Synthesis of ferrocenylphenyl derivatives including biphenylferrocenes, arylferrocenylphenyl ethers and arylferrocenylphenyl amines

The preparation of a series of substituted biphenylferrocenes via a modified Suzuki reaction between 4-bromophenylferrocene and substituted phenylboronic acids is described. The X-ray crystal structure of 4′-formyl-4-biphenylferrocene is reported and this compound is then incorporated into the first...

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Vydané v:	Journal of organometallic chemistry Ročník 645; číslo 1; s. 65 - 81
Hlavní autori:	Imrie, Christopher, Engelbrecht, Pieter, Loubser, Christa, McCleland, Cedric W, Nyamori, Vincent O, Bogardi, Robert, Levendis, Demetrius C, Tolom, Nomfuneko, van Rooyen, Jason, Williams, Nadia
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	LAUSANNE Elsevier B.V 2002 Elsevier
Predmet:	Arylferrocenylphenyl amines Arylferrocenylphenyl ethers Biphenylferrocenes Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology Arylferrocenylphenyl ethers Arylferrocenylphenyl amines Biphenylferrocenes biphenylferrocenes PHYSICAL-PROPERTIES MONOSUBSTITUTED FERROCENE DERIVATIVES THERMOTROPIC LIQUID-CRYSTALS PHASE arylferrocenylphenyl ethers CHOLESTERYL GROUP ACIDS arylferrocenylphenyl amines ARYLATION DIARYL ETHERS
ISSN:	0022-328X, 1872-8561
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Abstract	The preparation of a series of substituted biphenylferrocenes via a modified Suzuki reaction between 4-bromophenylferrocene and substituted phenylboronic acids is described. The X-ray crystal structure of 4′-formyl-4-biphenylferrocene is reported and this compound is then incorporated into the first series of ferrocenomesogens containing the ferrocenylbiphenyl unit. The synthesis of a series of arylferrocenylphenyl ethers and arylferrocenylphenyl amines is also described. The reaction of 4-bromophenylfererrocene with substituted phenylboronic acids provides excellent yields of substituted biphenylferrocenes. The synthesis of arylferrocenylphenyl ethers and arylferrocenylphenyl amines has been achieved. The X-ray structure of 4′-formyl-4-biphenylferrocene has been determined. A series of ferrocenomesogens has been prepared from 4′-formyl-4-biphenylferrocene.
AbstractList	The preparation of a series of substituted biphenylferrocenes via a modified Suzuki reaction between 4-bromophenylferrocene and substituted phenylboronic acids is described. The X-ray crystal structure of 4'-formyl-4-biphenylferrocene is reported and this compound is then incorporated into the first series of ferrocenomesogens containing the ferrocenylbiphenyl unit. The synthesis of a series of arylferrocenylphenyl ethers and arylferrocenylphenyl amines is also described. (C) 2002 Elsevier Science B.V. All rights reserved. The preparation of a series of substituted biphenylferrocenes via a modified Suzuki reaction between 4-bromophenylferrocene and substituted phenylboronic acids is described. The X-ray crystal structure of 4′-formyl-4-biphenylferrocene is reported and this compound is then incorporated into the first series of ferrocenomesogens containing the ferrocenylbiphenyl unit. The synthesis of a series of arylferrocenylphenyl ethers and arylferrocenylphenyl amines is also described. The reaction of 4-bromophenylfererrocene with substituted phenylboronic acids provides excellent yields of substituted biphenylferrocenes. The synthesis of arylferrocenylphenyl ethers and arylferrocenylphenyl amines has been achieved. The X-ray structure of 4′-formyl-4-biphenylferrocene has been determined. A series of ferrocenomesogens has been prepared from 4′-formyl-4-biphenylferrocene.
ArticleNumber	0022
Author	Tolom, Nomfuneko van Rooyen, Jason Imrie, Christopher Williams, Nadia Bogardi, Robert Nyamori, Vincent O Loubser, Christa McCleland, Cedric W Engelbrecht, Pieter Levendis, Demetrius C
Author_xml	– sequence: 1 givenname: Christopher surname: Imrie fullname: Imrie, Christopher email: chacci@upe.ac.za organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa – sequence: 2 givenname: Pieter surname: Engelbrecht fullname: Engelbrecht, Pieter organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa – sequence: 3 givenname: Christa surname: Loubser fullname: Loubser, Christa – sequence: 4 givenname: Cedric W surname: McCleland fullname: McCleland, Cedric W organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa – sequence: 5 givenname: Vincent O surname: Nyamori fullname: Nyamori, Vincent O organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa – sequence: 6 givenname: Robert surname: Bogardi fullname: Bogardi, Robert organization: Department of Chemistry, Centre for Molecular Design, University of the Witwatersrand, Johannesburg, South Africa – sequence: 7 givenname: Demetrius C surname: Levendis fullname: Levendis, Demetrius C organization: Department of Chemistry, Centre for Molecular Design, University of the Witwatersrand, Johannesburg, South Africa – sequence: 8 givenname: Nomfuneko surname: Tolom fullname: Tolom, Nomfuneko organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa – sequence: 9 givenname: Jason surname: van Rooyen fullname: van Rooyen, Jason organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa – sequence: 10 givenname: Nadia surname: Williams fullname: Williams, Nadia organization: Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa
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Keywords	Arylferrocenylphenyl ethers Arylferrocenylphenyl amines Biphenylferrocenes biphenylferrocenes PHYSICAL-PROPERTIES MONOSUBSTITUTED FERROCENE DERIVATIVES THERMOTROPIC LIQUID-CRYSTALS PHASE arylferrocenylphenyl ethers CHOLESTERYL GROUP ACIDS arylferrocenylphenyl amines ARYLATION DIARYL ETHERS
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An expedient synthesis of thyroxine publication-title: TETRAHEDRON LETTERS
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Snippet	The preparation of a series of substituted biphenylferrocenes via a modified Suzuki reaction between 4-bromophenylferrocene and substituted phenylboronic acids...
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SubjectTerms	Arylferrocenylphenyl amines Arylferrocenylphenyl ethers Biphenylferrocenes Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology
Title	Synthesis of ferrocenylphenyl derivatives including biphenylferrocenes, arylferrocenylphenyl ethers and arylferrocenylphenyl amines
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