Effect of graphene content on the tribological and corrosion behavior of high-speed-laser-clad high-entropy-alloy composite coatings
To repair oil drill pipe joints that have failed owing to dry wear and tribocorrosion, graphene-reinforced CoCrFeMo0.5NiTi0.5 high-entropy alloy composite coatings (HEACCs) were developed through high-speed laser cladding. The HEACC containing 1.5 wt% graphene exhibited dry wear and tribocorrosion r...
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| Vydané v: | Tribology international Ročník 201; s. 110197 |
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| Hlavní autori: | , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
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Elsevier Ltd
01.01.2025
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| ISSN: | 0301-679X |
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| Abstract | To repair oil drill pipe joints that have failed owing to dry wear and tribocorrosion, graphene-reinforced CoCrFeMo0.5NiTi0.5 high-entropy alloy composite coatings (HEACCs) were developed through high-speed laser cladding. The HEACC containing 1.5 wt% graphene exhibited dry wear and tribocorrosion rates that were 59.18 % and 32.20 % of those observed in the high-entropy alloy coating, respectively. The HEACC exhibited a corrosion current density of 2.475 × 10−7 A/cm2. The HEACC containing 1.5 wt% graphene underwent progressive damage during dry wear owing to the combined effects of abrasive wear, which created furrows; adhesive wear, which led to flaking; and oxidative wear, which formed oxide layers. During tribocorrosion, chloride ions exacerbated surface damage caused by hard abrasives and asperities, intensifying corrosive–abrasive wear interactions.
●Composite coatings of graphene-reinforced high-entropy alloys were prepared via high-speed laser cladding.●The tribocorrosion rate of the HEACC can reach 2.720 µm3·N−1·mm−1, which is only 32.20 % of that of the HEA.●The influence of the graphene content on the tribocorrosion performance of HEACCs was investigated.●The corrosion current density of the HEACC reached about an order of magnitude smaller than that of the HEA.●The formation of reinforcing phases and the self-lubricating effect of graphene collectively enhanced the tribocorrosion resistance of the composite coating. |
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| AbstractList | To repair oil drill pipe joints that have failed owing to dry wear and tribocorrosion, graphene-reinforced CoCrFeMo0.5NiTi0.5 high-entropy alloy composite coatings (HEACCs) were developed through high-speed laser cladding. The HEACC containing 1.5 wt% graphene exhibited dry wear and tribocorrosion rates that were 59.18 % and 32.20 % of those observed in the high-entropy alloy coating, respectively. The HEACC exhibited a corrosion current density of 2.475 × 10−7 A/cm2. The HEACC containing 1.5 wt% graphene underwent progressive damage during dry wear owing to the combined effects of abrasive wear, which created furrows; adhesive wear, which led to flaking; and oxidative wear, which formed oxide layers. During tribocorrosion, chloride ions exacerbated surface damage caused by hard abrasives and asperities, intensifying corrosive–abrasive wear interactions.
●Composite coatings of graphene-reinforced high-entropy alloys were prepared via high-speed laser cladding.●The tribocorrosion rate of the HEACC can reach 2.720 µm3·N−1·mm−1, which is only 32.20 % of that of the HEA.●The influence of the graphene content on the tribocorrosion performance of HEACCs was investigated.●The corrosion current density of the HEACC reached about an order of magnitude smaller than that of the HEA.●The formation of reinforcing phases and the self-lubricating effect of graphene collectively enhanced the tribocorrosion resistance of the composite coating. |
| ArticleNumber | 110197 |
| Author | Sun, Wenlei Xie, Lei Huang, Yong Yu, Jiangtong Huang, Haibo |
| Author_xml | – sequence: 1 givenname: Jiangtong surname: Yu fullname: Yu, Jiangtong email: yujtong@163.com organization: School of Mechanical Engineering, Xinjiang University, Urumqi 830017, China – sequence: 2 givenname: Wenlei surname: Sun fullname: Sun, Wenlei email: xjusunwenlei@163.com organization: School of Mechanical Engineering, Xinjiang University, Urumqi 830017, China – sequence: 3 givenname: Lei surname: Xie fullname: Xie, Lei organization: School of Physics Science and Technology, Xinjiang University, Urumqi 830017, China – sequence: 4 givenname: Yong surname: Huang fullname: Huang, Yong organization: Electromechanical Engineering College, Xinjiang Institute of Engineering, Urumqi 830023, China – sequence: 5 givenname: Haibo surname: Huang fullname: Huang, Haibo organization: Electromechanical Engineering College, Xinjiang Institute of Engineering, Urumqi 830023, China |
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| CitedBy_id | crossref_primary_10_1016_j_surfcoat_2025_132292 crossref_primary_10_1016_j_surfcoat_2025_132707 crossref_primary_10_1016_j_optlastec_2025_112598 crossref_primary_10_1016_j_mtcomm_2025_112107 crossref_primary_10_1016_j_ceramint_2025_08_271 |
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Nanomaterials doi: 10.3390/nano12122113 |
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