Photocatalyst‐Free Visible‐Light Induced Radical Difluoromethylation/Cyclization Cascade Reaction for the Synthesis of Difluoromethylated Oxindoles with Difluoromethyl Phenoxathiinium Salt

A photocatalyst‐free photoinduced radical difluoromethylation approach for the convenient synthesis of difluoromethylated oxindoles from N‐arylacrylamides with difluoromethyl phenoxathiinium salt (PT‐CF2H+BF4−) was developed, this transformation involves radical difluoromethylation/cyclization casca...

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Bibliographic Details
Published in:	European journal of organic chemistry Vol. 27; no. 48
Main Authors:	Long, Hong‐Xin, Liu, Guo‐Kai
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 23.12.2024 Wiley Subscription Services, Inc
Subjects:	Cascade chemical reactions Cascade reaction Chemical synthesis Chemistry Chemistry, Organic Functional groups Oxindole Photocatalyst-free Photocatalysts Physical Sciences Radical difluoromethylation Science & Technology Cascade reaction Oxindole Radical difluoromethylation DESIGN PHARMACEUTICALS N-ARYLACRYLAMIDES BIOISOSTERES FLUORINATED 3,3-DISUBSTITUTED 2-OXINDOLES Photocatalyst-free CATALYST CYCLIZATION
ISSN:	1434-193X, 1099-0690
Online Access:	Get full text
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