Partially fluorinated derivatives as a powerful tool for the restoration of blanched easel paintings
The use of specific coatings has considerable importance in the field of cultural heritage conservation. The blanching of easel paintings is a worrying phenomenon induced by excessive humidity and porous structures, often obscuring the image beneath a white haze. The research available in the litera...
Saved in:
| Published in: | Progress in organic coatings Vol. 207; p. 109375 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Elsevier B.V
01.10.2025
Elsevier |
| Subjects: | |
| ISSN: | 0300-9440 |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | The use of specific coatings has considerable importance in the field of cultural heritage conservation. The blanching of easel paintings is a worrying phenomenon induced by excessive humidity and porous structures, often obscuring the image beneath a white haze. The research available in the literature describing solutions to solve this problem is extremely limited. In this research, new oligoamides containing hydroxyl and/or amino groups, i.e., partially fluorinated oligodiethylene succinamide-l-tartaramide (DSTF) and oligodiethylene succinamide (DSF), were designed to give high affinity with the polar components present in paint films through non-covalent interactions, and have reduced environmental impact compared to the previously proposed perfluoroamide (DC6G900). These innovative products represent one of the few solutions proposed for this area of application. Their syntheses were carried out via condensation and subsequently ring-opening reaction of the short-fluorinated epoxy compound, 3-perfluorohexyl-1,2-epoxypropane (EC6F). The short-fluorinated chain has a dual effect; it improves surface performance by lowering surface tension while simultaneously reducing environmental impact compared to the perfluoro source previously used. The performance of the two new fluorinated oligoamides (DSTF, DSF) on blanched easel paintings was investigated through a series of tests, from the macroscopic to the microscopic scale. The new fluorinated oligoamides dramatically decreased the luminance value (almost restoring the value of the un-blanched sample) in comparison with the other tested compounds (ESTF, ESF, DF and DC6G900 as a reference). This result is ascribed to the ability of the compounds to fill the pores of the blanched surfaces, as demonstrated by the morphological study using a Field emission gun - Scanning electron microscopy. In addition, preliminary investigations showed that all the tested compounds, can be removed from the treated mock-ups using 2-propanol or 2,2,2-trifluoroethanol, giving promising results concerning the removal of the restoration treatments.
[Display omitted]
•New partially fluorinated oligoamides easy synthesized by two steps reaction•The new oligoamides have proven to be effective for blanched paintings restoration•The new oligoamides have reduced environmental impact compared to perfluoro compounds•FEG-SEM study proved their ability to fill the pores that cause the blanching effect |
|---|---|
| AbstractList | The use of specific coatings has considerable importance in the field of cultural heritage conservation. The blanching of easel paintings is a worrying phenomenon induced by excessive humidity and porous structures, often obscuring the image beneath a white haze. The research available in the literature describing solutions to solve this problem is extremely limited. In this research, new oligoamides containing hydroxyl and/or amino groups, i.e., partially fluorinated oligodiethylene succinamide-L-tartaramide (DSTF) and oligodiethylene succinamide (DSF), were designed to give high affinity with the polar components present in paint films through noncovalent interactions, and have reduced environmental impact compared to the previously proposed perfluoroamide (DC6G900). These innovative products represent one of the few solutions proposed for this area of application. Their syntheses were carried out via condensation and subsequently ring-opening reaction of the short-fluorinated epoxy compound, 3-perfluorohexyl-1,2-epoxypropane (EC6F). The short-fluorinated chain has a dual effect; it improves surface performance by lowering surface tension while simultaneously reducing environmental impact compared to