Revealed pathways of furan ring opening and surface crosslinking in biobased polyfurfuryl alcohol
Aldehydes are conjugated while ketones are non-conjugated. Oxidative ring opening explain the stiffer surface of PFA materials. [Display omitted] •Ring opening in Polyfurfuryl alcohol occurs preferentially on furan-end groups.•2D-NMR investigations allow to highlight the presence of aldehyde functio...
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| Veröffentlicht in: | European polymer journal Jg. 187; S. 111869 |
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| Format: | Journal Article |
| Sprache: | Englisch |
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Elsevier Ltd
03.04.2023
Elsevier |
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| ISSN: | 0014-3057, 1873-1945 |
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| Abstract | Aldehydes are conjugated while ketones are non-conjugated.
Oxidative ring opening explain the stiffer surface of PFA materials.
[Display omitted]
•Ring opening in Polyfurfuryl alcohol occurs preferentially on furan-end groups.•2D-NMR investigations allow to highlight the presence of aldehyde functions in PFA.•Oxidative and hydrolytic ring opening pathways are proposed.•The formed conjugated aldehydes are good dienophile prone for Diels-Alder ccycloaddition.
Poly(furfuryl alcohol) – (PFA) is a biobased thermoset known for its highly crosslinked structure. Bidimensional NMR (2D-NMR) was employed to give new insights on the complex structural organization in PFA with a special emphasis on the side structures resulting from furan ring-opening. Interestingly, the presence of aldehyde functions was for the first time clearly highlighted and quantified in PFA resins. Overall, the aldehydes account for about 20 % of the total carbonyls present in PFA. Results from HSQC and HMBC sequences allowed proposing two pathways for the furan ring opening reactions. The first one is an hydrolytic-ring opening leading to levulinic like species. The second one is rather an oxidative furan-ring opening leading to conjugated aldehydes. These conjugated aldehydes are prone to crosslink via Diel-Alder cycloadditions with furanic entities thus leading to crosslinking. At macroscopic scale, this newly proposed crosslinking pathway would explain the formation of the rigid shell formed at the external surfaces of PFA resins. |
|---|---|
| AbstractList | Aldehydes are conjugated while ketones are non-conjugated.
Oxidative ring opening explain the stiffer surface of PFA materials.
[Display omitted]
•Ring opening in Polyfurfuryl alcohol occurs preferentially on furan-end groups.•2D-NMR investigations allow to highlight the presence of aldehyde functions in PFA.•Oxidative and hydrolytic ring opening pathways are proposed.•The formed conjugated aldehydes are good dienophile prone for Diels-Alder ccycloaddition.
Poly(furfuryl alcohol) – (PFA) is a biobased thermoset known for its highly crosslinked structure. Bidimensional NMR (2D-NMR) was employed to give new insights on the complex structural organization in PFA with a special emphasis on the side structures resulting from furan ring-opening. Interestingly, the presence of aldehyde functions was for the first time clearly highlighted and quantified in PFA resins. Overall, the aldehydes account for about 20 % of the total carbonyls present in PFA. Results from HSQC and HMBC sequences allowed proposing two pathways for the furan ring opening reactions. The first one is an hydrolytic-ring opening leading to levulinic like species. The second one is rather an oxidative furan-ring opening leading to conjugated aldehydes. These conjugated aldehydes are prone to crosslink via Diel-Alder cycloadditions with furanic entities thus leading to crosslinking. At macroscopic scale, this newly proposed crosslinking pathway would explain the formation of the rigid shell formed at the external surfaces of PFA resins. |
| ArticleNumber | 111869 |
| Author | Delliere, Pierre Guigo, Nathanael |
| Author_xml | – sequence: 1 givenname: Pierre surname: Delliere fullname: Delliere, Pierre – sequence: 2 givenname: Nathanael surname: Guigo fullname: Guigo, Nathanael email: nathanael.guigo@univ-cotedazur.fr |
