Methoxy-substituted copper complexes as possible redox mediators in dye-sensitized solar cells
Three aromatic diimine ligands and the corresponding homoleptic copper(i) and copper(ii) complexes have been synthesized and characterized. The copper(ii) derivatives are stabilized by an ancillary chlorido ligand. The nature of the chelating ligand seriously impacts the photophysical and electroche...
Gespeichert in:
| Veröffentlicht in: | New journal of chemistry Jg. 45; H. 34; S. 15303 - 15311 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Journal Article |
| Sprache: | Englisch |
| Veröffentlicht: |
CAMBRIDGE
Royal Soc Chemistry
14.09.2021
|
| Schlagworte: | |
| ISSN: | 1144-0546, 1369-9261 |
| Online-Zugang: | Weitere Angaben |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Abstract | Three aromatic diimine ligands and the corresponding homoleptic copper(i) and copper(ii) complexes have been synthesized and characterized. The copper(ii) derivatives are stabilized by an ancillary chlorido ligand. The nature of the chelating ligand seriously impacts the photophysical and electrochemical properties of the complexes. The substitution of the pendant methyl groups with methoxy influences the coordination geometry of the complexes, resulting in an intramolecular dynamic equilibrium between different coordination modes (i.e. nitrogen and oxygen binding), proved by variable-temperature H-1-NMR measurements. As a proof of concept, the most promising complexes were employed as redox mediators in semi-transparent dye-sensitized solar cells. Once implemented in devices, the nature of the ligand plays a crucial role: the methoxy-substituted derivatives appear upon severe ligand exchange with tert-butylpyridine, resulting in an unexpectedly high open circuit voltage. |
|---|---|
| AbstractList | Three aromatic diimine ligands and the corresponding homoleptic copper(i) and copper(ii) complexes have been synthesized and characterized. The copper(ii) derivatives are stabilized by an ancillary chlorido ligand. The nature of the chelating ligand seriously impacts the photophysical and electrochemical properties of the complexes. The substitution of the pendant methyl groups with methoxy influences the coordination geometry of the complexes, resulting in an intramolecular dynamic equilibrium between different coordination modes (i.e. nitrogen and oxygen binding), proved by variable-temperature H-1-NMR measurements. As a proof of concept, the most promising complexes were employed as redox mediators in semi-transparent dye-sensitized solar cells. Once implemented in devices, the nature of the ligand plays a crucial role: the methoxy-substituted derivatives appear upon severe ligand exchange with tert-butylpyridine, resulting in an unexpectedly high open circuit voltage. |
| Author | Mariani, Paolo Bonomo, Matteo Viscardi, Guido Giordano, Marco Volpi, Giorgio Garino, Claudio |
