Ternary nanostructures of Cr2O3/graphene oxide/conducting polymers for supercapacitor application
In this work, nanostructured composites of Cr2O3-graphene oxide (Cr2O3/GO) with conducting polymers; polyaniline (PANI) and polypyrrole (PPy) with the shape of cauliflower were synthesized via s simple and low cost one-step chronoamperometry method. The structures and morphologies of the resulting t...
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| Vydané v: | Journal of electroanalytical chemistry (Lausanne, Switzerland) Ročník 823; s. 505 - 516 |
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| Hlavní autori: | , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
Elsevier B.V
15.08.2018
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| ISSN: | 1572-6657, 1873-2569 |
| On-line prístup: | Získať plný text |
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| Abstract | In this work, nanostructured composites of Cr2O3-graphene oxide (Cr2O3/GO) with conducting polymers; polyaniline (PANI) and polypyrrole (PPy) with the shape of cauliflower were synthesized via s simple and low cost one-step chronoamperometry method. The structures and morphologies of the resulting ternary nanocomposites were characterized by using Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The electrochemical capacitive properties of the prepared nanocomposites were evaluated by using cycle voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. The as-synthesized Cr2O3/GO/PANI and Cr2O3/GO/PPy composites exhibit a highest specific capacitance of 525 and 495 F g−1 at 5 A g−1 in the three-electrode tests, respectively. Interestingly, Cr2O3/GO/PANI and Cr2O3/GO/PPy composites retain 84 and 80% of their initial capacitance values after 4000 charge-discharge cycles, suggesting good electrochemical stability of the nanocomposite electrodes. The assembled symmetric devices based on Cr2O3/GO/PANI and Cr2O3/GO/PPy composites show a high specific capacitance of 263 and 100 F g−1 at the current density of 5 A g−1, respectively.
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•Cr2O3/GO/CPs is deposited on SS using a potentiostatic method.•Cr2O3/GO/PANI showed an excellent specific capacitance of 895 F g−1 at 5 A g−1.•Cr2O3/GO/PPy has a good specific capacitance of 695 F g−1 at 5 A g−1.•Cr2O3/GO/PANI shows highest power and energy density among the prepared composite electrodes. |
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| AbstractList | In this work, nanostructured composites of Cr2O3-graphene oxide (Cr2O3/GO) with conducting polymers; polyaniline (PANI) and polypyrrole (PPy) with the shape of cauliflower were synthesized via s simple and low cost one-step chronoamperometry method. The structures and morphologies of the resulting ternary nanocomposites were characterized by using Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The electrochemical capacitive properties of the prepared nanocomposites were evaluated by using cycle voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. The as-synthesized Cr2O3/GO/PANI and Cr2O3/GO/PPy composites exhibit a highest specific capacitance of 525 and 495 F g−1 at 5 A g−1 in the three-electrode tests, respectively. Interestingly, Cr2O3/GO/PANI and Cr2O3/GO/PPy composites retain 84 and 80% of their initial capacitance values after 4000 charge-discharge cycles, suggesting good electrochemical stability of the nanocomposite electrodes. The assembled symmetric devices based on Cr2O3/GO/PANI and Cr2O3/GO/PPy composites show a high specific capacitance of 263 and 100 F g−1 at the current density of 5 A g−1, respectively.
[Display omitted]
•Cr2O3/GO/CPs is deposited on SS using a potentiostatic method.•Cr2O3/GO/PANI showed an excellent specific capacitance of 895 F g−1 at 5 A g−1.•Cr2O3/GO/PPy has a good specific capacitance of 695 F g−1 at 5 A g−1.•Cr2O3/GO/PANI shows highest power and energy density among the prepared composite electrodes. |
| Author | Shahrokhian, Saeed zad, Azam Iraji Asen, Parvin |
| Author_xml | – sequence: 1 givenname: Parvin surname: Asen fullname: Asen, Parvin organization: Institute for Nanoscience and Technology, Sharif University of Technology, Tehran, Iran – sequence: 2 givenname: Saeed orcidid: 0000-0003-3138-6578 surname: Shahrokhian fullname: Shahrokhian, Saeed email: shahrokhian@sharif.edu organization: Institute for Nanoscience and Technology, Sharif University of Technology, Tehran, Iran – sequence: 3 givenname: Azam Iraji surname: zad fullname: zad, Azam Iraji organization: Institute for Nanoscience and Technology, Sharif University of Technology, Tehran, Iran |
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| Keywords | Supercapacitor Graphene oxide Polyaniline Chromium oxide Ternary composite Polypyrrole |
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| SubjectTerms | Chromium oxide Graphene oxide Polyaniline Polypyrrole Supercapacitor Ternary composite |
| Title | Ternary nanostructures of Cr2O3/graphene oxide/conducting polymers for supercapacitor application |
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