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| Cites_doi | 10.1039/c2gc16397g 10.1515/HF.2008.110 10.1039/D1RA05305A 10.1016/j.cej.2019.05.029 10.1002/app.1963.070070104 10.1016/j.vibspec.2008.04.013 10.1016/S0014-3057(01)00090-8 10.1016/j.tetlet.2006.07.071 10.1002/macp.1982.021831115 10.1021/ma00232a058 10.1038/s41467-021-22157-5 10.1016/j.eurpolymj.2016.03.037 10.1039/C6RA04745A 10.1002/app.1968.070120716 10.3390/molecules27103212 10.1002/macp.1992.021930101 10.1016/B978-0-12-821632-3.00006-3 10.1016/j.apcatb.2015.06.003 10.1002/(SICI)1097-0126(199908)48:8<637::AID-PI206>3.0.CO;2-C 10.1039/C6RA22611F 10.1016/j.tetlet.2011.09.076 10.1039/C5EE02666K 10.1021/acs.macromol.1c02098 10.3390/polym14050943 10.1021/ma00135a019 10.1002/app.1971.070150504 10.3390/polym11122126 10.1038/nprot.2012.064 10.1002/cssc.201501259 10.1021/cr050989d 10.1039/c4cc01196a 10.3390/ma15010350 10.1002/cctc.201100098 10.1021/jp073958q 10.1021/ie50391a010 10.1039/C0CC04164E 10.1021/ma951522f 10.1002/cssc.201900601 10.1021/jf034372d 10.1021/acssuschemeng.1c07807 10.1002/cssc.201800620 10.1016/j.theochem.2006.05.027 10.1039/D1GC01524A 10.1016/j.biombioe.2014.02.020 10.1105/tpc.113.113142 10.1021/acsmacrolett.2c00427 10.1021/acs.orglett.6b03237 |
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| Keywords | Surface crosslinking Oxidation Poly(furfuryl alcohol) 2D-NMR Biobased thermoset Ring-opening |
| Language | English |
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| References | Buchwalter (b0095) 1985; 1 Fernández-Costas, Gouveia, Sanromán, Moldes (b0170) 2014; 63 Merino (b0240) 2015; 87 Palframan, Pattenden (b0225) 2014; 50 Barr, Wallon (b0055) 1971; 15 Quinquet, Delliere, Guigo (b0150) 2022; 27 Simeonov, Ravutsov, Mihovilovic (b0250) 2019; 12 Tobimatsu, Chen, Nakashima, Escamilla-Treviño, Jackson, Dixon, Ralph (b0175) 2013; 25 Szczurek, Fierro, Thébault, Pizzi, Celzard (b0105) 2016; 78 Hu, Jiang, Kadarwati, Dong, Li (b0220) 2016; 6 Fawcett, Dadamba (b0065) 1982; 183 X. Liu, B. Li, G. Han, X. Liu, Z. Cao, D. en Jiang, Y. Sun, Electrocatalytic synthesis of heterocycles from biomass-derived furfuryl alcohols, Nat. Commun. 12 (2021) 1–12. https://doi.org/10.1038/s41467-021-22157-5. Barsberg, Thygesen (b0120) 2009; 49 Chuang, Maciel, Myers (b0080) 1984; 17 Nordstierna, Lande, Westin, Karlsson, Furó (b0180) 2008; 62 Gonzales, Martinez, Ortiz (b0070) 1992; 193 Principe, Ortiz, Martínez (b0060) 1999; 48 Blank, Stephens (b0235) 2006; 47 Wewerka (b0045) 1971; 9 Delliere, Guigo (b0155) 2022; 11 Black, Ferrell (b0195) 2016; 30 . Choura, Belgacem, Gandini (b0100) 1996; 29 Gelmini, Albonetti, Cavani, Cesari, Lolli, Zanotti, Mazzoni (b0245) 2016; 180 Balakshin, Capanema, Chen, Gracz (b0165) 2003; 51 Yang, Tao, Peng, Zhang, He, Liu (b0010) 2022; 10 Dunlop, Peters (b0040) 1942; 34 R. M. Silverstein, F. X. Webster, D. J. Kiemle, D. L. Bryce, Spectrometric identification of organic compounds 8 Montero, Montero, Martínez, Spange (b0115) 2006; 770 Delliere, Guigo (b0145) 2022; 55 Kim, Assary, Marshall, Gosztola, Curtiss, Stair (b0110) 2011; 3 Maciel, Chuang, Myers (b0075) 1982; 15 edition, John Wiley & Sons, Inc. 2014. Mansfield, Kim, Lu, Ralph (b0160) 2012; 7 González, Figueroa, González (b0125) 2002; 38 Mariscal, Maireles-Torres, Ojeda, Sádaba, López Granados (b0020) 2016; 9 Noutsias, Alexopoulou, Montagnon, Vassilikogiannakis (b0260) 2012; 14 Wewerka (b0050) 1968; 12 Falco, Guigo, Vincent, Sbirrazzuoli (b0130) 2018; 11 X. Zhu, B. Bruijnaers, T. V. Lourençon, M. Balakshin, Structural Analysis of Lignin-Based Furan Resin, Materials (Basel). 15(1) (2022). 350 Clayden, Greeves, Warren (b0215) 1970 Pin, Guigo, Vincent, Sbirrazzuoli, Mija (b0190) 2015; 8 Bertarione, Bonino, Cesano, Damin, Scarano, Zecchina (b0090) 2008; 112 Kikaš, Horváth, Škoric (b0275) 2011; 52 Corma Canos, Iborra, Velty (b0005) 2007; 107 A. Gandini, M.N. Belgacem, Handbook of thermoset plastics, Elsevier, 2022. Ghosh, Brindisi (b0210) 2016; 6 de Jong, Visser, de Sousa Dias, Harvey, Gruter (b0015) 2022; 14 Tondi, Cefarin, Sepperer, D’Amico, Berger, Musso, Birarda, Reyer, Schnabel, Vaccari (b0140) 2019; 11 Soininen (b0200) 2008 Wang, Zhang, Zheng, Seong (b0270) 2021; 11 Martin, Jelavić, Cragg, Thygesen (b0030) 2021; 23 Pophali, Lee, Zhang, Chuang, Ehm, Cuiffo, Halada, Rafailovich, Verma, Kim (b0035) 2019; 373 El Kaïm, Grimaud, Wagschal (b0230) 2011; 47 Conley, Metil (b0085) 1963; 7 D’Amico, Musso, Berger, Cefarin, Birarda, Tondi, Bertoldo Menezes, Reyer, Scarabattoli, Sepperer, Schnabel, Vaccari (b0135) 2021; 262 Plutschack, Seeberger, Gilmore (b0265) 2017; 19 Gonzales (10.1016/j.eurpolymj.2023.111869_b0070) 1992; 193 El Kaïm (10.1016/j.eurpolymj.2023.111869_b0230) 2011; 47 