| Author_xml | – sequence: 1 givenname: Marco surname: Giordano fullname: Giordano, Marco organization: Univ Turin, NIS Interdept Ctr, Dept Chem, Turin, Italy – sequence: 2 givenname: Giorgio orcidid: 0000-0002-9695-9202 surname: Volpi fullname: Volpi, Giorgio organization: Univ Turin, NIS Interdept Ctr, Dept Chem, Turin, Italy – sequence: 3 givenname: Matteo orcidid: 0000-0002-1944-2664 surname: Bonomo fullname: Bonomo, Matteo organization: Univ Turin, NIS Interdept Ctr, Dept Chem, Turin, Italy – sequence: 4 givenname: Paolo orcidid: 0000-0003-4491-2127 surname: Mariani fullname: Mariani, Paolo organization: Univ Roma Tor Vergata, CHOSE, Rome, Italy – sequence: 5 givenname: Claudio orcidid: 0000-0002-7854-6076 surname: Garino fullname: Garino, Claudio email: claudio.garino@unito.it organization: Univ Turin, NIS Interdept Ctr, Dept Chem, Turin, Italy – sequence: 6 givenname: Guido orcidid: 0000-0002-9387-2849 surname: Viscardi fullname: Viscardi, Guido organization: Univ Turin, NIS Interdept Ctr, Dept Chem, Turin, Italy |
| BookMark | eNqNjs1KxDAURoOM4Di68Qmyl2jStEm6lOIfjLjRrUOa3mCGTlJ6Mzjj0xvQB3B1zuZ8fOdkEVMEQq4EvxFctreDiFteNVrDCVkKqVrWVkosiou6Zryp1Rk5R9xyLoRWYkk-XiB_psOR4b7HHPI-w0BdmiaYC3bTCAdAapFOCTH0I9AZhnSgOxiCzWlGGiIdjsAQIoYcvkuOabSlhnHEC3Lq7Yhw-ccVeX-4f-ue2Pr18bm7WzMnhc7M-1Za8KaFchO8Vtbo2gsvQEuplBqktsYZ0xvVNI47MJZXnntdN6KpfVWtiPnd_YI-eXQBooPNNIednY8bzrky3GjVFuOiC9nmkGKX9jGX9Pr_afUDiwltpA |
| CitedBy_id | crossref_primary_10_1021_acsaem_5c00998 crossref_primary_10_1016_j_jlumin_2021_118529 crossref_primary_10_3390_molecules29030653 crossref_primary_10_3390_polym14101998 crossref_primary_10_3390_molecules28093703 crossref_primary_10_3390_molecules29112668 crossref_primary_10_1002_ajoc_202200171 crossref_primary_10_1039_D1SC06828H crossref_primary_10_1016_j_mcat_2025_115083 crossref_primary_10_1039_D5TC01530H crossref_primary_10_3390_molecules26237161 crossref_primary_10_1039_D5SC03537F crossref_primary_10_1002_slct_202501972 crossref_primary_10_1002_adfm_202411230 crossref_primary_10_1016_j_cattod_2024_114876 crossref_primary_10_1016_j_dyepig_2023_111482 crossref_primary_10_1016_j_inoche_2025_114952 crossref_primary_10_1016_j_ica_2022_120849 |
| Cites_doi | 10.1039/c8cc07191h 10.1080/00958972.2018.1509070 10.1039/c6dt00970k 10.1021/cr050193e 10.1021/cr1003419 10.1016/j.ccr.2013.02.027 10.1016/j.dyepig.2019.107713 10.1021/acs.jpcc.6b01020 10.1039/c6ta06782d 10.1002/anie.201201471 10.1016/j.electacta.2016.12.185 10.1021/ja413098m 10.1021/jacs.6b10721 10.1016/j.orgel.2018.11.032 10.1021/acsami.9b19119 10.1021/acsaem.7b00196 10.1039/c0cs00114g 10.1016/j.ccr.2018.05.010 10.1021/am503306f 10.1039/d1nj00322d 10.3390/molecules26010194 10.1039/c2ee23081j 10.1002/pssb.201900677 10.1039/c5cs00215j 10.1021/om701175z 10.1039/d0gc01148g 10.1002/chem.200801474 10.1039/c5ee01204j 10.1038/ncomms15390 10.1021/cr300503r 10.1021/ja0506814 10.1039/c8tc03542c 10.1016/j.ccr.2017.09.011 10.1021/acs.inorgchem.6b00204 10.1016/j.dyepig.2021.109455 10.1039/c9dt00790c 10.1002/pip.1166 10.1021/cr900356p 10.1021/cr020630e 10.1021/acs.jpcc.0c00671 10.3390/inorganics7030030 10.1016/j.ccr.2012.09.008 10.1021/jo402084m 10.1021/acs.jpcc.6b01658 10.1016/j.poly.2017.11.048 10.1016/j.ica.2010.06.011 10.1016/j.electacta.2014.07.086 10.1016/j.ica.2020.119662 |
| ContentType | Journal Article |
| DBID | 17B 1KM BLEPL DTL EGQ HGBXW |
| DOI | 10.1039/d1nj02577e |
| DatabaseName | Web of Knowledge Index Chemicus Web of Science Core Collection Science Citation Index Expanded Web of Science Primary (SCIE, SSCI & AHCI) Web of Science - Science Citation Index Expanded - 2021 |
| DatabaseTitle | Web of Science |
| DatabaseTitleList | Web of Science |
| Database_xml | – sequence: 1 dbid: 1KM name: Index Chemicus url: https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.IC sourceTypes: Enrichment Source Index Database |
