Activating a high-spin iron(II) complex to thermal spin-crossover with an inert non-isomorphous molecular dopant

[Fe(bpp) ][ClO ] (bpp = 2,6-bis{pyrazol-1-yl}pyridine; monoclinic, 2/ ) is high-spin between 5-300 K, and crystallises with a highly distorted molecular geometry that lies along the octahedral-trigonal prismatic distortion pathway. In contrast, [Ni(bpp) ][ClO ] (monoclinic, 2 ) adopts a more regular...

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Bibliographic Details

Published in:	Dalton transactions : an international journal of inorganic chemistry Vol. 53; no. 16; p. 6983
Main Authors:	Halcrow, Malcolm A, Vasili, Hari Babu, Pask, Christopher M, Kulak, Alexander N, Cespedes, Oscar
Format:	Journal Article
Language:	English
Published:	England 23.04.2024
ISSN:	1477-9234, 1477-9234
Online Access:	Get more information
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