the perfluoro source previously used. The performance of the two new fluorinated oligoamides (DSTF, DSF) on blanched easel paintings was investigated through a series of tests, from the macroscopic to the microscopic scale. The new fluorinated oligoamides dramatically decreased the luminance value (almost restoring the value of the un-blanched sample) in comparison with the other tested compounds (ESTF, ESF, DF and DC6G900 as a reference). This result is ascribed to the ability of the compounds to fill the pores of the blanched surfaces, as demonstrated by the morphological study using a Field emission gun -Scanning electron microscopy. In addition, preliminary investigations showed that all the tested compounds, can be removed from the treated mock-ups using 2-propanol or 2,2,2-trifluoroethanol, giving promising results concerning the removal of the restoration treatments. The use of specific coatings has considerable importance in the field of cultural heritage conservation. The blanching of easel paintings is a worrying phenomenon induced by excessive humidity and porous structures, often obscuring the image beneath a white haze. The research available in the literature describing solutions to solve this problem is extremely limited. In this research, new oligoamides containing hydroxyl and/or amino groups, i.e., partially fluorinated oligodiethylene succinamide-l-tartaramide (DSTF) and oligodiethylene succinamide (DSF), were designed to give high affinity with the polar components present in paint films through non-covalent interactions, and have reduced environmental impact compared to the previously proposed perfluoroamide (DC6G900). These innovative products represent one of the few solutions proposed for this area of application. Their syntheses were carried out via condensation and subsequently ring-opening reaction of the short-fluorinated epoxy compound, 3-perfluorohexyl-1,2-epoxypropane (EC6F). The short-fluorinated chain has a dual effect; it improves surface performance by lowering surface tension while simultaneously reducing environmental impact compared to the perfluoro source previously used. The performance of the two new fluorinated oligoamides (DSTF, DSF) on blanched easel paintings was investigated through a series of tests, from the macroscopic to the microscopic scale. The new fluorinated oligoamides dramatically decreased the luminance value (almost restoring the value of the un-blanched sample) in comparison with the other tested compounds (ESTF, ESF, DF and DC6G900 as a reference). This result is ascribed to the ability of the compounds to fill the pores of the blanched surfaces, as demonstrated by the morphological study using a Field emission gun - Scanning electron microscopy. In addition, preliminary investigations showed that all the tested compounds, can be removed from the treated mock-ups using 2-propanol or 2,2,2-trifluoroethanol, giving promising results concerning the removal of the restoration treatments. [Display omitted] •New partially fluorinated oligoamides easy synthesized by two steps reaction•The new oligoamides have proven to be effective for blanched paintings restoration•The new oligoamides have reduced environmental impact compared to perfluoro compounds•FEG-SEM study proved their ability to fill the pores that cause the blanching effect |
| ArticleNumber | 109375 |
| Author | Camaiti, Mara Salvini, Antonella Lubin-Germain, Nadège Lattuati-Derieux, Agnès Zhang, Yuqing Gallier, Florian Eveno, Myriam |
| Author_xml | – sequence: 1 givenname: Yuqing surname: Zhang fullname: Zhang, Yuqing organization: CY Cergy Paris Université, CNRS, BioCIS, 95000 Cergy-Pontoise, France – sequence: 2 givenname: Myriam surname: Eveno fullname: Eveno, Myriam organization: Centre de Recherche et de Restauration des Musées de France (C2RMF), Palais du Louvre, 75001 Paris, France – sequence: 3 givenname: Florian surname: Gallier fullname: Gallier, Florian organization: CY Cergy Paris Université, CNRS, BioCIS, 95000 Cergy-Pontoise, France – sequence: 4 givenname: Agnès surname: Lattuati-Derieux fullname: Lattuati-Derieux, Agnès organization: Centre de Recherche et de Restauration des Musées de France (C2RMF), Palais du Louvre, 75001 Paris, France – sequence: 5 givenname: Nadège surname: Lubin-Germain fullname: Lubin-Germain, Nadège organization: CY Cergy Paris Université, CNRS, BioCIS, 95000 Cergy-Pontoise, France – sequence: 6 givenname: Mara surname: Camaiti fullname: Camaiti, Mara email: mara.camaiti@igg.cnr.it organization: CNR-Institute of Geosciences and Earth Resources, Via Giorgio La Pira 4, 50121 Florence, Italy – sequence: 7 givenname: Antonella surname: Salvini fullname: Salvini, Antonella email: antonella.salvini@unifi.it organization: Department of Chemistry, University of Florence, 50019 Sesto Fiorentino, Italy |
