, large specific capacity, and high ionic conductivity, Na‐based layered transition metal oxide cathodes commonly suffer from the sluggish kinetics, multiphase evolution, poor air stability, and insufficient comprehensive performance, restricting their commercialization application. Here, this review summarizes the recent advances in layered oxide cathode materials for SIBs through different optimal structure modulation technologies, with an emphasis placed on strategies to boost Na+ kinetics and reduce the irreversible phase transition as well as enhance the store stability. Meanwhile, a thorough and in‐depth systematical investigation of the structure–function–property relationship is also discussed, and the challenges as well as opportunities for practical application electrode materials are sketched. The insights brought forward in this review can be considered as a guide for SIBs in next‐generation EESC.
Author Li, Shi
Yang, Tingqiang
Zhu, Yan‐Fang
Wang, Lude
Guo, Xiao‐Dong
Zhang, Han
Ling, Wei
Peng, Ling
Guo, Yu‐Guo
Tan, Shuang‐Jie
Abbasi, Nasir Mahmood
Yin, Ya‐Xia
Xiao, Yao
Author_xml – sequence: 1
  givenname: Yao
  surname: Xiao
  fullname: Xiao, Yao
  organization: Nanyang Technological University
– sequence: 2
  givenname: Nasir Mahmood
  surname: Abbasi
  fullname: Abbasi, Nasir Mahmood
  organization: Shenzhen University
– sequence: 3
  givenname: Yan‐Fang
  surname: Zhu
  fullname: Zhu, Yan‐Fang
  organization: Sichuan University
– sequence: 4
  givenname: Shi
  surname: Li
  fullname: Li, Shi
  organization: Sichuan University
– sequence: 5
  givenname: Shuang‐Jie
  surname: Tan
  fullname: Tan, Shuang‐Jie
  organization: Chinese Academy of Sciences (CAS)
– sequence: 6
  givenname: Wei
  surname: Ling
  fullname: Ling, Wei
  organization: Chinese Academy of Sciences (CAS)
– sequence: 7
  givenname: Ling
  surname: Peng
  fullname: Peng, Ling
  organization: Shenzhen University
– sequence: 8
  givenname: Tingqiang
  surname: Yang
  fullname: Yang, Tingqiang
  organization: Shenzhen University
– sequence: 9
  givenname: Lude
  surname: Wang
  fullname: Wang, Lude
  organization: Shenzhen University
– sequence: 10
  givenname: Xiao‐Dong
  orcidid: 0000-0003-0322-8476
  surname: Guo
  fullname: Guo, Xiao‐Dong
  organization: Sichuan University
– sequence: 11
  givenname: Ya‐Xia
  surname: Yin
  fullname: Yin, Ya‐Xia
  organization: Chinese Academy of Sciences (CAS)
– sequence: 12
  givenname: Han
  surname: Zhang
  fullname: Zhang, Han
  email: hzhang@szu.edu.cn
  organization: Shenzhen University
– sequence: 13
  givenname: Yu‐Guo
  surname: Guo
  fullname: Guo, Yu‐Guo
  email: ygguo@iccas.ac.cn
  organization: Chinese Academy of Sciences (CAS)
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– ident: e_1_2_6_152_1
  doi: 10.1002/smtd.201900239
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Snippet Considering the ever‐growing climatic degeneration, sustainable and renewable energy sources are needed to be effectively integrated into the grid through...
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SubjectTerms Cathodes
Commercialization
Degeneration
electrochemistry
Electrode materials
Energy storage
Ion currents
Kinetics
layered oxides
Lithium
Materials science
Modulation
Phase transitions
Rechargeable batteries
Renewable energy sources
Sodium-ion batteries
structure modulation
Transition metal oxides
Title Layered Oxide Cathodes Promoted by Structure Modulation Technology for Sodium‐Ion Batteries
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https://www.proquest.com/docview/2426170095
Volume 30
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