Towards high-performance heterogeneous palladium nanoparticle catalysts for sustainable liquid-phase reactions
High-performance supported palladium nanoparticle (Pd-NP) catalysts help to address the growing demand for 'green' chemical production processes. At present, literature information on how the NP characteristics, NP-support and support-reactant/product interactions affect the catalytic perf...
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| Vydané v: | Reaction chemistry & engineering Ročník 5; číslo 9; s. 1556 - 1618 |
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| Hlavní autori: | , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
Cambridge
Royal Society of Chemistry
01.09.2020
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| Predmet: | |
| ISSN: | 2058-9883, 2058-9883 |
| On-line prístup: | Získať plný text |
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| Shrnutí: | High-performance supported palladium nanoparticle (Pd-NP) catalysts help to address the growing demand for 'green' chemical production processes. At present, literature information on how the NP characteristics, NP-support and support-reactant/product interactions affect the catalytic performance, is scattered. As a result, the present review aims to bring together and critically analyze the relevant literature reports on the catalytic performance of supported Pd-NP catalysts in various liquid-phase reactions such as (de-)hydrogenation, alcohol (electro-)oxidation and cross-coupling reactions. The five main NP support classes,
i.e.
, metal oxides, zeolites, carbon structures, polymers and ordered porous materials, are discussed in detail. A thorough understanding about the catalytic behaviour of supported Pd-NP catalysts
via
the NP characteristics, NP-support and support-reactant/product interactions give useful insights to optimize current or even create novel NP catalysts for a specific liquid-phase reaction.
A walk-through of nanoparticle-reactant/product, nanoparticle-support and support-reactant/product interaction effects on the catalytic performance of heterogeneous palladium catalysts in liquid-phase reactions. |
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| Bibliografia: | Joris W. Thybaut is full professor in catalytic reaction engineering at the Laboratory for Chemical Technology (LCT) at Ghent University since October 2014. He obtained his master's degree in chemical engineering in 1998 at the same university, where he continued his PhD studies on single-event microkinetic (SEMK) modelling of hydrocracking and hydrogenation. In 2003 he went to the Institut des Recherches sur la Catalyse in Lyon, France, for postdoctoral research on high throughput experimentation, before being appointed in 2005 at Ghent University. Today he's an active executive committee member of the LCT with research focused on the kinetics of large-scale, heterogeneously catalyzed reactions. Fundamental kinetic modeling is employed as a tool to acquire a better understanding of the elementary phenomena involved and exploit it for novel catalyst and process design. Beau Van Vaerenbergh received his Master of Science degree in Chemical Engineering Technology from Ghent University in 2014. After graduation, he joined the research group Industrial Catalysis and Adsorption Technology at Ghent University as a PhD student and teaching assistant under the guidance of prof. De Clercq, prof. Thybaut and prof. Vermeir. His PhD study focuses on the synthesis and characterization of supported metal nanoparticles as high-performance catalysts in various liquid-phase reactions such as the Suzuki-Miyaura cross-coupling reaction (pharmaceutical and fine chemicals) and the hydrolysis of sodium borohydride for hydrogen gas production (renewable energy). Jeriffa De Clercq is associate professor at Ghent University since 2016. She obtained her master's degree in Chemical Engineering in 1996 and PhD degree in 2006 at the same university. She is co-heading the Industrial Catalysis and Adsorption Technology research group, comprising about 10 researchers. This group focuses on catalyst and adsorbent development and mapping the relationship between their properties and performance for optimization. Also catalyst stability, re-use and reaction mechanisms are investigated. The studied applications include several biomass conversion reactions, the Suzuki coupling reaction, the hydrogen gas production and the removal of natural organic matter fractions from surface water. Jeroen Lauwaert is a postdoc of the Research Foundation - Flanders hosted by Ghent University. In 2015, he obtained his PhD on the design of cooperative catalysts, at the Laboratory for Chemical Technology in collaboration with the Center for Ordered Materials, Organometallics and Catalysis. During his PhD, he gained international experience in the Jones group at Georgia Institute of Technology. Afterwards, he became a postdoc within the Industrial Catalysis and Adsorption Technology group. His main research interests are related to catalyst development for among others, aldol reactions, esterifications, hydrodeoxygenations and Suzuki cross-coupling reactions. His activities comprise a broad spectrum of fields, including catalyst synthesis and characterization, assessing catalytic activity and stability, and kinetic and thermodynamic modelling. Pieter Vermeir is a professor in analytical chemistry at Ghent University since 2015. He obtained his master's degree in chemical engineering technology in 2006 and received his PhD in sciences in 2012. His postdoctoral research at the industrial catalysis and adsorption technology research group focused on the synthesis and characterization of metal nanoparticles on solid supports for heterogeneous catalysis. He is currently in charge of the Laboratory for Chemical Analyses (LCA) focusing on analytical method development and optimization of both inorganic and organic compounds. His laboratory has an ISO17025 accreditation and provides services for industries, universities and research institutes. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
| ISSN: | 2058-9883 2058-9883 |
| DOI: | 10.1039/d0re00197j |