| BackLink | https://hal.science/hal-05104320$$DView record in HAL |
| BookMark | eNqFkEFLAzEQhXOoYKv-BcnVw9Zks7vt3ixFrVDQg57DbDJpU-JmSdKV_nu3rHoVhhl4vPdgvhmZtL5FQm45m3PGq_vDvPNhpzykec7ychBrsSgnZMoEY1ldFOySzGI8MMYqIeop0W8QkgXnTtS4ow-2hYSaagy2h2R7jBSGoZ3_wmCOjibvHTU-0LRHGjAmHwafb6k3tHHQqv0QR4joaAe2TbbdxWtyYcBFvPm5V-Tj6fF9vcm2r88v69U2U6IQKdPAKwV6ydEUtcprI4BBXpRQYAk1a6ocTb7UfJHzRjTDNhqaErDhWC-0UuKK3I29e3CyC_YTwkl6sHKz2sqzxkrOCpGzng_eavSq4GMMaP4CnMkzS3mQvyzlmaUcWQ7BhzGIwye9xSCjstgq1DagSlJ7-1_FN7uMhzg |
| Cites_doi | 10.1007/s10570-019-02737-x 10.1007/s00339-017-1092-1 10.1021/acsami.7b09440 10.1021/jo300044q 10.1021/ja00081a018 10.1002/chem.200903335 10.3390/molecules26133967 10.1007/s10965-014-0496-2 10.1016/0022-1139(93)03045-N 10.3390/coatings10040353 10.1016/j.apsusc.2013.06.130 10.1007/s00339-015-9366-y 10.1371/journal.pone.0207630 10.1021/ja507848f 10.1016/j.crhy.2018.07.002 10.1179/sic.1972.17.s1.016i 10.1007/s11356-016-8306-5 10.1016/0048-9697(94)90537-1 10.3390/coatings12070927 10.1179/sic.1990.35.s1.029 10.1016/j.culher.2023.06.008 10.1021/es070895g |
| ContentType | Journal Article |
| Copyright | 2025 The Authors Distributed under a Creative Commons Attribution 4.0 International License |
| Copyright_xml | – notice: 2025 The Authors – notice: Distributed under a Creative Commons Attribution 4.0 International License |
| DBID | 6I. AAFTH AAYXX CITATION 1XC BXJBU IHQJB VOOES |
| DOI | 10.1016/j.porgcoat.2025.109375 |
| DatabaseName | ScienceDirect Open Access Titles Elsevier:ScienceDirect:Open Access CrossRef Hyper Article en Ligne (HAL) HAL-SHS: Archive ouverte en Sciences de l'Homme et de la Société HAL-SHS: Archive ouverte en Sciences de l'Homme et de la Société (Open Access) Hyper Article en Ligne (HAL) (Open Access) |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry |
| ExternalDocumentID | oai:HAL:hal-05104320v1 10_1016_j_porgcoat_2025_109375 S0300944025003248 |
| GroupedDBID | --K --M .~1 0R~ 123 1B1 1~. 1~5 29P 4.4 457 4G. 5VS 6I. 7-5 71M 8P~ 9JN AABXZ AAEDT AAEDW AAEPC AAFTH AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AATTM AAXKI AAXUO AAYWO ABFNM ABJNI ABMAC ABNUV ABWVN ABXDB ABXRA ACDAQ ACGFS ACIWK ACNNM ACRLP ACRPL ACVFH ADBBV ADCNI ADEWK ADEZE ADMUD ADNMO AEBSH AEIPS AEKER AENEX AEUPX AEZYN AFJKZ AFPUW AFRZQ AFTJW AGCQF AGHFR AGQPQ AGUBO AGYEJ AHHHB AHPOS AIEXJ AIGII AIIUN AIKHN AITUG AKBMS AKRWK AKURH AKYEP ALMA_UNASSIGNED_HOLDINGS AMRAJ ANKPU APXCP ASPBG AVWKF AXJTR AZFZN BBWZM BKOJK BLXMC CS3 DU5 EBS EFJIC EFKBS EJD ENUVR EO8 EO9 EP2 EP3 FDB FEDTE FGOYB FIRID FNPLU FYGXN G-2 G-Q GBLVA HLY HVGLF HZ~ IHE J1W KOM LX7 M24 M41 MAGPM MO0 N9A NDZJH O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCE SDF SDG SES SEW SMS SPC SPCBC SSG SSM SSZ T5K UHS WH7 WUQ ~G- 9DU AAYXX ACLOT CITATION EFLBG ~HD 1XC BXJBU IHQJB VOOES |
| ID | FETCH-LOGICAL-c343t-da16cad81ef49c29f3a0a245a4e5a90b62ef28d1721b3b721fdab5aeb1e97dcc3 |
| ISICitedReferencesCount | 1 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=001497930200001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 0300-9440 |
| IngestDate | Tue Oct 14 20:32:10 EDT 2025 Sat Nov 29 06:58:41 EST 2025 Sat Aug 16 17:01:02 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Reversibility of the treatment Blanched paintings restoration Spectrocolorimeter and SEM-EDS Fluorinated oligoamides/amines Pores filling |
| Language | English |
| License | This is an open access article under the CC BY-NC-ND license. Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c343t-da16cad81ef49c29f3a0a245a4e5a90b62ef28d1721b3b721fdab5aeb1e97dcc3 |
| ORCID | 0000-0003-0713-9286 0000-0003-3022-5270 |
| OpenAccessLink | https://hal.science/hal-05104320 |
| ParticipantIDs | hal_primary_oai_HAL_hal_05104320v1 crossref_primary_10_1016_j_porgcoat_2025_109375 elsevier_sciencedirect_doi_10_1016_j_porgcoat_2025_109375 |
| PublicationCentury | 2000 |
| PublicationDate | 2025-10-01 |