| DeliveryMethod | no_fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1369-9261 |
| EndPage | 15311 |
| ExternalDocumentID | 000680876900001 |
| GrantInformation_xml | – fundername: European Union; European Union (EU) grantid: 826013 |
| GroupedDBID | --- -DZ -~X 0-7 0R~ 123 17B 1KM 29N 2WC 4.4 705 70~ 7~J AAEMU AAFBY AAIWI AAJAE AAMEH AANOJ AAWGC AAXHV AAXPP ABASK ABCQX ABDVN ABEMK ABJNI ABPDG ABRYZ ABUFD ABXOH ACGFS ACIWK ACLDK ACNCT ADMRA ADSRN AEFDR AENEX AENGV AESAV AETIL AFLYV AFOGI AFRDS AFRZK AFVBQ AGEGJ AGKEF AGMRB AGRSR AHGCF AKMSF ALMA_UNASSIGNED_HOLDINGS ALUYA ANUXI APEMP ASKNT AUDPV AZFZN BLAPV BLEPL BSQNT C6K CS3 D0L DTL DU5 EBS ECGLT EE0 EF- F5P GGIMP GNO GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED GROUPED_WOS_WEB_OF_SCIENCE H13 HZ~ H~N IDZ J3I L7B M4U N9A O9- P2P R56 R7B R7C R7D RAOCF RCNCU RNS RPMJG RRA RRC RSCEA SKA SKF SKH SLH TN5 TWZ VH6 YNT YQT |
| ID | FETCH-LOGICAL-c317t-ff93aef89e144ef76a874f1f1e733666d37a8c88b8655c0ce8a02f0f745154f22 |
| ISICitedReferencesCount | 23 |
| ISICitedReferencesURI | https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000680876900001 |
| ISSN | 1144-0546 |
| IngestDate | Wed Nov 05 08:44:35 EST 2025 Fri Dec 05 22:42:35 EST 2025 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 34 |
| Keywords | ELECTRON-TRANSFER TRANSITION-METAL-COMPLEXES LIGANDS PHENANTHROLINE COUPLE LIGHT COORDINATION MODEL COMPLEXES CHARGE-TRANSFER |
| Language | English |
| LinkModel | OpenURL |
| LogoURL | https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg |
| MergedId | FETCHMERGED-LOGICAL-c317t-ff93aef89e144ef76a874f1f1e733666d37a8c88b8655c0ce8a02f0f745154f22 |
| ORCID | 0000-0002-9695-9202 0000-0002-9387-2849 0000-0002-7854-6076 0000-0003-4491-2127 0000-0002-1944-2664 |
| OpenAccessLink | http://hdl.handle.net/2318/1801005 |
| PageCount | 9 |
| ParticipantIDs | webofscience_primary_000680876900001CitationCount webofscience_primary_000680876900001 |
| PublicationCentury | 2000 |
| PublicationDate | 2021-09-14 |
| PublicationDateYYYYMMDD | 2021-09-14 |
| PublicationDate_xml | – month: 09 year: 2021 text: 2021-09-14 day: 14 |
| PublicationDecade | 2020 |
| PublicationPlace | CAMBRIDGE |
| PublicationPlace_xml | – name: CAMBRIDGE |
| PublicationTitle | New journal of chemistry |
| PublicationTitleAbbrev | NEW J CHEM |
| PublicationYear | 2021 |
| Publisher | Royal Soc Chemistry |
| Publisher_xml | – name: Royal Soc Chemistry |
| References | Prier, CK (WOS:000321810600018) 2013; 113 Dragonetti, C (WOS:000473920400026) 2019; 48 Volpi, G (WOS:000484870700056) 2019; 171 Dragonetti, C (WOS:000458705100065) 2018; 1 Bizzarri, C (WOS:000443785600004) 2018; 373 Cao, YM (WOS:000402959800001) 2017; 8 Freitag, M (WOS:000375969000007) 2016; 120 Kannankutty, K (WOS:000512216900060) 2020; 12 Zhao, Q (WOS:000289630700030) 2011; 40 Freitag, M (WOS:000360456600006) 2015; 8 Mariotti, N (WOS:000583614600032) 2020; 22 Magni, M (WOS:000343022900043) 2014; 141 NAZEERUDDIN, MK (WOS:A1993LT17300063) 1993; 115 Hoffeditz, WL (WOS:000371104400018) 2016; 120 Magni, M (WOS:000377151000022) 2016; 55 Ilmi, R (WOS:000456343200002) 2018; 71 Saygili, Y (WOS:000464287600004) 2019; 7 Singh, A (WOS:000323593600013) 2013; 257 Wang, YJ (WOS:000448823200017) 2018; 54 Blanco-Rodríguez, AM (WOS:000335086100032) 2014; 136 VIG, JR (WOS:A1985AKX4900160) 1985; 3 Volpi, G (WOS:000632977700001) 2021; 45 Albrecht, G (WOS:000453572400043) 