Mansfield (10.1016/j.eurpolymj.2023.111869_b0160) 2012; 7 Noutsias (10.1016/j.eurpolymj.2023.111869_b0260) 2012; 14 Dunlop (10.1016/j.eurpolymj.2023.111869_b0040) 1942; 34 Quinquet (10.1016/j.eurpolymj.2023.111869_b0150) 2022; 27 Balakshin (10.1016/j.eurpolymj.2023.111869_b0165) 2003; 51 Soininen (10.1016/j.eurpolymj.2023.111869_b0200) 2008 Ghosh (10.1016/j.eurpolymj.2023.111869_b0210) 2016; 6 Buchwalter (10.1016/j.eurpolymj.2023.111869_b0095) 1985; 1 de Jong (10.1016/j.eurpolymj.2023.111869_b0015) 2022; 14 Delliere (10.1016/j.eurpolymj.2023.111869_b0155) 2022; 11 Plutschack (10.1016/j.eurpolymj.2023.111869_b0265) 2017; 19 10.1016/j.eurpolymj.2023.111869_b0025 Pin (10.1016/j.eurpolymj.2023.111869_b0190) 2015; 8 Clayden (10.1016/j.eurpolymj.2023.111869_b0215) 1970 Principe (10.1016/j.eurpolymj.2023.111869_b0060) 1999; 48 Szczurek (10.1016/j.eurpolymj.2023.111869_b0105) 2016; 78 10.1016/j.eurpolymj.2023.111869_b0185 Kim (10.1016/j.eurpolymj.2023.111869_b0110) 2011; 3 González (10.1016/j.eurpolymj.2023.111869_b0125) 2002; 38 Martin (10.1016/j.eurpolymj.2023.111869_b0030) 2021; 23 Gelmini (10.1016/j.eurpolymj.2023.111869_b0245) 2016; 180 Delliere (10.1016/j.eurpolymj.2023.111869_b0145) 2022; 55 Barsberg (10.1016/j.eurpolymj.2023.111869_b0120) 2009; 49 Pophali (10.1016/j.eurpolymj.2023.111869_b0035) 2019; 373 Conley (10.1016/j.eurpolymj.2023.111869_b0085) 1963; 7 Merino (10.1016/j.eurpolymj.2023.111869_b0240) 2015; 87 Wewerka (10.1016/j.eurpolymj.2023.111869_b0050) 1968; 12 Tobimatsu (10.1016/j.eurpolymj.2023.111869_b0175) 2013; 25 Maciel (10.1016/j.eurpolymj.2023.111869_b0075) 1982; 15 Barr (10.1016/j.eurpolymj.2023.111869_b0055) 1971; 15 Falco (10.1016/j.eurpolymj.2023.111869_b0130) 2018; 11 D’Amico (10.1016/j.eurpolymj.2023.111869_b0135) 2021; 262 Black (10.1016/j.eurpolymj.2023.111869_b0195) 2016; 30 Mariscal (10.1016/j.eurpolymj.2023.111869_b0020) 2016; 9 Chuang (10.1016/j.eurpolymj.2023.111869_b0080) 1984; 17 Bertarione (10.1016/j.eurpolymj.2023.111869_b0090) 2008; 112 Choura (10.1016/j.eurpolymj.2023.111869_b0100) 1996; 29 Montero (10.1016/j.eurpolymj.2023.111869_b0115) 2006; 770 Wewerka (10.1016/j.eurpolymj.2023.111869_b0045) 1971; 9 Hu (10.1016/j.eurpolymj.2023.111869_b0220) 2016; 6 Simeonov (10.1016/j.eurpolymj.2023.111869_b0250) 2019; 12 Kikaš (10.1016/j.eurpolymj.2023.111869_b0275) 2011; 52 Palframan (10.1016/j.eurpolymj.2023.111869_b0225) 2014; 50 Wang (10.1016/j.eurpolymj.2023.111869_b0270) 2021; 11 Nordstierna (10.1016/j.eurpolymj.2023.111869_b0180) 2008; 62 Tondi (10.1016/j.eurpolymj.2023.111869_b0140) 2019; 11 10.1016/j.eurpolymj.2023.111869_b0205 10.1016/j.eurpolymj.2023.111869_b0255 Corma Canos (10.1016/j.eurpolymj.2023.111869_b0005) 2007; 107 Fernández-Costas (10.1016/j.eurpolymj.2023.111869_b0170) 2014; 63 Blank (10.1016/j.eurpolymj.2023.111869_b0235) 2006; 47 Yang (10.1016/j.eurpolymj.2023.111869_b0010) 2022; 10 Fawcett (10.1016/j.eurpolymj.2023.111869_b0065) 1982; 183 |
| References_xml | – volume: 49 start-page: 52 year: 2009 end-page: 63 ident: b0120 article-title: Poly(furfuryl alcohol) formation in neat furfuryl alcohol and in cymene studied by ATR-IR spectroscopy and density functional theory (B3LYP) prediction of vibrational bands publication-title: Vib. Spectrosc. – volume: 50 start-page: 7223 year: 2014 end-page: 7242 ident: b0225 article-title: The versatility of furfuryl alcohols and furanoxonium ions in synthesis publication-title: Chem. Commun. – volume: 29 start-page: 3839 year: 1996 end-page: 3850 ident: b0100 article-title: Acid-catalyzed polycondensation of furfuryl alcohol: Mechanisms of chromophore formation and cross-linking publication-title: Macromolecules. – volume: 193 start-page: 1 year: 1992 end-page: 9 ident: b0070 article-title: Polymerization of furfuryl alcohols with trifluoroacetic acid : the influence of experimental conditions publication-title: Macromol. Chem. Phys. – volume: 3 start-page: 1451 year: 2011 end-page: 1458 ident: b0110 article-title: Acid-catalyzed furfuryl alcohol polymerization: Characterizations of molecular structure and thermodynamic properties publication-title: ChemCatChem. – reference: X. Liu, B. Li, G. Han, X. Liu, Z. Cao, D. en Jiang, Y. Sun, Electrocatalytic synthesis of heterocycles from biomass-derived furfuryl alcohols, Nat. Commun. 