Electronic structure and magnetic anisotropy design of functional metal complexes

[Display omitted] •Two chemically controllable parameters can assess the potential use of a magnetic material.•Coordination chemistry can be used to engineer functional magnetic materials.•Five types of magnetic functional materials are analysed.•The compatibility between different functionalities i...

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Vydané v:Coordination chemistry reviews Ročník 490; s. 215213
Hlavní autori: Raza, Arsen, Perfetti, Mauro
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Elsevier B.V 01.09.2023
Predmet:
Anisotropy switches
Electronic structure
Magnetic anisotropy
Magnetic refrigerants
Optically addressable qubits
Pseudo contact shift agents
Single molecule magnets
Single molecule magnets
Pseudo contact shift agents
Electronic structure
Anisotropy switches
Optically addressable qubits
Magnetic anisotropy
Magnetic refrigerants
ISSN:0010-8545, 1873-3840
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Shrnutí:[Display omitted] •Two chemically controllable parameters can assess the potential use of a magnetic material.•Coordination chemistry can be used to engineer functional magnetic materials.•Five types of magnetic functional materials are analysed.•The compatibility between different functionalities is discussed. Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy are of primary importance in physics, chemistry and biology. Our literature overview highlights that engineering the energy gap between the ground and first excited state and tailoring the magnetic anisotropy of paramagnetic molecules is an excellent starting point for boosting the performances of many molecular materials with emerging properties of technological relevance such as Single Molecule Magnets, Pseudo Contact Shift agents, Optically Addressable Qubits, Magnetic Refrigerants, and Magnetic Anisotropy Switches. We also discuss the compatibility between different functionalities.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2023.215213