2019; 65 Saygili, Y (WOS:000388428200040) 2016; 138 Wang, MK (WOS:000310006200018) 2012; 5 Liao, LY (WOS:000330099000031) 2014; 79 Saygili, Y (WOS:000526328500012) 2020; 124 Salassa, L (WOS:000254565900011) 2008; 27 Hagfeldt, A (WOS:000284134300006) 2010; 110 Vesce, L (WOS:000311419300006) 2012; 20 Albrecht, G (WOS:000509613600001) 2020; 257 Fresta, E (WOS:000424185400017) 2018; 140 Costa, RD (WOS:000307215900007) 2012; 51 Housecroft, CE (WOS:000364853400001) 2015; 44 Bignozzi, CA (WOS:000316518900004) 2013; 257 Hattori, S (WOS:000230220900068) 2005; 127 Benesperi, I (WOS:000450436300009) 2018; 6 Weber, MD (WOS:000377920900037) 2016; 45 KARLIN, KD (WOS:A1984SP63700003) 1984; 23 Kavan, L (WOS:000394399600023) 2017; 227 Esswein, AJ (WOS:000249839900006) 2007; 107 Rorabacher, DB (WOS:000188934400012) 2004; 104 Liu, YR (WOS:000446283200025) 2018; 375 Klein, A (WOS:000282677800021) 2010; 363 Colombo, A (WOS:000606669600001) 2021; 26 KITAGAWA, S (WOS:A1984SN01800017) 1984; 84 Colombo, A (WOS:000341122000077) 2014; 6 Volpi, G (WOS:000541486700009) 2020; 509 Cong, JY (WOS:000385360300005) 2016; 4 Volpi, G (WOS:000267721500015) 2009; 15 Volpi, G (WOS:000660302400003) 2021; 192 TIECCO, M (WOS:A1984TL57800007) 1984 Nozik, AJ (WOS:000284134300001) 2010; 110 |
| References_xml | – volume: 54 start-page: 12361 year: 2018 ident: WOS:000448823200017 article-title: Improved performance induced by in situ ligand exchange reactions of copper bipyridyl redox couples in dye- sensitized solar cells publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/c8cc07191h – volume: 84 start-page: 79 year: 1984 ident: WOS:A1984SN01800017 article-title: AUTOREDUCTION OF COPPER(II) COMPLEXES OF 6,6'-DIALKYL-2,2'-BIPYRIDINE AND CHARACTERIZATION OF THEIR COPPER(I) COMPLEXES publication-title: INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS – volume: 71 start-page: 3045 year: 2018 ident: WOS:000456343200002 article-title: Recent progress in coordination chemistry, photo-physical properties, and applications of pyridine-based Cu(I) complexes publication-title: JOURNAL OF COORDINATION CHEMISTRY doi: 10.1080/00958972.2018.1509070 – volume: 45 start-page: 8984 year: 2016 ident: WOS:000377920900037 article-title: Origin of a counterintuitive yellow light-emitting electrochemical cell based on a blue-emitting heteroleptic copper(I) complex publication-title: DALTON TRANSACTIONS doi: 10.1039/c6dt00970k – volume: 107 start-page: 4022 year: 2007 ident: WOS:000249839900006 article-title: Hydrogen production by molecular photocatalysis publication-title: CHEMICAL REVIEWS doi: 10.1021/cr050193e – volume: 23 start-page: 1184 year: 1984 ident: WOS:A1984SP63700003 article-title: REDOX BEHAVIOR OF BLUE COPPER MODEL COMPLEXES - REDOX POTENTIALS AND ELECTRON-TRANSFER KINETICS OF SOME COPPER(II) COPPER(I) COMPLEXES WITH NITROGEN AND THIOETHER DONORS publication-title: INORGANIC CHEMISTRY – volume: 110 start-page: 6443 year: 2010 ident: WOS:000284134300001 article-title: Introduction to Solar Photon Conversion publication-title: CHEMICAL REVIEWS doi: 10.1021/cr1003419 – volume: 257 start-page: 2607 year: 2013 ident: WOS:000323593600013 article-title: Water oxidation catalysts based on abundant 1st row transition metals publication-title: COORDINATION CHEMISTRY REVIEWS doi: 10.1016/j.ccr.2013.02.027 – volume: 171 start-page: ARTN 107713 year: 2019 ident: WOS:000484870700056 