12 (2021) 1–12. https://doi.org/10.1038/s41467-021-22157-5. – volume: 52 start-page: 6255 year: 2011 end-page: 6259 ident: b0275 article-title: photocatalytic and thermal oxygenation of a furan derivative publication-title: Tetrahedron Lett. – volume: 47 start-page: 1887 year: 2011 end-page: 1889 ident: b0230 article-title: Palladium catalyzed ring opening of furans as a route to α, β-unsaturated aldehydes publication-title: Chem. Commun. – volume: 15 start-page: 1218 year: 1982 end-page: 1220 ident: b0075 article-title: 13C NMR Study of Cured Furfuryl Alcohol Resins Using Cross Polarization and Magic-Angle Spinning publication-title: Macromolecules. – volume: 23 start-page: 8003 year: 2021 end-page: 8015 ident: b0030 article-title: Furfurylation protects timber from degradation by marine wood boring crustaceans publication-title: Green Chem. – volume: 9 start-page: 1144 year: 2016 end-page: 1189 ident: b0020 article-title: Furfural: A renewable and versatile platform molecule for the synthesis of chemicals and fuels publication-title: Energy Environ. Sci. – volume: 112 start-page: 2580 year: 2008 end-page: 2589 ident: b0090 article-title: Furfuryl alcohol polymerization in H-Y confined spaces: Reaction mechanism and structure of carbocationic intermediates publication-title: J. Phys. Chem. B. – volume: 14 start-page: 1 year: 2022 end-page: 28 ident: b0015 article-title: The road to bring FDCA and PEF to the market publication-title: Polymers. – volume: 12 start-page: 1671 year: 1968 end-page: 1681 ident: b0050 article-title: An investigation of the polymerization of furfuryl alcohol with gel permeation chromatography publication-title: J. Appl. Polym. Sci. – volume: 63 start-page: 156 year: 2014 end-page: 166 ident: b0170 article-title: Structural characterization of Kraft lignins from different spent cooking liquors by 1D and 2D Nuclear Magnetic Resonance spectroscopy publication-title: Biomass and Bioenergy. – volume: 10 start-page: 1920 year: 2022 end-page: 1931 ident: b0010 article-title: Reactive and Mechanistic Insights into the Acid-Catalyzed Conversion of Concentrated C 5 /C 6 Sugars in Ethylene Glycol publication-title: ACS Sustain. Chem. Eng. – volume: 7 start-page: 1579 year: 2012 end-page: 1589 ident: b0160 article-title: Whole plant cell wall characterization using solution-state 2D NMR publication-title: Nat. Protoc. – volume: 78 start-page: 195 year: 2016 end-page: 212 ident: b0105 article-title: Structure and properties of poly(furfuryl alcohol)-tannin polyHIPEs publication-title: Eur. Polym. J. – volume: 48 start-page: 637 year: 1999 end-page: 641 ident: b0060 article-title: An NMR study of poly(furfuryl alcohol) prepared with p-toluenesulphonic acid publication-title: Polym. Int. – reference: edition, John Wiley & Sons, Inc. 2014. – volume: 14 start-page: 601 year: 2012 end-page: 604 ident: b0260 article-title: Using water, light, air and spirulina to access a wide variety of polyoxygenated compounds publication-title: Green Chem. – volume: 262 year: 2021 ident: b0135 article-title: Chemical constitution of polyfurfuryl alcohol investigated by FTIR and Resonant Raman spectroscopy, Spectrochim. Acta - Part A Mol. Biomol publication-title: Spectrosc. – volume: 51 start-page: 6116 year: 2003 end-page: 6127 ident: b0165 article-title: Elucidation of the structures of residual and dissolved pine kraft lignins using an HMQC NMR technique publication-title: J. Agric. Food Chem. – volume: 25 start-page: 2587 year: 2013 end-page: 2600 ident: b0175 article-title: Coexistence but independent biosynthesis of catechyl and guaiacyl/syringyl lignin polymers in seed coats publication-title: Plant Cell. – volume: 6 start-page: 40489 year: 2016 end-page: 40501 ident: b0220 article-title: Effects of water and alcohols on the polymerization of furan during its acid-catalyzed conversion into benzofuran publication-title: RSC Adv. – volume: 770 start-page: 99 year: 2006 end-page: 106 ident: b0115 article-title: Ab initio modelling of crosslinking in polymers. A case of chains with furan rings publication-title: J. Mol. Struct. Theochem. – volume: 9 start-page: 2703 year: 1971 end-page: 2715 ident: b0045 article-title: Study of the γ-alumina polymerization of furfuryl alcohol, J. Polym. Sci. Part A-1 publication-title: Polym. Chem. – volume: 8 start-page: 4149 year: 2015 end-page: 4161 ident: b0190 article-title: Copolymerization as a Strategy to Combine Epoxidized Linseed Oil and Furfuryl Alcohol: The Design of a Fully Bio-Based Thermoset publication-title: ChemSusChem. – volume: 27 start-page: 3212 year: 2022 ident: b0150 article-title: Conditions to Control Furan Ring Opening during Furfuryl Alcohol Polymerization publication-title: Molecules. – reference: A. Gandini, M.N. Belgacem, Handbook of thermoset plastics, Elsevier, 2022. – reference: X. Zhu, B. Bruijnaers, T. V. Lourençon, M. Balakshin, Structural Analysis of Lignin-Based Furan Resin, Materials (Basel). 