| PublicationDateYYYYMMDD | 2025-10-01 |
| PublicationDate_xml | – month: 10 year: 2025 text: 2025-10-01 day: 01 |
| PublicationDecade | 2020 |
| PublicationTitle | Progress in organic coatings |
| PublicationYear | 2025 |
| Publisher | Elsevier B.V Elsevier |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier |
| References | Uma Maheswari, Palanivelu (bb0180) 2017; 24 Baglioni, Poggi, Chelazzi, Baglioni (bb0075) 2021; 26 Commission Internationale de l’Eclairage (CIE) (bb0165) 1986 Zhang, Vespignani, Balzano, Bellandi, Camaiti, Lubin-Germain, Salvini (bb0065) 2022; 12 Dopierala, Maciejewski, Karasiewicz, Prochaska (bb0020) 2013; 283 van Loon, Noble, Burnstock (bb0090) 2012 Cotte, Genty-Vincent, Janssens, Susini (bb0120) 2018; 19 O’Hagan (bb0025) 2012; 77 Sletten, Swager (bb0175) 2014; 136 Ukaji, Soeta (bb0145) 2012 Kiely, Chen, Lin (bb0155) 1994; 116 ASTM (bb0170) 2000 Matrali, Kodros, Papathanasiou, Pandis (bb0085) 2023; 62 Lank (bb0105) 1972; 17 Camaiti, Brizi, Bortolotti, Papacchini, Salvini, Fantazzini (bb0055) 2017; 9 Wyld, Mills, Plesters (bb0100) 1980; 4 Schmitt (bb0135) 2012 Oliva, Albanese, Cipriani, Ridi, Giomi, Malavolti, Bernini, Salvini (bb0160) 2014; 21 Genty-Vincent, Song, Phan, Andraud, Menu (bb0125) 2017; 123 Piacenti, Ciampelli, Pasetti (bb0030) 1985 Genty-Vincent (bb0115) 2017 Conder, Hoke, De Wolf, Russell, Buck (bb0070) 2008; 42 Genty-Vincent, Baglioni, Eveno, Bastian, Uziel, Lubin-Germain, Menu (bb0060) 2018; 46 Bergeon, Mondorf, Delbourgo, Rioux (bb0140) 1981 Piacenti, Camaiti (bb0050) 1994; 68 Koller, Burmester (bb0130) 1990; 35 Caselli, Pancaldi, Mazzacane, Baldisserotto, Petrucci, Impallaria, Volpe, D’Accolti, Soffritti, Coccagna, Sassu, Bevilacqua, Volta, Bisi, Lanzoni (bb0080) 2018; 13 Cao, Salvini, Camaiti (bb0005) 2020; 10 Crick, Parkin (bb0015) 2010; 16 Piacenti (bb0040) 1994; 143 Szubert, Dutkiewicz, Dutkiewicz, Maciejewsk (bb0010) 2019; 26 Piacenti, Pasetti, Matteoli, Strepparola (bb0045) 1988 Spring, Keith (bb0110) 2009; 30 Frediani, Manganelli Del Fà, Matteoli, Tiano (bb0035) 1982; 27 Merrylin, Kannah, Banu, Yeom (bb0150) 2020 Genty-Vincent, Eveno, Nowik, Bastian, Ravaud, Cabillic, Uziel, Lubin-Germain, Menu (bb0095) 2015; 121 Szubert (10.1016/j.porgcoat.2025.109375_bb0010) 2019; 26 Dopierala (10.1016/j.porgcoat.2025.109375_bb0020) 2013; 283 O’Hagan (10.1016/j.porgcoat.2025.109375_bb0025) 2012; 77 Genty-Vincent (10.1016/j.porgcoat.2025.109375_bb0115) Schmitt (10.1016/j.porgcoat.2025.109375_bb0135) 2012 van Loon (10.1016/j.porgcoat.2025.109375_bb0090) 2012 Genty-Vincent (10.1016/j.porgcoat.2025.109375_bb0125) 2017; 123 Wyld (10.1016/j.porgcoat.2025.109375_bb0100) 1980; 4 Cao (10.1016/j.porgcoat.2025.109375_bb0005) 2020; 10 Matrali (10.1016/j.porgcoat.2025.109375_bb0085) 2023; 62 Piacenti (10.1016/j.porgcoat.2025.109375_bb0045) 1988 Conder (10.1016/j.porgcoat.2025.109375_bb0070) 2008; 42 Baglioni (10.1016/j.porgcoat.2025.109375_bb0075) 2021; 26 Ukaji (10.1016/j.porgcoat.2025.109375_bb0145) 2012 Cotte (10.1016/j.porgcoat.2025.109375_bb0120) 2018; 19 Frediani (10.1016/j.porgcoat.2025.109375_bb0035) 1982; 27 Piacenti (10.1016/j.porgcoat.2025.109375_bb0040) 1994; 143 Piacenti (10.1016/j.porgcoat.2025.109375_bb0050) 1994; 68 Genty-Vincent (10.1016/j.porgcoat.2025.109375_bb0095) 2015; 121 Crick (10.1016/j.porgcoat.2025.109375_bb0015) 2010; 16 Camaiti (10.1016/j.porgcoat.2025.109375_bb0055) 2017; 9 Bergeon (10.1016/j.porgcoat.2025.109375_bb0140) 1981 Oliva (10.1016/j.porgcoat.2025.109375_bb0160) 2014; 21 Spring (10.1016/j.porgcoat.2025.109375_bb0110) 2009; 30 Genty-Vincent (10.1016/j.porgcoat.2025.109375_bb0060) 2018; 46 Lank (10.1016/j.porgcoat.2025.109375_bb0105) 1972; 17 Koller (10.1016/j.porgcoat.2025.109375_bb0130) 1990; 35 Caselli (10.1016/j.porgcoat.2025.109375_bb0080) 2018; 13 Kiely (10.1016/j.porgcoat.2025.109375_bb0155) 1994; 116 Sletten (10.1016/j.porgcoat.2025.109375_bb0175) 2014; 136 Piacenti (10.1016/j.porgcoat.2025.109375_bb0030) 1985 Merrylin (10.1016/j.porgcoat.2025.109375_bb0150) 2020 Zhang (10.1016/j.porgcoat.2025.109375_bb0065) 2022; 12 Uma Maheswari (10.1016/j.porgcoat.2025.109375_bb0180) 2017; 24 ASTM (10.1016/j.porgcoat.2025.109375_bb0170) 2000 Commission Internationale de l’Eclairage (CIE) (10.1016/j.porgcoat.2025.109375_bb0165) 1986 |