article-title: Halogenated imidazo[1,5-α]pyridines: chemical structure and optical properties of a promising luminescent scaffold publication-title: DYES AND PIGMENTS doi: 10.1016/j.dyepig.2019.107713 – volume: 120 start-page: 3731 year: 2016 ident: WOS:000371104400018 article-title: One Electron Changes Everything. A Multispecies Copper Redox Shuttle for Dye-Sensitized Solar Cells publication-title: JOURNAL OF PHYSICAL CHEMISTRY C doi: 10.1021/acs.jpcc.6b01020 – volume: 4 start-page: 14550 year: 2016 ident: WOS:000385360300005 article-title: Bis(1,1-bis(2-pyridyl)ethane)copper(I/II) as an efficient redox couple for liquid dye-sensitized solar cells publication-title: JOURNAL OF MATERIALS CHEMISTRY A doi: 10.1039/c6ta06782d – volume: 51 start-page: 8178 year: 2012 ident: WOS:000307215900007 article-title: Luminescent Ionic Transition-Metal Complexes for Light-Emitting Electrochemical Cells publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201201471 – volume: 227 start-page: 194 year: 2017 ident: WOS:000394399600023 article-title: Electrochemical Properties of Cu(II/I)-Based Redox Mediators for Dye-Sensitized Solar Cells publication-title: ELECTROCHIMICA ACTA doi: 10.1016/j.electacta.2016.12.185 – volume: 136 start-page: 5963 year: 2014 ident: WOS:000335086100032 article-title: Photophysics of Singlet and Triplet Intraligand Excited States in [ReCl(CO)3(1-(2-pyridyl)-imidazo[1,5-α]pyridine)] Complexes publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja413098m – volume: 138 start-page: 15087 year: 2016 ident: WOS:000388428200040 article-title: Copper Bipyridyl Redox Mediators for Dye-Sensitized Solar Cells with High Photovoltage publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.6b10721 – volume: 65 start-page: 321 year: 2019 ident: WOS:000453572400043 article-title: Electroluminescence and contact formation of 1-(pyridin-2-yl)-3-(quinolin-2-yl)imidazo [1,5-a] quinoline thin films publication-title: ORGANIC ELECTRONICS doi: 10.1016/j.orgel.2018.11.032 – volume: 12 start-page: 5812 year: 2020 ident: WOS:000512216900060 article-title: tert-Butylpyridine Coordination with [Cu(dmp)2]2+/+ Redox Couple and Its Connection to the Stability of the Dye-Sensitized Solar Cell publication-title: ACS APPLIED MATERIALS & INTERFACES doi: 10.1021/acsami.9b19119 – volume: 1 start-page: 751 year: 2018 ident: WOS:000458705100065 article-title: Coupling of a Copper Dye with a Copper Electrolyte: A Fascinating Springboard for Sustainable Dye-Sensitized Solar Cells publication-title: ACS APPLIED ENERGY MATERIALS doi: 10.1021/acsaem.7b00196 – volume: 40 start-page: 2508 year: 2011 ident: WOS:000289630700030 article-title: Phosphorescent heavy-metal complexes for bioimaging publication-title: CHEMICAL SOCIETY REVIEWS doi: 10.1039/c0cs00114g – volume: 375 start-page: 514 year: 2018 ident: WOS:000446283200025 article-title: Recent advances in copper complexes for electrical/light energy conversion publication-title: COORDINATION CHEMISTRY REVIEWS doi: 10.1016/j.ccr.2018.05.010 – volume: 6 start-page: 13945 year: 2014 ident: WOS:000341122000077 article-title: Efficient Copper Mediators Based on Bulky Asymmetric Phenanthrolines for DSSCs publication-title: ACS APPLIED MATERIALS & INTERFACES doi: 10.1021/am503306f – volume: 3 start-page: 1027 year: 1985 ident: WOS:A1985AKX4900160 article-title: UV OZONE CLEANING OF SURFACES publication-title: JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS – volume: 45 start-page: 5737 year: 2021 ident: WOS:000632977700001 article-title: Imidazo[1,5-a]pyridine derivatives: useful, luminescent and versatile scaffolds for different applications publication-title: NEW JOURNAL OF CHEMISTRY doi: 10.1039/d1nj00322d – volume: 26 start-page: ARTN 194 year: 2021 ident: WOS:000606669600001 article-title: Copper Complexes as Alternative Redox Mediators in Dye-Sensitized Solar Cells publication-title: MOLECULES doi: 10.3390/molecules26010194 – volume: 5 start-page: 9394 year: 2012 ident: WOS:000310006200018 article-title: Recent developments in redox electrolytes for dye-sensitized solar cells publication-title: ENERGY & ENVIRONMENTAL SCIENCE doi: 10.1039/c2ee23081j – volume: 257 start-page: ARTN 1900677 year: 2020 ident: WOS:000509613600001 article-title: Optimization of the Substitution Pattern of 1,3-Disubstituted Imidazo[1,5-a]Pyridines and -Quinolines for Electro-Optical Applications publication-title: PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS doi: 10.1002/pssb.201900677 – volume: 44 start-page: 8386 year: 2015 ident: WOS:000364853400001 article-title: The emergence of copper(I)-based dye sensitized solar cells publication-title: CHEMICAL SOCIETY REVIEWS doi: 10.1039/c5cs00215j – volume: 27 start-page: 1427 year: 2008 ident: WOS:000254565900011 article-title: Computational and spectroscopic studies of new rhenium(I) complexes containing pyridylimidazo[1,5-a]pyridine ligands:: Charge transfer and dual emission by fine-tuning of excited states publication-title: ORGANOMETALLICS doi: 10.1021/om701175z – volume: 22 start-page: 7168 year: 2020 ident: WOS:000583614600032 article-title: Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells publication-title: GREEN CHEMISTRY doi: 10.1039/d0gc01148g – volume: 15 start-page: 6415 year: 2009 ident: WOS:000267721500015 article-title: Cationic Heteroleptic Cyclometalated Iridium Complexes with 1-Pyridylimidazo[1,5-α]pyridine Ligands: Exploitation of an Efficient Intersystem Crossing publication-title: CHEMISTRY-A EUROPEAN JOURNAL doi: 10.1002/chem.200801474 – volume: 8 start-page: 2634 year: 2015 ident: WOS:000360456600006 article-title: High-efficiency dye-sensitized solar cells with molecular copper phenanthroline as solid hole conductor publication-title: ENERGY & ENVIRONMENTAL SCIENCE doi: 10.1039/c5ee01204j – volume: 8 start-page: ARTN 15390 year: 2017 ident: WOS:000402959800001 article-title: 11% efficiency solid-state dye-sensitized solar cells with copper(II/I) hole transport materials publication-title: NATURE COMMUNICATIONS doi: 10.1038/ncomms15390 – volume: 113 start-page: 5322 year: 2013 ident: WOS:000321810600018 article-title: Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis publication-title: CHEMICAL REVIEWS doi: 10.1021/cr300503r – volume: 127 start-page: 9648 year: 2005 ident: WOS:000230220900068 article-title: Blue copper model complexes with distorted tetragonal geometry acting as effective electron-transfer mediators in dye-sensitized solar cells publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0506814 – volume: 6 start-page: 11903 year: 2018 ident: WOS:000450436300009 article-title: The researcher's guide to solid-state dye-sensitized solar cells publication-title: JOURNAL OF MATERIALS CHEMISTRY C doi: 10.1039/c8tc03542c – volume: 373 start-page: 