15(1) (2022). 350 – volume: 15 start-page: 1079 year: 1971 end-page: 1090 ident: b0055 article-title: The chemistry of furfuryl alcohol resins publication-title: J. Appl. Polym. Sci. – volume: 373 start-page: 365 year: 2019 end-page: 374 ident: b0035 article-title: First synthesis of poly(furfuryl) alcohol precursor-based porous carbon beads as an efficient adsorbent for volatile organic compounds publication-title: Chem. Eng. J. – volume: 30 start-page: 1071 year: 2016 end-page: 1077 ident: b0195 article-title: Determination of Carbonyl Groups in Pyrolysis Bio-oils Using Potentiometric Titration: Review and Comparison of Methods publication-title: Energy and Fuels. – volume: 34 start-page: 814 year: 1942 end-page: 817 ident: b0040 article-title: The Nature of Furfuryl Alcohol publication-title: Ind. Eng. Chem. – volume: 107 start-page: 2411 year: 2007 end-page: 2502 ident: b0005 article-title: Chemical routes for the transformation of biomass into chemicals publication-title: Chem. Rev. – volume: 6 start-page: 111564 year: 2016 end-page: 111598 ident: b0210 article-title: Achmatowicz reaction and its application in the syntheses of bioactive molecules publication-title: RSC Adv. – volume: 11 start-page: 1202 year: 2022 end-page: 1206 ident: b0155 article-title: Exploring New Horizons for Bio-Based Poly(furfuryl alcohol) by Exploiting Functionalities Offered by Side Reactions publication-title: ACS Macro Letters. – volume: 180 start-page: 38 year: 2016 end-page: 43 ident: b0245 article-title: Oxidant free one-pot transformation of bio-based 2,5-bis-hydroxymethylfuran into α-6-hydroxy-6-methyl-4-enyl-2H-pyran-3-one in water publication-title: Appl. Catal. B Environ. – year: 2008 ident: b0200 article-title: Quantitative 1H NMR Spectroscopy - Chemical and Biological Applications – volume: 38 start-page: 287 year: 2002 end-page: 297 ident: b0125 article-title: Furfuryl alcohol polymerisation by iodine in methylene chloride publication-title: Eur. Polym. J. – volume: 62 start-page: 709 year: 2008 end-page: 713 ident: b0180 article-title: Towards novel wood-based materials: Chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR publication-title: Holzforschung. – volume: 11 start-page: 1 year: 2019 end-page: 15 ident: b0140 article-title: Understanding the polymerization of polyfurfuryl alcohol: Ring opening and diels-alder reactions publication-title: Polymers (Basel). – volume: 47 start-page: 6849 year: 2006 end-page: 6850 ident: b0235 article-title: Oxidative ring opening of 2,5-diarylfurans by Selectfluor® publication-title: Tetrahedron Lett. – volume: 12 start-page: 2748 year: 2019 end-page: 2754 ident: b0250 article-title: Biorefinery via Achmatowicz Rearrangement: Synthesis of Pentane-1,2,5-triol from Furfuryl Alcohol publication-title: ChemSusChem. – volume: 11 start-page: 1805 year: 2018 end-page: 1812 ident: b0130 article-title: Opening Furan for Tailoring Properties of Bio-based Poly(Furfuryl Alcohol) Thermoset publication-title: ChemSusChem. – volume: 55 start-page: 1196 year: 2022 end-page: 1204 ident: b0145 article-title: Monitoring the Degree of Carbonyl-Based Open Structure in a Furanic Macromolecular System publication-title: Macromolecules. – reference: R. M. Silverstein, F. X. Webster, D. J. Kiemle, D. L. Bryce, Spectrometric identification of organic compounds 8 – volume: 87 start-page: 1 year: 2015 end-page: 256 ident: b0240 article-title: Oxidative cleavage of furans publication-title: Org. React. – volume: 17 start-page: 1087 year: 1984 end-page: 1090 ident: b0080 article-title: 13C NMR Study of Curing in Furfuryl Alcohol Resins publication-title: Macromolecules. – volume: 11 start-page: 31395 year: 2021 end-page: 31399 ident: b0270 article-title: Furan oxidation by Mn(III)/Co(II) catalysts – application to benzofuran synthesis† publication-title: RSC Adv. – reference: . – year: 1970 ident: b0215 article-title: Organic Chemistry publication-title: Oxford University Press – volume: 19 start-page: 30 year: 2017 end-page: 33 ident: b0265 article-title: Visible-light-mediated achmatowicz rearrangement publication-title: Org. Lett. – volume: 1 start-page: 2897 year: 1985 