Synthesis, structure and physical properties of a low dimensional compound

The crystal structure of (μ3-oxo)hexakis(cyanoacetato-κO,O′)(cyanoacetato-κO)diaquatriiron(III) cyanoacetic acid shows the formation of trinuclear complexes in a hydrogen-bond network that bonds all the molecules in a 3D arrangement. For this complex, within whose clusters the whole magnetic interac...

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Bibliographic Details
Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 172; pp. 9 - 13
Main Authors: Ramos Silva, Manuela, Coutinho, Joana T., Pereira, Laura C.J., Martín-Ramos, Pablo, Waerenborgh, João C.
Format: Journal Article
Language:English
Published: England Elsevier B.V 05.02.2017
Subjects:
AFM interaction
Cyanoacetate complex
Low dimensional compound
Trinuclear Fe(III) complex
Low dimensional compound
Trinuclear Fe(III) complex
AFM interaction
Cyanoacetate complex
ISSN:1386-1425, 1873-3557
Online Access:Get full text
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Summary:The crystal structure of (μ3-oxo)hexakis(cyanoacetato-κO,O′)(cyanoacetato-κO)diaquatriiron(III) cyanoacetic acid shows the formation of trinuclear complexes in a hydrogen-bond network that bonds all the molecules in a 3D arrangement. For this complex, within whose clusters the whole magnetic interaction takes place, 57Fe Mössbauer spectroscopy shows that the Fe cations are in the S=5/2 state in the temperature range 2–295K. The asymmetric broadening of the absorption peaks below 80K is consistent with strong antiferromagnetic interactions between the metal spins. The magnetization measurements also show the antiferromagnetic character of the spin ensemble and an ST=1/2 magnetic ground state typical of triangular systems with similar J between Fe-Fe pairs. [Display omitted] •A novel cyanoacetato-based compound with Fe(III) has been synthesized.•Fe clusters are H-bonded in a 3D arrangement.•Mossbauer spectroscopy reveals that Fe cations are in the high spin, S=5/2, state.•Magnetic properties of trinuclear Fe complex are described by isosceles two-J model.•Fe(III) triangular system shows strong antiferromagnetic interactions with ST=1/2.
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ISSN:1386-1425
1873-3557
DOI:10.1016/j.saa.2016.06.037