49 year: 2018 ident: WOS:000443785600004 article-title: Sustainable metal complexes for organic light-emitting diodes (OLEDs) publication-title: COORDINATION CHEMISTRY REVIEWS doi: 10.1016/j.ccr.2017.09.011 – volume: 55 start-page: 5245 year: 2016 ident: WOS:000377151000022 article-title: Tetracoordinated Bis-phenanthroline Copper-Complex Couple as Efficient Redox Mediators for Dye Solar Cells publication-title: INORGANIC CHEMISTRY doi: 10.1021/acs.inorgchem.6b00204 – volume: 192 start-page: ARTN 109455 year: 2021 ident: WOS:000660302400003 article-title: Strategies to increase the quantum yield: Luminescent methoxylated imidazo[1,5-a]pyridines publication-title: DYES AND PIGMENTS doi: 10.1016/j.dyepig.2021.109455 – start-page: 736 year: 1984 ident: WOS:A1984TL57800007 article-title: A CONVENIENT SYNTHESIS OF BIPYRIDINES BY NICKEL-PHOSPHINE COMPLEX-MEDIATED HOMO COUPLING OF HALOPYRIDINES publication-title: SYNTHESIS-STUTTGART – volume: 48 start-page: 9703 year: 2019 ident: WOS:000473920400026 article-title: Towards efficient sustainable full-copper dye-sensitized solar cells publication-title: DALTON TRANSACTIONS doi: 10.1039/c9dt00790c – volume: 20 start-page: 960 year: 2012 ident: WOS:000311419300006 article-title: Processing and characterization of a TiO2 paste based on small particle size powders for dye-sensitized solar cell semi-transparent photo-electrodes publication-title: PROGRESS IN PHOTOVOLTAICS doi: 10.1002/pip.1166 – volume: 110 start-page: 6595 year: 2010 ident: WOS:000284134300006 article-title: Dye-Sensitized Solar Cells publication-title: CHEMICAL REVIEWS doi: 10.1021/cr900356p – volume: 104 start-page: 651 year: 2004 ident: WOS:000188934400012 article-title: Electron transfer by copper centers publication-title: CHEMICAL REVIEWS doi: 10.1021/cr020630e – volume: 124 start-page: 7071 year: 2020 ident: WOS:000526328500012 article-title: Liquid State and Zombie Dye Sensitized Solar Cells with Copper Bipyridine Complexes Functionalized with Alkoxy Groups publication-title: JOURNAL OF PHYSICAL CHEMISTRY C doi: 10.1021/acs.jpcc.0c00671 – volume: 7 start-page: ARTN 30 year: 2019 ident: WOS:000464287600004 article-title: Metal Coordination Complexes as Redox Mediators in Regenerative Dye-Sensitized Solar Cells publication-title: INORGANICS doi: 10.3390/inorganics7030030 – volume: 257 start-page: 1472 year: 2013 ident: WOS:000316518900004 article-title: The role of transition metal complexes in dye sensitized solar devices publication-title: COORDINATION CHEMISTRY REVIEWS doi: 10.1016/j.ccr.2012.09.008 – volume: 79 start-page: 777 year: 2014 ident: WOS:000330099000031 article-title: Reductive Couplings of 2-Halopyridines without External Ligand: Phosphine-Free Nickel-Catalyzed Synthesis of Symmetrical and Unsymmetrical 2,2′-Bipyridines publication-title: JOURNAL OF ORGANIC CHEMISTRY doi: 10.1021/jo402084m – volume: 120 start-page: 9595 year: 2016 ident: WOS:000375969000007 article-title: Copper Phenanthroline as a Fast and High-Performance Redox Mediator for Dye-Sensitized Solar Cells publication-title: JOURNAL OF PHYSICAL CHEMISTRY C doi: 10.1021/acs.jpcc.6b01658 – volume: 115 start-page: 6382 year: 1993 ident: WOS:A1993LT17300063 article-title: CONVERSION OF LIGHT TO ELECTRICITY BY CIS-X2BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)RUTHENIUM(II) CHARGE-TRANSFER SENSITIZERS (X = CL-, BR-, I-, CN-, AND SCN-) ON