| References_xml | – year: 2017 ident: bb0115 article-title: Les chancis des vernis et des couches picturales des peintures de chevalet à l'huile: Contribution à la caractérisation physico-chimique, à la connaissance des mécanismes de formation et aux traitements de restauration. PhD Thesis, École doctorale Sciences et ingénierie (Cergy-Pontoise, Val d'Oise), France – volume: 13 year: 2018 ident: bb0080 article-title: Characterization of biodegradation in a 17 publication-title: PLoS One – start-page: 119 year: 2020 end-page: 141 ident: bb0150 article-title: Production of organic acids and enzymes/biocatalysts from food waste publication-title: Food Waste to Valuable Resources – year: 1986 ident: bb0165 article-title: Colorimetry publication-title: Publication CIE No. 15.2 – volume: 62 start-page: 322 year: 2023 end-page: 328 ident: bb0085 article-title: Quantification of the degradation of paintings due to the deposition of atmospheric aerosols publication-title: J. Cult. Herit. – volume: 10 start-page: 353 year: 2020 end-page: 376 ident: bb0005 article-title: Current status and future prospects of applying bioinspired superhydrophobic materials for conservation of stone artworks publication-title: Coatings – volume: 116 start-page: 571 year: 1994 end-page: 578 ident: bb0155 article-title: Hydroxylated nylons based on unprotected esterified D-glucaric acid by simple condensation reactions publication-title: J. Am. Chem. Soc. – year: 2000 ident: bb0170 article-title: Standards on color and appearance measurement – volume: 46 start-page: 90 year: 2018 end-page: 95 ident: bb0060 article-title: Les chancis des peintures de chevalet: étude des traitements de restauration actuels et proposition d’une alternative innovante publication-title: Techné. La science au service de l’histoire de l’art et de la préservation des biens culturels – year: 1988 ident: bb0045 article-title: Method for protecting stone materials from atmospheric agents by means of perfluoropolyether derivatives US 4745009 – volume: 12 start-page: 927 year: 2022 end-page: 952 ident: bb0065 article-title: Low fluorinated oligoamides for use as wood protective coating publication-title: Coatings – volume: 9 start-page: 37279 year: 2017 end-page: 37288 ident: bb0055 article-title: An environmental friendly fluorinated oligoamide for producing nonwetting coatings with high performance on porous surfaces publication-title: ACS Appl. Mater. Interfaces – volume: 123 start-page: 9473 year: 2017 end-page: 9482 ident: bb0125 article-title: Four-flux model of the light scattering in porous varnish and paint layers: towards understanding the visual appearance of altered blanched easel oil paintings publication-title: Appl. Phys. A – volume: 16 start-page: 3568 year: 2010 end-page: 3588 ident: bb0015 article-title: Preparation and characterization of super-hydrophobic surfaces publication-title: Chem. Eur. J. – year: 1985 ident: bb0030 article-title: Protecting materials subject to degradation by atmospheric and polluting agents by means of perfluoropolyethers US 4499146 – volume: 17 start-page: 809 year: 1972 end-page: 813 ident: bb0105 article-title: The use of dimethyl formamide vapour in reforming blanched oil paintings publication-title: Stud. Conserv. – volume: 143 start-page: 113 year: 1994 end-page: 120 ident: bb0040 article-title: Chemistry for the conservation of the cultural heritage publication-title: Sci. Total Environ. – volume: 42 start-page: 995 year: 2008 end-page: 1003 ident: bb0070 article-title: Are PFCAs bioaccumulative? A critical review and comparison with regulatory criteria and persistent lipophilic compounds publication-title: Environ. Sci. Technol. – volume: 283 start-page: 453 year: 2013 end-page: 459 ident: bb0020 article-title: Alkyl-and fluoroalkyltrialkoxysilanes for wettability modification publication-title: Appl. Surf. Sci. – volume: 30 start-page: 71 year: 2009 end-page: 85 ident: bb0110 article-title: Aelbert Cuyp's large Dort: colour change and conservation publication-title: Natl. Gallery Tech. Bull. – volume: 35 start-page: 138 year: 1990 end-page: 143 ident: bb0130 article-title: Blanching of unvarnished modern paintings: a case study on a painting by Serge Poliakoff publication-title: Stud. Conserv. – volume: 121 start-page: 779 year: 2015 end-page: 788 ident: bb0095 article-title: Blanching of paint and varnish layers in easel paintings: contribution to the understanding of the alteration publication-title: