A superhydrophobic/electrothermal synergistically anti-icing strategy based on graphene composite

Surface icing tends to cause serious problems such as flash over and the following blackout accident. Although electrothermal system is the most widely used method, how to solve the re-freeze problem as the melted ice tend to stay on the surface is still a challenge. Here, we introduced a superhydro...

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Published in:Composites science and technology Vol. 198; p. 108307
Main Authors: Wang, Peng, Yao, Tao, Li, Ziqiang, Wei, Weidong, Xie, Qing, Duan, Wei, Han, Huilong
Format: Journal Article
Language:English
Published: Barking Elsevier Ltd 29.09.2020
Elsevier BV
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ISSN:0266-3538, 1879-1050
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Abstract Surface icing tends to cause serious problems such as flash over and the following blackout accident. Although electrothermal system is the most widely used method, how to solve the re-freeze problem as the melted ice tend to stay on the surface is still a challenge. Here, we introduced a superhydrophobic/electrothermal synergistically anti-icing strategy based on graphene composite. The superhydrophobicity together with the high electrothermal efficiency let the graphene surface dry and clean in the simulated “glaze ice” condition. Although ice accretion would be formed on the surface when the DC voltage was off, the ice could be rapidly removed within 70 s after applying the voltage of 50 V. To enhance the durability of superhydrophobic surface, the hierarchical structure was constructed by the tri-scale nature of inorganic fillers (graphene, carbon nanotubes and silica nanoparticles). Then the hierarchical structure was partially embedded into the substrate by a dissolution and resolidification method. The coupling effect of partially-embedded structure and hierarchical structure led to the superior robustness, which could withstand sandpaper abrasion (500 g load, 8.00 m), the attack of various corrosive liquids, and low/high temperature treatment without losing superhydrophobicity. More remarkably, this graphene superhydrophobic composite retained deicing property even after 30 icing/deicing cycles.
AbstractList Surface icing tends to cause serious problems such as flash over and the following blackout accident. Although electrothermal system is the most widely used method, how to solve the re-freeze problem as the melted ice tend to stay on the surface is still a challenge. Here, we introduced a superhydrophobic/electrothermal synergistically anti-icing strategy based on graphene composite. The superhydrophobicity together with the high electrothermal efficiency let the graphene surface dry and clean in the simulated "glaze ice" condition. Although ice accretion would be formed on the surface when the DC voltage was off, the ice could be rapidly removed within 70 s after applying the voltage of 50 V. To enhance the durability of superhydrophobic surface, the hierarchical structure was constructed by the tri-scale nature of inorganic fillers (graphene, carbon nanotubes and silica nanoparticles). Then the hierarchical structure was partially embedded into the substrate by a dissolution and resolidification method. The coupling effect of partially-embedded structure and hierarchical structure led to the superior robustness, which could withstand sandpaper abrasion (500 g load, 8.00 m), the attack of various corrosive liquids, and low/high temperature treatment without losing superhydrophobicity. More remarkably, this graphene superhydrophobic composite retained deicing property even after 30 icing/deicing cycles.
Surface icing tends to cause serious problems such as flash over and the following blackout accident. Although electrothermal system is the most widely used method, how to solve the re-freeze problem as the melted ice tend to stay on the surface is still a challenge. Here, we introduced a superhydrophobic/electrothermal synergistically anti-icing strategy based on graphene composite. The superhydrophobicity together with the high electrothermal efficiency let the graphene surface dry and clean in the simulated “glaze ice” condition. Although ice accretion would be formed on the surface when the DC voltage was off, the ice could be rapidly removed within 70 s after applying the voltage of 50 V. To enhance the durability of superhydrophobic surface, the hierarchical structure was constructed by the tri-scale nature of inorganic fillers (graphene, carbon nanotubes and silica nanoparticles). Then the hierarchical structure was partially embedded into the substrate by a dissolution and resolidification method. The coupling effect of partially-embedded structure and hierarchical structure led to the superior robustness, which could withstand sandpaper abrasion (500 g load, 8.00 m), the attack of various corrosive liquids, and low/high temperature treatment without losing superhydrophobicity. More remarkably, this graphene superhydrophobic composite retained deicing property even after 30 icing/deicing cycles.
ArticleNumber 108307
Author Wei, Weidong
Wang, Peng
Li, Ziqiang
Han, Huilong
Xie, Qing
Yao, Tao
Duan, Wei
Author_xml – sequence: 1
  givenname: Peng
  surname: Wang
  fullname: Wang, Peng
  email: wang.peng.ncepu@foxmail.com
  organization: School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding, 071000, China
– sequence: 2
  givenname: Tao
  surname: Yao
  fullname: Yao, Tao
  organization: School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding, 071000, China
– sequence: 3
  givenname: Ziqiang
  surname: Li
  fullname: Li, Ziqiang
  organization: School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding, 071000, China
– sequence: 4
  givenname: Weidong
  surname: Wei
  fullname: Wei, Weidong
  organization: School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding, 071000, China
– sequence: 5
  givenname: Qing
  surname: Xie
  fullname: Xie, Qing
  email: xq_ncepu@126.com
  organization: School of Electrical and Electronic Engineering, North China Electric Power University, 071003, Baoding, Hebei, China
– sequence: 6
  givenname: Wei
  surname: Duan
  fullname: Duan, Wei
  organization: School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding, 071000, China
– sequence: 7
  givenname: Huilong
  surname: Han
  fullname: Han, Huilong
  organization: School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding, 071000, China
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ID FETCH-LOGICAL-c349t-83f6fcb02242ae7973c41133e46aa872f68da39e9b1af41de5a8239cee07e5ce3
ISICitedReferencesCount 252
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ISSN 0266-3538
IngestDate Fri Jul 25 02:46:31 EDT 2025
Sat Nov 29 07:22:46 EST 2025
Tue Nov 18 21:38:58 EST 2025
Fri Feb 23 02:48:33 EST 2024
IsPeerReviewed true
IsScholarly true
Keywords Anti-icing
Superhydrophobic
Electrothermal
Graphene
Language English
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crossref_primary_10_1016_j_compscitech_2020_108307
crossref_citationtrail_10_1016_j_compscitech_2020_108307
elsevier_sciencedirect_doi_10_1016_j_compscitech_2020_108307
PublicationCentury 2000
PublicationDate 2020-09-29
PublicationDateYYYYMMDD 2020-09-29
PublicationDate_xml – month: 09
  year: 2020
  text: 2020-09-29
  day: 29
PublicationDecade 2020
PublicationPlace Barking
PublicationPlace_xml – name: Barking
PublicationTitle Composites science and technology
PublicationYear 2020
Publisher Elsevier Ltd
Elsevier BV
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Snippet Surface icing tends to cause serious problems such as flash over and the following blackout accident. Although electrothermal system is the most widely used...
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StartPage 108307
SubjectTerms Abrasion
Anti-icing
Blackout
Carbon nanotubes
Composite materials
Deicing
Electric potential
Electrothermal
Embedded structures
Graphene
High temperature
Hydrophobic surfaces
Hydrophobicity
Ice accumulation
Ice formation
Ice removal
Nanoparticles
Sandpaper
Silicon dioxide
Structural hierarchy
Substrates
Superhydrophobic
Voltage
Title A superhydrophobic/electrothermal synergistically anti-icing strategy based on graphene composite
URI https://dx.doi.org/10.1016/j.compscitech.2020.108307
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