A review on electrospun PVDF-based nanocomposites: Recent trends and developments in energy harvesting and sensing applications

Modern-day requirements for efficient, eco-friendly, and self-powered devices have resulted in a growing interest in piezoelectric polymers among the scientific community. Polyvinylidene fluoride (PVDF) is an excellent electroactive polymer that is flexible, with high mechanical strength, thermal st...

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Published in:Polymer (Guilford) Vol. 283; p. 126179
Main Authors: Purushothaman, Sreelakshmi Moozhiyil, Tronco, Maïté Fernandes, Kottathodi, Bicy, Royaud, Isabelle, Ponçot, Marc, Kalarikkal, Nandakumar, Thomas, Sabu, Rouxel, Didier
Format: Journal Article
Language:English
Published: Elsevier Ltd 22.09.2023
Elsevier
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ISSN:0032-3861, 1873-2291
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Abstract Modern-day requirements for efficient, eco-friendly, and self-powered devices have resulted in a growing interest in piezoelectric polymers among the scientific community. Polyvinylidene fluoride (PVDF) is an excellent electroactive polymer that is flexible, with high mechanical strength, thermal stability, and biocompatibility. The relatively low cost and easiness to be fabricated into thin pliable films made PVDF one of the most studied polymers for the development of nanogenerators and wearable sensors. The piezoelectric properties and therefore the energy harvesting and sensing capabilities of PVDF are distinct characteristics of its electroactive polar phases, especially the β phase. Hence, several PVDF-based nanocomposites that could achieve a high β phase fraction have been widely explored. Electrospinning is one of the best methods for manufacturing such PVDF-based nanocomposite films. This article, therefore, highlights essential information about different electrospinning parameters which help to enhance the β phase in PVDF. The review then progresses into the recent developments and technological advances of electrospun PVDF-based nanocomposite devices in energy harvesting and sensing applications. The piezo-, pyro-, and triboelectric properties of PVDF allow the fabrication of conventional and hybrid nanogenerators. The later can harvest energy simultaneously from multiple sources, sense various fluctuations in their surroundings, and transmit the acquired data immediately when integrated with Bluetooth or wireless devices. They are fine models of self-powered, portable, multifunctional, and sustainable engineering. Finally, a peek into the other possible applications of electrospun PVDF-nanocomposite fibers is also made. Overall, the review aims to illustrate the innovative research and developments of PVDF fiber-based devices and the relevance and prospects they hold as future green sources of energy. [Display omitted]
AbstractList Modern-day requirements for efficient, eco-friendly, and self-powered devices have resulted in a growing interest in piezoelectric polymers among the scientific community. Polyvinylidene fluoride (PVDF) is an excellent electroactive polymer that is flexible, with high mechanical strength, thermal stability, and biocompatibility. The relatively low cost and easiness to be fabricated into thin pliable films made PVDF one of the most studied polymers for the development of nanogenerators and wearable sensors. The piezoelectric properties and therefore the energy harvesting and sensing capabilities of PVDF are distinct characteristics of its electroactive polar phases, especially the β phase. Hence, several PVDF-based nanocomposites that could achieve a high β phase fraction have been widely explored. Electrospinning is one of the best methods for manufacturing such PVDF-based nanocomposite films. This article, therefore, highlights essential Hybrid Hybrid Hybrid
Modern-day requirements for efficient, eco-friendly, and self-powered devices have resulted in a growing interest in piezoelectric polymers among the scientific community. Polyvinylidene fluoride (PVDF) is an excellent electroactive polymer that is flexible, with high mechanical strength, thermal stability, and biocompatibility. The relatively low cost and easiness to be fabricated into thin pliable films made PVDF one of the most studied polymers for the development of nanogenerators and wearable sensors. The piezoelectric properties and therefore the energy harvesting and sensing capabilities of PVDF are distinct characteristics of its electroactive polar phases, especially the β phase. Hence, several PVDF-based nanocomposites that could achieve a high β phase fraction have been widely explored. Electrospinning is one of the best methods for manufacturing such PVDF-based nanocomposite films. This article, therefore, highlights essential information about different electrospinning parameters which help to enhance the β phase in PVDF. The review then progresses into the recent developments and technological advances of electrospun PVDF-based nanocomposite devices in energy harvesting and sensing applications. The piezo-, pyro-, and triboelectric properties of PVDF allow the fabrication of conventional and hybrid nanogenerators. The later can harvest energy simultaneously from multiple sources, sense various fluctuations in their surroundings, and transmit the acquired data immediately when integrated with Bluetooth or wireless devices. They are fine models of self-powered, portable, multifunctional, and sustainable engineering. Finally, a peek into the other possible applications of electrospun PVDF-nanocomposite fibers is also made. Overall, the review aims to illustrate the innovative research and developments of PVDF fiber-based devices and the relevance and prospects they hold as future green sources of energy. [Display omitted]
ArticleNumber 126179
Author Rouxel, Didier
Royaud, Isabelle
Thomas, Sabu
Purushothaman, Sreelakshmi Moozhiyil
Tronco, Maïté Fernandes
Ponçot, Marc
Kalarikkal, Nandakumar
Kottathodi, Bicy
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  givenname: Maïté Fernandes
  surname: Tronco
  fullname: Tronco, Maïté Fernandes
  organization: Université de Lorraine, CNRS, IJL, F-54000, Nancy, France
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  givenname: Bicy
  surname: Kottathodi
  fullname: Kottathodi, Bicy
  organization: Université de Lorraine, CNRS, IJL, F-54000, Nancy, France
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  surname: Rouxel
  fullname: Rouxel, Didier
  email: didier.rouxel@univ-lorraine.fr
  organization: Université de Lorraine, CNRS, IJL, F-54000, Nancy, France
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Keywords Electrospinning
Piezoelectricity
Hybrid nanogenerators
PVDF-Nanocomposites
Triboelectricity
PVDF-Nanocomposites Electrospinning Piezoelectricity Triboelectricity Hybrid nanogenerators
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  text: 2023-09-22
  day: 22
PublicationDecade 2020
PublicationTitle Polymer (Guilford)
PublicationYear 2023
Publisher Elsevier Ltd
Elsevier
Publisher_xml – name: Elsevier Ltd
– name: Elsevier
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  publication-title: Nanoscale
  doi: 10.1039/c1nr10467e
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Snippet Modern-day requirements for efficient, eco-friendly, and self-powered devices have resulted in a growing interest in piezoelectric polymers among the...
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StartPage 126179
SubjectTerms Chemical Sciences
Electrospinning
Engineering Sciences
Hybrid nanogenerators
Materials
Mechanics
Mechanics of materials
Physics
Piezoelectricity
Polymers
PVDF-Nanocomposites
Triboelectricity
Title A review on electrospun PVDF-based nanocomposites: Recent trends and developments in energy harvesting and sensing applications
URI https://dx.doi.org/10.1016/j.polymer.2023.126179
https://hal.science/hal-04243721
Volume 283
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