Appl. Phys. A – start-page: 176 year: 2012 end-page: 201 ident: bb0145 article-title: 3.6 Acetogenin (Polypriopionate) Derived Auxiliaries: Tartaric Acid publication-title: Comprehensive chirality – volume: 19 start-page: 473 year: 2018 ident: bb0120 article-title: Applications of synchrotron X-ray nano-probes in the field of cultural heritage publication-title: C. R. Phys. – start-page: 492 year: 2012 end-page: 496 ident: bb0135 article-title: Research on the Pettenkofer method and the historical understanding of paint film swelling and interaction publication-title: The Conservation of Easel Paintings – volume: 26 start-page: 3967 year: 2021 end-page: 3987 ident: bb0075 article-title: Advanced materials in cultural heritage conservation publication-title: Molecules – volume: 21 start-page: 1 year: 2014 end-page: 12 ident: bb0160 article-title: Water soluble trehalose-derived oligoamides publication-title: J. Polym. Res. – volume: 68 start-page: 227 year: 1994 end-page: 235 ident: bb0050 article-title: Synthesis and characterization of fluorinated polyetheric amides publication-title: J. Fluor. Chem. – volume: 77 start-page: 3689 year: 2012 end-page: 3699 ident: bb0025 article-title: Organofluorine chemistry: synthesis and conformation of vicinal fluoromethylene motifs publication-title: J. Org. Chem. – volume: 26 start-page: 9853 year: 2019 end-page: 9861 ident: bb0010 article-title: Wood protective coatings based on fluorocarbosilane publication-title: Cellulose – volume: 4 start-page: 49 year: 1980 end-page: 63 ident: bb0100 article-title: Some observations on blanching (with special reference to the paintings of Claude) publication-title: Natl. Gallery Tech. Bull. – volume: 136 start-page: 13574 year: 2014 end-page: 13577 ident: bb0175 article-title: Fluorofluorophores: fluorescent fluorous chemical tools spanning the visible spectrum publication-title: J. Am. Chem. Soc. – volume: 24 start-page: 5733 year: 2017 end-page: 5745 ident: bb0180 article-title: Alkyl amine and vegetable oil mixture – a viable candidate for CO publication-title: Environ. Sci. Pollut. Res. – year: 1981 ident: bb0140 article-title: Le blanchiment: un cas précis d’étude publication-title: ICOM Committee for Conservation 7th Triennial Meeting Ottawa Canada 21–25 September – volume: 27 start-page: 31 year: 1982 end-page: 37 ident: bb0035 article-title: Use of perfluoropolyethers as water repellents: study of their behaviuor on pietra serena, a florentine building stone publication-title: Stud. Conserv. – start-page: 216 year: 2012 end-page: 243 ident: bb0090 article-title: Ageing and deterioration of traditional oil and tempera paints publication-title: The Conservation of Easel Paintings – volume: 4 start-page: 49 year: 1980 ident: 10.1016/j.porgcoat.2025.109375_bb0100 article-title: Some observations on blanching (with special reference to the paintings of Claude) publication-title: Natl. Gallery Tech. Bull. – start-page: 119 year: 2020 ident: 10.1016/j.porgcoat.2025.109375_bb0150 article-title: Production of organic acids and enzymes/biocatalysts from food waste – year: 2000 ident: 10.1016/j.porgcoat.2025.109375_bb0170 – volume: 26 start-page: 9853 year: 2019 ident: 10.1016/j.porgcoat.2025.109375_bb0010 article-title: Wood protective coatings based on fluorocarbosilane publication-title: Cellulose doi: 10.1007/s10570-019-02737-x – volume: 123 start-page: 9473 year: 2017 ident: 10.1016/j.porgcoat.2025.109375_bb0125 article-title: Four-flux model of the light scattering in porous varnish and paint layers: towards understanding the visual appearance of altered blanched easel oil paintings publication-title: Appl. Phys. A doi: 10.1007/s00339-017-1092-1 – start-page: 492 year: 2012 ident: 10.1016/j.porgcoat.2025.109375_bb0135 article-title: Research on the Pettenkofer method and the historical understanding of paint film swelling and interaction – volume: 9 start-page: 37279 year: 2017 ident: 10.1016/j.porgcoat.2025.109375_bb0055 article-title: An environmental friendly fluorinated oligoamide for producing nonwetting coatings with high performance on porous surfaces publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.7b09440 – volume: 77 start-page: 3689 issue: 8 year: 2012 ident: 10.1016/j.porgcoat.2025.109375_bb0025 article-title: Organofluorine chemistry: synthesis and conformation of vicinal fluoromethylene