Progress of Prussian Blue and Its Analogues as Cathode Materials for Potassium Ion Batteries

Environmental pollution and the energy crisis have promoted the development of clean energy as well as new‐generation energy storage systems. Potassium ion batteries (PIBs) have emerged as a possible alternative to lithium‐ion batteries due to their abundant reserves, low cost, and impressive electr...

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Published in:European journal of inorganic chemistry Vol. 26; no. 25
Main Authors: Bai, Yue, YuChi, Ke'er, Liu, Xu, Tian, Shinuo, Yang, Shujie, Qian, Xi, Ma, Bin, Fang, Minghao, Liu, Yan'gai, Huang, Zhaohui, Min, Xin
Format: Journal Article
Language:English
Published: Weinheim Wiley Subscription Services, Inc 01.09.2023
Subjects:
Cathode materials
Cathodes
Clean energy
Composition
Doping
Electrochemical analysis
Electrode materials
Energy storage
Inorganic chemistry
Ion storage
Lithium-ion batteries
Materials science
Optimization
Pigments
Potassium
Potassium ion batteries
Prussian blue analogues
Storage systems
Transition metals
ISSN:1434-1948, 1099-0682
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Abstract Environmental pollution and the energy crisis have promoted the development of clean energy as well as new‐generation energy storage systems. Potassium ion batteries (PIBs) have emerged as a possible alternative to lithium‐ion batteries due to their abundant reserves, low cost, and impressive electrochemical performance. However, the search for suitable cathode materials has become particularly crucial. Recently, Prussian blue (PB) has been investigated as a potential cathode material for PIBs, which has an open three‐dimensional framework to accommodate a large volume of potassium ions and adjustable composition for different applications. In this review, Prussian blue and its analogues (PBAs) and their application in PIBs were summarized detailly. We presented the composition, structure, potassium ion storage mechanism, preparation process of PBAs, and then focus on the performance optimization methods of the PBAs, including transition metal doping and conductive material adding into PBAs. Finally, the challenges as well as the outlook on the future development of PBAs were proposed for further application in this battery system. In potassium ion batteries with Prussian blue and its analogs as cathodes, the performance of the batteries can be optimized by various pairs of methods. These include improving the preparation process, doping with a variety of transition metals, and compounding with conductive materials. The enhancement of performance helps to promote the large‐scale application of potassium ion batteries.
AbstractList Environmental pollution and the energy crisis have promoted the development of clean energy as well as new‐generation energy storage systems. Potassium ion batteries (PIBs) have emerged as a possible alternative to lithium‐ion batteries due to their abundant reserves, low cost, and impressive electrochemical performance. However, the search for suitable cathode materials has become particularly crucial. Recently, Prussian blue (PB) has been investigated as a potential cathode material for PIBs, which has an open three‐dimensional framework to accommodate a large volume of potassium ions and adjustable composition for different applications. In this review, Prussian blue and its analogues (PBAs) and their application in PIBs were summarized detailly. We presented the composition, structure, potassium ion storage mechanism, preparation process of PBAs, and then focus on the performance optimization methods of the PBAs, including transition metal doping and conductive material adding into PBAs. Finally, the challenges as well as the outlook on the future development of PBAs were proposed for further application in this battery system.
Environmental pollution and the energy crisis have promoted the development of clean energy as well as new‐generation energy storage systems. Potassium ion batteries (PIBs) have emerged as a possible alternative to lithium‐ion batteries due to their abundant reserves, low cost, and impressive electrochemical performance. However, the search for suitable cathode materials has become particularly crucial. Recently, Prussian blue (PB) has been investigated as a potential cathode material for PIBs, which has an open three‐dimensional framework to accommodate a large volume of potassium ions and adjustable composition for different applications. In this review, Prussian blue and its analogues (PBAs) and their application in PIBs were summarized detailly. We presented the composition, structure, potassium ion storage mechanism, preparation process of PBAs, and then focus on the performance optimization methods of the PBAs, including transition metal doping and conductive material adding into PBAs. Finally, the challenges as well as the outlook on the future development of PBAs were proposed for further application in this battery system. In potassium ion batteries with Prussian blue and its analogs as cathodes, the performance of the batteries can be optimized by various pairs of methods. These include improving the preparation process, doping with a variety of transition metals, and compounding with conductive materials. The enhancement of performance helps to promote the large‐scale application of potassium ion batteries.
Author Tian, Shinuo
Fang, Minghao
Liu, Xu
Yang, Shujie
Liu, Yan'gai
Bai, Yue
YuChi, Ke'er
Qian, Xi
Ma, Bin
Min, Xin
Huang, Zhaohui
Author_xml – sequence: 1
  givenname: Yue
  surname: Bai
  fullname: Bai, Yue
  organization: China University of Geosciences (Beijing)
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  givenname: Ke'er
  surname: YuChi
  fullname: YuChi, Ke'er
  organization: China University of Geosciences (Beijing)
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  givenname: Xu
  surname: Liu
  fullname: Liu, Xu
  organization: China University of Geosciences (Beijing)
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  givenname: Shinuo
  surname: Tian
  fullname: Tian, Shinuo
  organization: China University of Geosciences (Beijing)
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  givenname: Shujie
  surname: Yang
  fullname: Yang, Shujie
  organization: China University of Geosciences (Beijing)
– sequence: 6
  givenname: Xi
  surname: Qian
  fullname: Qian, Xi
  organization: China University of Geosciences (Beijing)
– sequence: 7
  givenname: Bin
  surname: Ma
  fullname: Ma, Bin
  organization: Qinghai University
– sequence: 8
  givenname: Minghao
  surname: Fang
  fullname: Fang, Minghao
  organization: China University of Geosciences (Beijing)
– sequence: 9
  givenname: Yan'gai
  surname: Liu
  fullname: Liu, Yan'gai
  organization: China University of Geosciences (Beijing)
– sequence: 10
  givenname: Zhaohui
  surname: Huang
  fullname: Huang, Zhaohui
  organization: China University of Geosciences (Beijing)
– sequence: 11
  givenname: Xin
  orcidid: 0000-0003-3953-2699
  surname: Min
  fullname: Min, Xin
  email: minx@cugb.edu.cn
  organization: China University of Geosciences (Beijing)
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Snippet Environmental pollution and the energy crisis have promoted the development of clean energy as well as new‐generation energy storage systems. Potassium ion...
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SubjectTerms Cathode materials
Cathodes
Clean energy
Composition
Doping
Electrochemical analysis
Electrode materials
Energy storage
Inorganic chemistry
Ion storage
Lithium-ion batteries
Materials science
Optimization
Pigments
Potassium
Potassium ion batteries
Prussian blue analogues
Storage systems
Transition metals
Title Progress of Prussian Blue and Its Analogues as Cathode Materials for Potassium Ion Batteries
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Volume 26
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