end-page: 2911 ident: b0095 article-title: Polymerization of Furfuryl Acetate in Acetonitrole publication-title: J. Polym. Sci. A – volume: 7 start-page: 37 year: 1963 end-page: 52 ident: b0085 article-title: An investigation of the structure of furfuryl alcohol polycondensates with infrared spectroscopy publication-title: J. Appl. Polym. Sci. – volume: 183 start-page: 2799 year: 1982 end-page: 2809 ident: b0065 article-title: Characterization of furfuryl alcohol oligomers by 1H and 13C NMR spectroscopy publication-title: Die Makromol. Chemie. – volume: 14 start-page: 601 year: 2012 ident: 10.1016/j.eurpolymj.2023.111869_b0260 article-title: Using water, light, air and spirulina to access a wide variety of polyoxygenated compounds publication-title: Green Chem. doi: 10.1039/c2gc16397g – year: 2008 ident: 10.1016/j.eurpolymj.2023.111869_b0200 – volume: 62 start-page: 709 year: 2008 ident: 10.1016/j.eurpolymj.2023.111869_b0180 article-title: Towards novel wood-based materials: Chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR publication-title: Holzforschung. doi: 10.1515/HF.2008.110 – volume: 11 start-page: 31395 year: 2021 ident: 10.1016/j.eurpolymj.2023.111869_b0270 article-title: Furan oxidation by Mn(III)/Co(II) catalysts – application to benzofuran synthesis† publication-title: RSC Adv. doi: 10.1039/D1RA05305A – volume: 373 start-page: 365 year: 2019 ident: 10.1016/j.eurpolymj.2023.111869_b0035 article-title: First synthesis of poly(furfuryl) alcohol precursor-based porous carbon beads as an efficient adsorbent for volatile organic compounds publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2019.05.029 – volume: 1 start-page: 2897 issue: 23 year: 1985 ident: 10.1016/j.eurpolymj.2023.111869_b0095 article-title: Polymerization of Furfuryl Acetate in Acetonitrole publication-title: J. Polym. Sci. A – volume: 7 start-page: 37 year: 1963 ident: 10.1016/j.eurpolymj.2023.111869_b0085 article-title: An investigation of the structure of furfuryl alcohol polycondensates with infrared spectroscopy publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.1963.070070104 – volume: 49 start-page: 52 year: 2009 ident: 10.1016/j.eurpolymj.2023.111869_b0120 article-title: Poly(furfuryl alcohol) formation in neat furfuryl alcohol and in cymene studied by ATR-IR spectroscopy and density functional theory (B3LYP) prediction of vibrational bands publication-title: Vib. Spectrosc. doi: 10.1016/j.vibspec.2008.04.013 – volume: 38 start-page: 287 year: 2002 ident: 10.1016/j.eurpolymj.2023.111869_b0125 article-title: Furfuryl alcohol polymerisation by iodine in methylene chloride publication-title: Eur. Polym. J. doi: 10.1016/S0014-3057(01)00090-8 – volume: 47 start-page: 6849 year: 2006 ident: 10.1016/j.eurpolymj.2023.111869_b0235 article-title: Oxidative ring opening of 2,5-diarylfurans by Selectfluor® publication-title: Tetrahedron Lett. doi: 10.1016/j.tetlet.2006.07.071 – volume: 183 start-page: 2799 year: 1982 ident: 10.1016/j.eurpolymj.2023.111869_b0065 article-title: Characterization of furfuryl alcohol oligomers by 1H and 13C NMR spectroscopy publication-title: Die Makromol. Chemie. doi: 10.1002/macp.1982.021831115 – volume: 15 start-page: 1218 year: 1982 ident: 10.1016/j.eurpolymj.2023.111869_b0075 article-title: 13C NMR Study of Cured Furfuryl Alcohol Resins Using Cross Polarization and Magic-Angle Spinning publication-title: Macromolecules. doi: 10.1021/ma00232a058 – ident: 10.1016/j.eurpolymj.2023.111869_b0255 doi: 10.1038/s41467-021-22157-5 – year: 1970 ident: 10.1016/j.eurpolymj.2023.111869_b0215 article-title: Organic Chemistry publication-title: Oxford University Press – volume: 78 start-page: 195 year: 2016 ident: 10.1016/j.eurpolymj.2023.111869_b0105 article-title: Structure and properties of poly(furfuryl alcohol)-tannin polyHIPEs publication-title: Eur. Polym. J. doi: 10.1016/j.eurpolymj.2016.03.037 – volume: 6 start-page: 40489 year: 2016 ident: 10.1016/j.eurpolymj.2023.111869_b0220 article-title: Effects of water and alcohols on the polymerization of furan during its acid-catalyzed conversion into benzofuran publication-title: RSC Adv. doi: 10.1039/C6RA04745A – volume: 12 start-page: 1671 year: 1968 ident: 10.1016/j.eurpolymj.2023.111869_b0050 article-title: An investigation of the polymerization of furfuryl alcohol with gel permeation chromatography publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.1968.070120716 – volume: 27 start-page: 3212 year: 2022 ident: 