motifs publication-title: J. Org. Chem. doi: 10.1021/jo300044q – ident: 10.1016/j.porgcoat.2025.109375_bb0115 – volume: 116 start-page: 571 year: 1994 ident: 10.1016/j.porgcoat.2025.109375_bb0155 article-title: Hydroxylated nylons based on unprotected esterified D-glucaric acid by simple condensation reactions publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00081a018 – volume: 16 start-page: 3568 issue: 12 year: 2010 ident: 10.1016/j.porgcoat.2025.109375_bb0015 article-title: Preparation and characterization of super-hydrophobic surfaces publication-title: Chem. Eur. J. doi: 10.1002/chem.200903335 – year: 1981 ident: 10.1016/j.porgcoat.2025.109375_bb0140 article-title: Le blanchiment: un cas précis d’étude – start-page: 176 year: 2012 ident: 10.1016/j.porgcoat.2025.109375_bb0145 article-title: 3.6 Acetogenin (Polypriopionate) Derived Auxiliaries: Tartaric Acid – volume: 46 start-page: 90 year: 2018 ident: 10.1016/j.porgcoat.2025.109375_bb0060 article-title: Les chancis des peintures de chevalet: étude des traitements de restauration actuels et proposition d’une alternative innovante publication-title: Techné. La science au service de l’histoire de l’art et de la préservation des biens culturels – volume: 26 start-page: 3967 year: 2021 ident: 10.1016/j.porgcoat.2025.109375_bb0075 article-title: Advanced materials in cultural heritage conservation publication-title: Molecules doi: 10.3390/molecules26133967 – volume: 21 start-page: 1 year: 2014 ident: 10.1016/j.porgcoat.2025.109375_bb0160 article-title: Water soluble trehalose-derived oligoamides publication-title: J. Polym. Res. doi: 10.1007/s10965-014-0496-2 – year: 1985 ident: 10.1016/j.porgcoat.2025.109375_bb0030 – volume: 27 start-page: 31 issue: 1 year: 1982 ident: 10.1016/j.porgcoat.2025.109375_bb0035 article-title: Use of perfluoropolyethers as water repellents: study of their behaviuor on pietra serena, a florentine building stone publication-title: Stud. Conserv. – volume: 68 start-page: 227 year: 1994 ident: 10.1016/j.porgcoat.2025.109375_bb0050 article-title: Synthesis and characterization of fluorinated polyetheric amides publication-title: J. Fluor. Chem. doi: 10.1016/0022-1139(93)03045-N – volume: 10 start-page: 353 year: 2020 ident: 10.1016/j.porgcoat.2025.109375_bb0005 article-title: Current status and future prospects of applying bioinspired superhydrophobic materials for conservation of stone artworks publication-title: Coatings doi: 10.3390/coatings10040353 – volume: 283 start-page: 453 year: 2013 ident: 10.1016/j.porgcoat.2025.109375_bb0020 article-title: Alkyl-and fluoroalkyltrialkoxysilanes for wettability modification publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2013.06.130 – volume: 121 start-page: 779 year: 2015 ident: 10.1016/j.porgcoat.2025.109375_bb0095 article-title: Blanching of paint and varnish layers in easel paintings: contribution to the understanding of the alteration publication-title: Appl. Phys. A doi: 10.1007/s00339-015-9366-y – volume: 13 issue: 12 year: 2018 ident: 10.1016/j.porgcoat.2025.109375_bb0080 article-title: Characterization of biodegradation in a 17th century easel painting and potential for a biological approach publication-title: PLoS One doi: 10.1371/journal.pone.0207630 – year: 1986 ident: 10.1016/j.porgcoat.2025.109375_bb0165 article-title: Colorimetry – volume: 136 start-page: 13574 year: 2014 ident: 10.1016/j.porgcoat.2025.109375_bb0175 article-title: Fluorofluorophores: fluorescent fluorous chemical tools spanning the visible spectrum publication-title: J. Am. Chem. Soc. doi: 10.1021/ja507848f – volume: 19 start-page: 473 year: 2018 ident: 10.1016/j.porgcoat.2025.109375_bb0120 article-title: Applications of synchrotron X-ray nano-probes in the field of cultural heritage publication-title: C. R. Phys. doi: 10.1016/j.crhy.2018.07.002 – volume: 17 start-page: 809 year: 1972 ident: 10.1016/j.porgcoat.2025.109375_bb0105 article-title: The use of dimethyl formamide vapour in reforming blanched oil paintings publication-title: Stud. Conserv. doi: 10.1179/sic.1972.17.s1.016i – volume: 24 start-page: 5733 year: 2017 ident: 10.1016/j.porgcoat.2025.109375_bb0180 article-title: Alkyl amine and vegetable oil mixture – a viable candidate for CO2 capture and utilization publication-title: Environ. Sci. Pollut. Res. doi: 10.1007/s11356-016-8306-5 – volume: 30 start-page: 71 