Routes to high-performance layered oxide cathodes for sodium-ion batteries

Sodium-ion batteries (SIBs) are experiencing a large-scale renaissance to supplement or replace expensive lithium-ion batteries (LIBs) and low energy density lead-acid batteries in electrical energy storage systems and other applications. In this case, layered oxide materials have become one of the...

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Veröffentlicht in:Chemical Society reviews Jg. 53; H. 8; S. 4230
Hauptverfasser: Wang, Jingqiang, Zhu, Yan-Fang, Su, Yu, Guo, Jun-Xu, Chen, Shuangqiang, Liu, Hua-Kun, Dou, Shi-Xue, Chou, Shu-Lei, Xiao, Yao
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Veröffentlicht: England 22.04.2024
ISSN:1460-4744, 1460-4744
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Abstract Sodium-ion batteries (SIBs) are experiencing a large-scale renaissance to supplement or replace expensive lithium-ion batteries (LIBs) and low energy density lead-acid batteries in electrical energy storage systems and other applications. In this case, layered oxide materials have become one of the most popular cathode candidates for SIBs because of their low cost and comparatively facile synthesis method. However, the intrinsic shortcomings of layered oxide cathodes, which severely limit their commercialization process, urgently need to be addressed. In this review, inherent challenges associated with layered oxide cathodes for SIBs, such as their irreversible multiphase transition, poor air stability, and low energy density, are systematically summarized and discussed, together with strategies to overcome these dilemmas through bulk phase modulation, surface/interface modification, functional structure manipulation, and cationic and anionic redox optimization. Emphasis is placed on investigating variations in the chemical composition and structural configuration of layered oxide cathodes and how they affect the electrochemical behavior of the cathodes to illustrate how these issues can be addressed. The summary of failure mechanisms and corresponding modification strategies of layered oxide cathodes presented herein provides a valuable reference for scientific and practical issues related to the development of SIBs.
AbstractList Sodium-ion batteries (SIBs) are experiencing a large-scale renaissance to supplement or replace expensive lithium-ion batteries (LIBs) and low energy density lead-acid batteries in electrical energy storage systems and other applications. In this case, layered oxide materials have become one of the most popular cathode candidates for SIBs because of their low cost and comparatively facile synthesis method. However, the intrinsic shortcomings of layered oxide cathodes, which severely limit their commercialization process, urgently need to be addressed. In this review, inherent challenges associated with layered oxide cathodes for SIBs, such as their irreversible multiphase transition, poor air stability, and low energy density, are systematically summarized and discussed, together with strategies to overcome these dilemmas through bulk phase modulation, surface/interface modification, functional structure manipulation, and cationic and anionic redox optimization. Emphasis is placed on investigating variations in the chemical composition and structural configuration of layered oxide cathodes and how they affect the electrochemical behavior of the cathodes to illustrate how these issues can be addressed. The summary of failure mechanisms and corresponding modification strategies of layered oxide cathodes presented herein provides a valuable reference for scientific and practical issues related to the development of SIBs.Sodium-ion batteries (SIBs) are experiencing a large-scale renaissance to supplement or replace expensive lithium-ion batteries (LIBs) and low energy density lead-acid batteries in electrical energy storage systems and other applications. In this case, layered oxide materials have become one of the most popular cathode candidates for SIBs because of their low cost and comparatively facile synthesis method. However, the intrinsic shortcomings of layered oxide cathodes, which severely limit their commercialization process, urgently need to be addressed. In this review, inherent challenges associated with layered oxide cathodes for SIBs, such as their irreversible multiphase transition, poor air stability, and low energy density, are systematically summarized and discussed, together with strategies to overcome these dilemmas through bulk phase modulation, surface/interface modification, functional structure manipulation, and cationic and anionic redox optimization. Emphasis is placed on investigating variations in the chemical composition and structural configuration of layered oxide cathodes and how they affect the electrochemical behavior of the cathodes to illustrate how these issues can be addressed. The summary of failure mechanisms and corresponding modification strategies of layered oxide cathodes presented herein provides a valuable reference for scientific and practical issues related to the development of SIBs.
Sodium-ion batteries (SIBs) are experiencing a large-scale renaissance to supplement or replace expensive lithium-ion batteries (LIBs) and low energy density lead-acid batteries in electrical energy storage systems and other applications. In this case, layered oxide materials have become one of the most popular cathode candidates for SIBs because of their low cost and comparatively facile synthesis method. However, the intrinsic shortcomings of layered oxide cathodes, which severely limit their commercialization process, urgently need to be addressed. In this review, inherent challenges associated with layered oxide cathodes for SIBs, such as their irreversible multiphase transition, poor air stability, and low energy density, are systematically summarized and discussed, together with strategies to overcome these dilemmas through bulk phase modulation, surface/interface modification, functional structure manipulation, and cationic and anionic redox optimization. Emphasis is placed on investigating variations in the chemical composition and structural configuration of layered oxide cathodes and how they affect the electrochemical behavior of the cathodes to illustrate how these issues can be addressed. The summary of failure mechanisms and corresponding modification strategies of layered oxide cathodes presented herein provides a valuable reference for scientific and practical issues related to the development of SIBs.
Author Zhu, Yan-Fang
Guo, Jun-Xu
Su, Yu
Xiao, Yao
Wang, Jingqiang
Liu, Hua-Kun
Chou, Shu-Lei
Chen, Shuangqiang
Dou, Shi-Xue
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  surname: Wang
  fullname: Wang, Jingqiang
  email: yanfangzhu@wzu.edu.cn
  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
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  surname: Zhu
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  email: yanfangzhu@wzu.edu.cn
  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
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  givenname: Yu
  surname: Su
  fullname: Su, Yu
  email: yanfangzhu@wzu.edu.cn
  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
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  surname: Guo
  fullname: Guo, Jun-Xu
  email: yanfangzhu@wzu.edu.cn
  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
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  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
– sequence: 6
  givenname: Hua-Kun
  surname: Liu
  fullname: Liu, Hua-Kun
  organization: Institute of Energy Materials Science (IEMS), University of Shanghai for Science and Technology, Shanghai 200093, China
– sequence: 7
  givenname: Shi-Xue
  orcidid: 0000-0003-3824-7693
  surname: Dou
  fullname: Dou, Shi-Xue
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  orcidid: 0000-0003-1155-6082
  surname: Chou
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  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
– sequence: 9
  givenname: Yao
  orcidid: 0000-0002-5317-8799
  surname: Xiao
  fullname: Xiao, Yao
  email: yanfangzhu@wzu.edu.cn
  organization: Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou 325035, China
BackLink https://www.ncbi.nlm.nih.gov/pubmed/38477330$$D View this record in MEDLINE/PubMed
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