10.1016/j.eurpolymj.2023.111869_b0150 article-title: Conditions to Control Furan Ring Opening during Furfuryl Alcohol Polymerization publication-title: Molecules. doi: 10.3390/molecules27103212 – volume: 193 start-page: 1 year: 1992 ident: 10.1016/j.eurpolymj.2023.111869_b0070 article-title: Polymerization of furfuryl alcohols with trifluoroacetic acid : the influence of experimental conditions publication-title: Macromol. Chem. Phys. doi: 10.1002/macp.1992.021930101 – ident: 10.1016/j.eurpolymj.2023.111869_b0025 doi: 10.1016/B978-0-12-821632-3.00006-3 – volume: 180 start-page: 38 year: 2016 ident: 10.1016/j.eurpolymj.2023.111869_b0245 article-title: Oxidant free one-pot transformation of bio-based 2,5-bis-hydroxymethylfuran into α-6-hydroxy-6-methyl-4-enyl-2H-pyran-3-one in water publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2015.06.003 – volume: 48 start-page: 637 year: 1999 ident: 10.1016/j.eurpolymj.2023.111869_b0060 article-title: An NMR study of poly(furfuryl alcohol) prepared with p-toluenesulphonic acid publication-title: Polym. Int. doi: 10.1002/(SICI)1097-0126(199908)48:8<637::AID-PI206>3.0.CO;2-C – volume: 6 start-page: 111564 year: 2016 ident: 10.1016/j.eurpolymj.2023.111869_b0210 article-title: Achmatowicz reaction and its application in the syntheses of bioactive molecules publication-title: RSC Adv. doi: 10.1039/C6RA22611F – volume: 9 start-page: 2703 year: 1971 ident: 10.1016/j.eurpolymj.2023.111869_b0045 article-title: Study of the γ-alumina polymerization of furfuryl alcohol, J. Polym. Sci. Part A-1 publication-title: Polym. Chem. – volume: 52 start-page: 6255 year: 2011 ident: 10.1016/j.eurpolymj.2023.111869_b0275 article-title: photocatalytic and thermal oxygenation of a furan derivative publication-title: Tetrahedron Lett. doi: 10.1016/j.tetlet.2011.09.076 – volume: 9 start-page: 1144 year: 2016 ident: 10.1016/j.eurpolymj.2023.111869_b0020 article-title: Furfural: A renewable and versatile platform molecule for the synthesis of chemicals and fuels publication-title: Energy Environ. Sci. doi: 10.1039/C5EE02666K – volume: 55 start-page: 1196 year: 2022 ident: 10.1016/j.eurpolymj.2023.111869_b0145 article-title: Monitoring the Degree of Carbonyl-Based Open Structure in a Furanic Macromolecular System publication-title: Macromolecules. doi: 10.1021/acs.macromol.1c02098 – volume: 30 start-page: 1071 year: 2016 ident: 10.1016/j.eurpolymj.2023.111869_b0195 article-title: Determination of Carbonyl Groups in Pyrolysis Bio-oils Using Potentiometric Titration: Review and Comparison of Methods publication-title: Energy and Fuels. – volume: 14 start-page: 1 issue: 5 year: 2022 ident: 10.1016/j.eurpolymj.2023.111869_b0015 article-title: The road to bring FDCA and PEF to the market publication-title: Polymers. doi: 10.3390/polym14050943 – volume: 17 start-page: 1087 year: 1984 ident: 10.1016/j.eurpolymj.2023.111869_b0080 article-title: 13C NMR Study of Curing in Furfuryl Alcohol Resins publication-title: Macromolecules. doi: 10.1021/ma00135a019 – volume: 15 start-page: 1079 year: 1971 ident: 10.1016/j.eurpolymj.2023.111869_b0055 article-title: The chemistry of furfuryl alcohol resins publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.1971.070150504 – volume: 11 start-page: 1 year: 2019 ident: 10.1016/j.eurpolymj.2023.111869_b0140 article-title: Understanding the polymerization of polyfurfuryl alcohol: Ring opening and diels-alder reactions publication-title: Polymers (Basel). doi: 10.3390/polym11122126 – volume: 7 start-page: 1579 year: 2012 ident: 10.1016/j.eurpolymj.2023.111869_b0160 article-title: Whole plant cell wall characterization using solution-state 2D NMR publication-title: Nat. Protoc. doi: 10.1038/nprot.2012.064 – volume: 8 start-page: 4149 year: 2015 ident: 10.1016/j.eurpolymj.2023.111869_b0190 article-title: Copolymerization as a Strategy to Combine Epoxidized Linseed Oil and Furfuryl Alcohol: The Design of a Fully Bio-Based Thermoset publication-title: ChemSusChem. doi: 10.1002/cssc.201501259 – volume: 107 start-page: 2411 year: 2007 ident: 10.1016/j.eurpolymj.2023.111869_b0005 article-title: Chemical routes for the transformation of biomass into chemicals publication-title: Chem. Rev. doi: 10.1021/cr050989d – volume: 50 start-page: 7223 year: 2014 ident: 10.1016/j.eurpolymj.2023.111869_b0225 article-title: The versatility of furfuryl alcohols and furanoxonium ions in synthesis publication-title: Chem. Commun. doi: 10.1039/c4cc01196a – ident: 