Crystal Structure and Characterization of Two Layered Copper(II) Coordination Polymers with Anions of 3‐Phosphonopropionic Acid and (RS)‐2‐Phosphonobutyric Acid

Blue single crystals of Cu[μ3‐O3P(CH2)2COOH]·2H2O (1) and Cu[(RS)‐μ3‐O3PCH(C2H5)COOH]·3H2O (2) were prepared in aqueous solutions (pH = 2.5–3.5). 1 crystallizes in space group Pbca (no. 61) with a = 812.5(2), b = 919.00(9), and c = 2102.3(2) pm. Cu2+ is fivefold coordinated by three oxygen atoms ste...

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Vydáno v:	Zeitschrift für anorganische und allgemeine Chemie (1950) Ročník 644; číslo 4; s. 205 - 214
Hlavní autoři:	Köferstein, Roberto, Arnold, Michael, Robl, Christian
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Weinheim Wiley Subscription Services, Inc 01.03.2018 Wiley-VCH Verlag
Témata:	2‐Phosphonobutyric acid 3‐Phosphonopropionic acid Anions Antiferromagnetism Cationic polymerization Chemical Sciences Coordination chemistry Coordination polymer Coordination polymers Copper Copper compounds Coupling (molecular) Cristallography Crystal structure Diffraction Hydrogen bonds Isomers Magnetic measurement Oxygen atoms Polymers Single crystals Structural analysis UV/Vis spectroscopy Water chemistry coordination polymers phosphonate Phosphonobutyric acid UV-Vis Isomers Antiferromagnetic coupling copper complexes electronic transition Phosphonopropionic Acid Superexchange copper Layers Metal organic frameworks MOFs
ISSN:	0044-2313, 1521-3749
On-line přístup:	Získat plný text
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