NANOCRYSTALLINE TIO2 ELECTRODES publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 140 start-page: 129 year: 2018 ident: WOS:000424185400017 article-title: Contextualizing yellow light-emitting electrochemical cells based on a blue-emitting imidazo-pyridine emitterd publication-title: POLYHEDRON doi: 10.1016/j.poly.2017.11.048 – volume: 363 start-page: 3282 year: 2010 ident: WOS:000282677800021 article-title: Electron transfer studies on Cu(II) complexes bearing phenoxy-pincer ligands publication-title: INORGANICA CHIMICA ACTA doi: 10.1016/j.ica.2010.06.011 – volume: 141 start-page: 324 year: 2014 ident: WOS:000343022900043 article-title: Steric vs electronic effects and solvent coordination in the electrochemistry of phenanthroline-based copper complexes publication-title: ELECTROCHIMICA ACTA doi: 10.1016/j.electacta.2014.07.086 – volume: 509 start-page: ARTN 119662 year: 2020 ident: WOS:000541486700009 article-title: Blue fluorescent zinc(II) complexes based on tunable imidazo[1,5-a ] pyridines publication-title: INORGANICA CHIMICA ACTA doi: 10.1016/j.ica.2020.119662 |
| SSID | ssj0011761 |
| Score | 2.450395 |
| Snippet | Three aromatic diimine ligands and the corresponding homoleptic copper(i) and copper(ii) complexes have been synthesized and characterized. The copper(ii)... |
| Source | Web of Science |
| SourceID | webofscience |
| SourceType | Enrichment Source Index Database |
| StartPage | 15303 |
| SubjectTerms | Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology |
| Title | Methoxy-substituted copper complexes as possible redox mediators in dye-sensitized solar cells |
| URI | http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000680876900001 |
| Volume | 45 |
| WOS | 000680876900001 |
| WOSCitedRecordID | wos000680876900001 |
| hasFullText | |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9QwELa2gAQXxFOUl3zoDUXESTa2j7ACIUErJErVE5Xj2CjVKomaqEr5Y_17nbETb1p6WA5cot1Zb7LJfDsej2e-IWQvLZReilxGSmVL3GZUkRAmi3RRFiUSShWujvvoGz84EMfH8vticTnVwpyveV2LYZDtf1U1yEDZWDr7D-oOJwUBvAalwxHUDsetFL-PPaGHi6gDk-DzALBwrW3Nmc8fN4PpsLtM2-DfYY1tU8pm8CUkrvUO5sdemKjD1Pa--mMwsI65qhjj7-bOLOZGzpgn9NQ7LuT0VLCyVa63N9YE6Wb64KhZty6LAEf8roL8I1ZYjMP73gQ5fLnyvafA4wVrPQ9VJAzzKtgmVOkDIj8a_W517Qd5ywsruwj8x5EX28tSAJFMPFv7ZK49--QIyzEQ6o0vGO84nc3k8N4b8r-miThFltWS1afg8nFuNpPhlABwY44MmYuxb1bCc-n2RXbIDs-xYwj7uh82rxj3NL3THU2suKl8v7nkrY6Oc2oOH5GH42qEfvAoekwWpn5C7ofn9pT8ugVN1KOJBjRR1dEJTdShiQY00aqm19FEHZqoQ9Mz8vPzp8PVl2hsyRFpcDT7yFqZKmOFNHBzxvJcCZ5ZZplBWs08L1OuhBaiwHpnHWsjVJzY2PIM_ObMJslzcqduavOC0CTLDayVpV1KLG7OFAOzIVWuZKKQ02iX7M0f0Enr2VdObmhgl7Bthq1GxntkeuhfbnfqV-TBBsWvyV0LFsK8Iff0eV91Z2-d0q8AKaaPfQ |
| linkProvider | Clarivate |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Methoxy-substituted+copper+complexes+as+possible+redox+mediators+in+dye-sensitized+solar+cells&rft.jtitle=New+journal+of+chemistry&rft.au=Giordano%2C+Marco&rft.au=Volpi%2C+Giorgio&rft.au=Bonomo%2C+Matteo&rft.au=Mariani%2C+Paolo&rft.date=2021-09-14&rft.pub=Royal+Soc+Chemistry&rft.issn=1144-0546&rft.eissn=1369-9261&rft.volume=45&rft.issue=34&rft.spage=15303&rft.epage=15311&rft_id=info:doi/10.1039%2Fd1nj02577e&rft.externalDBID=n%2Fa&rft.externalDocID=000680876900001 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1144-0546&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1144-0546&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1144-0546&client=summon |