10.1016/j.eurpolymj.2023.111869_b0185 doi: 10.3390/ma15010350 – volume: 3 start-page: 1451 year: 2011 ident: 10.1016/j.eurpolymj.2023.111869_b0110 article-title: Acid-catalyzed furfuryl alcohol polymerization: Characterizations of molecular structure and thermodynamic properties publication-title: ChemCatChem. doi: 10.1002/cctc.201100098 – volume: 262 year: 2021 ident: 10.1016/j.eurpolymj.2023.111869_b0135 article-title: Chemical constitution of polyfurfuryl alcohol investigated by FTIR and Resonant Raman spectroscopy, Spectrochim. Acta - Part A Mol. Biomol publication-title: Spectrosc. – ident: 10.1016/j.eurpolymj.2023.111869_b0205 – volume: 112 start-page: 2580 year: 2008 ident: 10.1016/j.eurpolymj.2023.111869_b0090 article-title: Furfuryl alcohol polymerization in H-Y confined spaces: Reaction mechanism and structure of carbocationic intermediates publication-title: J. Phys. Chem. B. doi: 10.1021/jp073958q – volume: 34 start-page: 814 year: 1942 ident: 10.1016/j.eurpolymj.2023.111869_b0040 article-title: The Nature of Furfuryl Alcohol publication-title: Ind. Eng. Chem. doi: 10.1021/ie50391a010 – volume: 47 start-page: 1887 year: 2011 ident: 10.1016/j.eurpolymj.2023.111869_b0230 article-title: Palladium catalyzed ring opening of furans as a route to α, β-unsaturated aldehydes publication-title: Chem. Commun. doi: 10.1039/C0CC04164E – volume: 29 start-page: 3839 year: 1996 ident: 10.1016/j.eurpolymj.2023.111869_b0100 article-title: Acid-catalyzed polycondensation of furfuryl alcohol: Mechanisms of chromophore formation and cross-linking publication-title: Macromolecules. doi: 10.1021/ma951522f – volume: 87 start-page: 1 year: 2015 ident: 10.1016/j.eurpolymj.2023.111869_b0240 article-title: Oxidative cleavage of furans publication-title: Org. React. – volume: 12 start-page: 2748 year: 2019 ident: 10.1016/j.eurpolymj.2023.111869_b0250 article-title: Biorefinery via Achmatowicz Rearrangement: Synthesis of Pentane-1,2,5-triol from Furfuryl Alcohol publication-title: ChemSusChem. doi: 10.1002/cssc.201900601 – volume: 51 start-page: 6116 year: 2003 ident: 10.1016/j.eurpolymj.2023.111869_b0165 article-title: Elucidation of the structures of residual and dissolved pine kraft lignins using an HMQC NMR technique publication-title: J. Agric. Food Chem. doi: 10.1021/jf034372d – volume: 10 start-page: 1920 year: 2022 ident: 10.1016/j.eurpolymj.2023.111869_b0010 article-title: Reactive and Mechanistic Insights into the Acid-Catalyzed Conversion of Concentrated C 5 /C 6 Sugars in Ethylene Glycol publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.1c07807 – volume: 11 start-page: 1805 year: 2018 ident: 10.1016/j.eurpolymj.2023.111869_b0130 article-title: Opening Furan for Tailoring Properties of Bio-based Poly(Furfuryl Alcohol) Thermoset publication-title: ChemSusChem. doi: 10.1002/cssc.201800620 – volume: 770 start-page: 99 year: 2006 ident: 10.1016/j.eurpolymj.2023.111869_b0115 article-title: Ab initio modelling of crosslinking in polymers. A case of chains with furan rings publication-title: J. Mol. Struct. Theochem. doi: 10.1016/j.theochem.2006.05.027 – volume: 23 start-page: 8003 year: 2021 ident: 10.1016/j.eurpolymj.2023.111869_b0030 article-title: Furfurylation protects timber from degradation by marine wood boring crustaceans publication-title: Green Chem. doi: 10.1039/D1GC01524A – volume: 63 start-page: 156 year: 2014 ident: 10.1016/j.eurpolymj.2023.111869_b0170 article-title: Structural characterization of Kraft lignins from different spent cooking liquors by 1D and 2D Nuclear Magnetic Resonance spectroscopy publication-title: Biomass and Bioenergy. doi: 10.1016/j.biombioe.2014.02.020 – volume: 25 start-page: 2587 year: 2013 ident: 10.1016/j.eurpolymj.2023.111869_b0175 article-title: Coexistence but independent biosynthesis of catechyl and guaiacyl/syringyl lignin polymers in seed coats publication-title: Plant Cell. doi: 10.1105/tpc.113.113142 – volume: 11 start-page: 1202 year: 2022 ident: 10.1016/j.eurpolymj.2023.111869_b0155 article-title: Exploring New Horizons for Bio-Based Poly(furfuryl alcohol) by Exploiting Functionalities Offered by Side Reactions publication-title: ACS Macro Letters. doi: 10.1021/acsmacrolett.2c00427 – volume: 19 start-page: 30 year: 2017 ident: 10.1016/j.eurpolymj.2023.111869_b0265 article-title: Visible-light-mediated achmatowicz rearrangement publication-title: Org. Lett. doi: 10.1021/acs.orglett.6b03237 |
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