year: 2009 ident: 10.1016/j.porgcoat.2025.109375_bb0110 article-title: Aelbert Cuyp's large Dort: colour change and conservation publication-title: Natl. Gallery Tech. Bull. – volume: 143 start-page: 113 year: 1994 ident: 10.1016/j.porgcoat.2025.109375_bb0040 article-title: Chemistry for the conservation of the cultural heritage publication-title: Sci. Total Environ. doi: 10.1016/0048-9697(94)90537-1 – volume: 12 start-page: 927 year: 2022 ident: 10.1016/j.porgcoat.2025.109375_bb0065 article-title: Low fluorinated oligoamides for use as wood protective coating publication-title: Coatings doi: 10.3390/coatings12070927 – volume: 35 start-page: 138 year: 1990 ident: 10.1016/j.porgcoat.2025.109375_bb0130 article-title: Blanching of unvarnished modern paintings: a case study on a painting by Serge Poliakoff publication-title: Stud. Conserv. doi: 10.1179/sic.1990.35.s1.029 – volume: 62 start-page: 322 year: 2023 ident: 10.1016/j.porgcoat.2025.109375_bb0085 article-title: Quantification of the degradation of paintings due to the deposition of atmospheric aerosols publication-title: J. Cult. Herit. doi: 10.1016/j.culher.2023.06.008 – volume: 42 start-page: 995 year: 2008 ident: 10.1016/j.porgcoat.2025.109375_bb0070 article-title: Are PFCAs bioaccumulative? A critical review and comparison with regulatory criteria and persistent lipophilic compounds publication-title: Environ. Sci. Technol. doi: 10.1021/es070895g – year: 1988 ident: 10.1016/j.porgcoat.2025.109375_bb0045 – start-page: 216 year: 2012 ident: 10.1016/j.porgcoat.2025.109375_bb0090 article-title: Ageing and deterioration of traditional oil and tempera paints |
| SSID | ssj0006339 |
| Score | 2.4518764 |
| Snippet | The use of specific coatings has considerable importance in the field of cultural heritage conservation. The blanching of easel paintings is a worrying... |
| SourceID | hal crossref elsevier |
| SourceType | Open Access Repository Index Database Publisher |
| StartPage | 109375 |
| SubjectTerms | Blanched paintings restoration Chemical Sciences Cultural heritage and museology Fluorinated oligoamides/amines Humanities and Social Sciences Organic chemistry Pores filling Reversibility of the treatment Spectrocolorimeter and SEM-EDS |
| Title | Partially fluorinated derivatives as a powerful tool for the restoration of blanched easel paintings |
| URI | https://dx.doi.org/10.1016/j.porgcoat.2025.109375 https://hal.science/hal-05104320 |
| Volume | 207 |
| WOSCitedRecordID | wos001497930200001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVESC databaseName: Elsevier SD Freedom Collection Journals 2021 issn: 0300-9440 databaseCode: AIEXJ dateStart: 19950101 customDbUrl: isFulltext: true dateEnd: 99991231 titleUrlDefault: https://www.sciencedirect.com omitProxy: false ssIdentifier: ssj0006339 providerName: Elsevier |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3fb9MwELa6DQl4QDCYGL9kId6iDNdJneSxGpsGgqkSQypPkePYW6eQljWtthf-du6c2AQGAoSQKquyFDu5-2R_uZzvI-RFrI0GVqHC1DAVxoUahoXmsBgKwZQAAOm0tGITyfFxOp1mk8HgizsLs66Suk4vL7PFf3U19IGz8ejsX7jbDwod8B-cDi24Hdo_cvwE-2RVXQWmWmF6nURSWcLUa1vke4nSMjJYoDwaJig3WIXTJxtaoRlPI4sKQHEGl-NHnCpYyJkVllj2Ke0EM7xwvZzVnUaUCtRcNv0QvA9Lf1x9dnulpfHaKn8H767AMJ98LhDc_ayF0iEmCPbShmTTYG3y8BXWZ17ZjXN8Wtuv_el3EQw-8rlwXVjt2tGa9jgXY2EWt7Wc3FLNW4Xca8t-G4E434NXllN8wj2cxlbKamVZfiip_R4Hx7GB_zFglOkG2eLJKINVcWv8-mD6xu_lIrJadP5memfMfz7br-jNxpkL1FvicnKX3OneOOi4Rco9MtD1Nrm574T-tsntXk3K-6T0-KE9_NAefqiEH3X4oYgfCvihgB_aww-dG-rwQy1-qMfPA_Lh8OBk_yjspDhCFcVRE5ZyKJQs06E2caZ4ZiLJJI9HMtYjmbFCcG14WmI8oYgKaE0pi5EEIqCzpFQq2iGb9bzWDwkVkTBKGyk5Z7FJuGRFoSIhShaXSab0LnnpLJgv2ooruUtFPM-dzXO0ed7afJdkztB5xxtbPpgDPn577XPwjJ8Ii60fjd_m2IfbVRxxth4--ocJHpNb3zD_hGw2Fyv9lNxQ62a2vHjW4e0rUceoQg |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Partially+fluorinated+derivatives+as+a+powerful+tool+for+the+restoration+of+blanched+easel+paintings&rft.jtitle=Progress+in+organic+coatings&rft.au=Zhang%2C+Yuqing&rft.au=Eveno%2C+Myriam&rft.au=Gallier%2C+Florian&rft.au=Lattuati-Derieux%2C+Agn%C3%A8s&rft.date=2025-10-01&rft.pub=Elsevier+B.V&rft.issn=0300-9440&rft.volume=207&rft_id=info:doi/10.1016%2Fj.porgcoat.2025.109375&rft.externalDocID=S0300944025003248 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0300-9440&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0300-9440&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0300-9440&client=summon |