Metalloradical Compounds with 1,2‐Dipivaloylhydrazido Ligands: Electron Transfer and Alkylation/Protonation Effects

Under oxidative conditions the complexes M(bpy)2Cl2, M = Ru or Os, react with 1,2‐dipivaloylhydrazine H2L = tBuC(O)‐NH‐NH‐C(O)‐tBu to yield the paramagnetic compounds [M(L)(bpy)2](PF6) {1(PF6), M = Ru and 2(PF6), M = Os}. Crystal structures of 1(ClO4) and 2(PF6) reveal an NNCO chelate coordination o...

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Bibliographic Details
Published in:	European journal of inorganic chemistry Vol. 2019; no. 21; pp. 2639 - 2647
Main Authors:	Mondal, Sudipta, Filippou, Vasileios, Bubrin, Martina, Schwederski, Brigitte, Fiedler, Jan, Kaim, Wolfgang
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 10.06.2019
Subjects:	Alkylation Chelates Crystal structure Electron transfer Electrons EPR spectroscopy Hydrazine Inorganic chemistry Ligands NMR Nuclear magnetic resonance Osmium Oxidation Protonation Ruthenium Spectroelectrochemistry Spin density
ISSN:	1434-1948, 1099-0682
Online Access:	Get full text
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