Crystal Structure of Oxide Ceramic Coatings Obtained On Alloys with High Silicon Content

Crystal structure of oxide ceramic coatings obtained on AK9M2 and AK12 alloys is determined. Already after 5 min of processing the AK9M2 alloy by plasma electrolyte oxidation (PEO) method in a standard electrolyte (KOH (3 g/L), Na 2 SiO 3 (2 g/L)), aluminum and silicon form a compound Al 3.21 Si 0.4...

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Vydáno v:	Materials science (New York, N.Y.) Ročník 58; číslo 4; s. 480 - 487
Hlavní autoři:	Kovalchuk, I. V., Yurkeych, R. M., Posuvailo, V. M.
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	New York Springer US 01.01.2023 Springer Springer Nature B.V
Témata:	Alloys Aluminum base alloys Aluminum oxide Analysis Ceramic coatings Ceramic materials Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Coatings Crystal structure Crystals Materials Science Mullite Oxidation Silicon Silicon compounds Silicon dioxide Sillimanite Solid Mechanics Specialty metals industry Stability analysis Structural Materials Structure Thermal stability mullite silumin sillimanite aluminum oxides crystal structure X-ray analysis oxide ceramic coatings plasma electrolyte oxidation
ISSN:	1068-820X, 1573-885X
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Abstract	Crystal structure of oxide ceramic coatings obtained on AK9M2 and AK12 alloys is determined. Already after 5 min of processing the AK9M2 alloy by plasma electrolyte oxidation (PEO) method in a standard electrolyte (KOH (3 g/L), Na 2 SiO 3 (2 g/L)), aluminum and silicon form a compound Al 3.21 Si 0.47 . The thermal stability of compounds with the Al 2 O 3 ∙SiO 2 composition is analyzed. A scheme for converting intermediate oxides into mullite is proposed. The obtained results show that with the increase of silicon content in alloys the amount of sillimanite in the corresponding coatings increases. Increase of the PEO process of silumins processing to 2 h causes a partial transformation of sillimanite into mullite. The maximum content of mullite in coatings is approximately 4 mass%.
AbstractList	Crystal structure of oxide ceramic coatings obtained on AK9M2 and AK12 alloys is determined. Already after 5 min of processing the AK9M2 alloy by plasma electrolyte oxidation (PEO) method in a standard electrolyte (KOH (3 g/L), Na 2SiO3 (2 g/L)), aluminum and silicon form a compound Al3.21Si0.47. The thermal stability of compounds with the Al2O3∙SiO2 composition is analyzed. A scheme for converting intermediate oxides into mullite is proposed. The obtained results show that with the increase of silicon content in alloys the amount of sillimanite in the corresponding coatings increases. Increase of the PEO process of silumins processing to 2 h causes a partial transformation of sillimanite into mullite. The maximum content of mullite in coatings is approximately 4 mass%. Crystal structure of oxide ceramic coatings obtained on AK9M2 and AK12 alloys is determined. Already after 5 min of processing the AK9M2 alloy by plasma electrolyte oxidation (PEO) method in a standard electrolyte (KOH (3 g/L), Na .sub.2SiO.sub.3 (2 g/L)), aluminum and silicon form a compound Al.sub.3.21Si.sub.0.47. The thermal stability of compounds with the Al.sub.2O.sub.3*SiO.sub.2 composition is analyzed. A scheme for converting intermediate oxides into mullite is proposed. The obtained results show that with the increase of silicon content in alloys the amount of sillimanite in the corresponding coatings increases. Increase of the PEO process of silumins processing to 2 h causes a partial transformation of sillimanite into mullite. The maximum content of mullite in coatings is approximately 4 mass%. Crystal structure of oxide ceramic coatings obtained on AK9M2 and AK12 alloys is determined. Already after 5 min of processing the AK9M2 alloy by plasma electrolyte oxidation (PEO) method in a standard electrolyte (KOH (3 g/L), Na 2 SiO 3 (2 g/L)), aluminum and silicon form a compound Al 3.21 Si 0.47 . The thermal stability of compounds with the Al 2 O 3 ∙SiO 2 composition is analyzed. A scheme for converting intermediate oxides into mullite is proposed. The obtained results show that with the increase of silicon content in alloys the amount of sillimanite in the corresponding coatings increases. Increase of the PEO process of silumins processing to 2 h causes a partial transformation of sillimanite into mullite. The maximum content of mullite in coatings is approximately 4 mass%.
Audience	Academic
Author	Posuvailo, V. M. Yurkeych, R. M. Kovalchuk, I. V.
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Cites_doi	10.1007/s11003-022-00638-2 10.1007/s11003-013-9614-2 10.1007/s11003-021-00538-x 10.1007/BF02359992 10.1007/s11003-021-00543-0 10.15587/1729-4061.2017.65718 10.1007/s11003-018-0128-9 10.1143/JJAP.15.871 10.3390/met9030280 10.1016/j.corsci.2010.11.009 10.1016/j.surfcoat.2007.10.008 10.1007/s12540-009-0949-z 10.1016/j.surfcoat.2019.01.015 10.3103/S1068375519050041 10.4028/www.scientific.net/JNanoR.51.92 10.1007/s11837-011-0090-6 10.1007/s11003-018-0137-8 10.4028/0-87849-390-5.27 10.1088/1757-899X/181/1/012045 10.1016/j.jallcom.2020.156320 10.1007/s11003-009-9183-6 10.1007/978-3-030-77719-7_53 10.1007/s11106-015-9678-7 10.1007/978-3-030-50794-7_53 10.1016/S0257-8972(97)00617-8 10.1179/1743278211Y.0000000022 10.1016/j.jmrt.2020.11.102
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Snippet	Crystal structure of oxide ceramic coatings obtained on AK9M2 and AK12 alloys is determined. Already after 5 min of processing the AK9M2 alloy by plasma...
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SubjectTerms	Alloys Aluminum base alloys Aluminum oxide Analysis Ceramic coatings Ceramic materials Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Coatings Crystal structure Crystals Materials Science Mullite Oxidation Silicon Silicon compounds Silicon dioxide Sillimanite Solid Mechanics Specialty metals industry Stability analysis Structural Materials Structure Thermal stability
Title	Crystal Structure of Oxide Ceramic Coatings Obtained On Alloys with High Silicon Content
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