Fractal model of the cracking resistance of modified polyethylene
It has been demonstrated that the fracture criterion for polyethylene samples in stress cracking tests in active media is met when the polar liquid reaches the median plane of the sample. The cracking stress resistance is accurately described within the framework of the fractal model of the transfer...
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| Published in: | Theoretical foundations of chemical engineering Vol. 42; no. 4; pp. 439 - 442 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
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SP MAIK Nauka/Interperiodica
01.08.2008
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| ISSN: | 0040-5795, 1608-3431 |
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| Abstract | It has been demonstrated that the fracture criterion for polyethylene samples in stress cracking tests in active media is met when the polar liquid reaches the median plane of the sample. The cracking stress resistance is accurately described within the framework of the fractal model of the transfer process in the polymers. The extremal growth of the cracking resistance is caused by structural changes due to the introduction of the finely dispersed Fe/FeO mixture and characterized by the dimensions of regions with localization of excess energy. |
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| AbstractList | It has been demonstrated that the fracture criterion for polyethylene samples in stress cracking tests in active media is met when the polar liquid reaches the median plane of the sample. The cracking stress resistance is accurately described within the framework of the fractal model of the transfer process in the polymers. The extremal growth of the cracking resistance is caused by structural changes due to the introduction of the finely dispersed Fe/FeO mixture and characterized by the dimensions of regions with localization of excess energy. |
| Author | Kozlov, G. V. Ovcharenko, E. N. Zaikov, G. E. |
| Author_xml | – sequence: 1 givenname: G. V. surname: Kozlov fullname: Kozlov, G. V. email: i_dolbin@mail.ru organization: Kabardino-Balkar State University – sequence: 2 givenname: E. N. surname: Ovcharenko fullname: Ovcharenko, E. N. organization: Semenov Institute of Chemical Physics, Russian Academy of Sciences – sequence: 3 givenname: G. E. surname: Zaikov fullname: Zaikov, G. E. organization: Emanuel Institute of Biochemical Physics, Russian Academy of Sciences |
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| Cites_doi | 10.1088/0953-8984/4/12/024 10.3367/UFNr.0171.200107b.0717 10.1051/jphyslet:019820043017062500 |
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| Issue | 4 |
| Keywords | HDPE Fracture Criterion Active Medium Fractal Model Water Cluster |
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| References | Belford, Sinai, Rowland (CR5) 1980 CR2 Mashukov, Gladyshev, Kozlov (CR3) 1991; 33 Brown, Rowland (CR6) 1980 CR9 Balankin (CR12) 1991 Alexander, Orbach (CR8) 1982; 42 Kozlov, Sanditov, Lipatov, Zaikov (CR10) 2004 Kozlov, Novikov (CR15) 2001; 171 Rogers, Baer (CR4) 1964 Kozlov, Zaikov (CR7) 2003; 45 Kozlov, Sanditov (CR11) 1994 Kalinchev, Sakovtseva (CR13) 1983 Budtov (CR16) 1992 Howard, Baer (CR1) 1964 Lin, Wang (CR14) 1992; 4 G.V. Kozlov (4012_CR7) 2003; 45 C.E. Rogers (4012_CR4) 1964 G.V. Kozlov (4012_CR10) 2004 G.V. Kozlov (4012_CR11) 1994 A.S. Balankin (4012_CR12) 1991 G.V. Kozlov (4012_CR15) 2001; 171 G.L. Brown (4012_CR6) 1980 E.L. Kalinchev (4012_CR13) 1983 V.P. Budtov (4012_CR16) 1992 4012_CR2 G. Belford (4012_CR5) 1980 J.B. Howard (4012_CR1) 1964 S. Alexander (4012_CR8) 1982; 42 D. Lin (4012_CR14) 1992; 4 4012_CR9 N.I. Mashukov (4012_CR3) 1991; 33 |
| References_xml | – year: 1964 ident: CR4 article-title: Permeability and Chemical Resistance publication-title: Engineering Design for Plastics – volume: 4 start-page: 3331 issue: 12 year: 1992 ident: CR14 publication-title: J. Phys.: Condens. Matter doi: 10.1088/0953-8984/4/12/024 – year: 2004 ident: CR10 article-title: Strukturnyi analiz fluktuatsionnogo svobodnogo ob’ema v amorfnom sostoyanii polimerov publication-title: Uspekhi v oblasti fiziko-khimii polimerov – year: 1992 ident: CR16 publication-title: Fizicheskaya khimiya rastvorov polimerov – ident: CR2 – year: 1980 ident: CR5 article-title: Relaxation Studies of Adsorbed Water on Porous Glass. Varying Temperature and Pore Size at Constant Coverages publication-title: Water in Polymers – volume: 45 start-page: 1197 issue: 7 year: 2003 ident: CR7 publication-title: Highmol. Com. – year: 1994 ident: CR11 publication-title: Angarmonicheskie effekty i fiziko-mekhanicheskie svoistva polimerov – year: 1964 ident: CR1 article-title: Stress Cracking publication-title: Engineering Design for Plastics – ident: CR9 – year: 1983 ident: CR13 publication-title: Svoistva i pererabotka termoplastov – volume: 171 start-page: 717 issue: 7 year: 2001 ident: CR15 publication-title: Usp. Fiz. Nauk doi: 10.3367/UFNr.0171.200107b.0717 – year: 1980 ident: CR6 article-title: Clustering of Water in Polymers publication-title: Water in Polymers – year: 1991 ident: CR12 publication-title: Sinergetika deformiruemogo tela – volume: 42 start-page: L625 issue: 17 year: 1982 ident: CR8 publication-title: J. Phys. Lett. (Paris) – volume: 33 start-page: 2538 issue: 12 year: 1991 ident: CR3 publication-title: Highmol. Com. – volume-title: Fizicheskaya khimiya rastvorov polimerov year: 1992 ident: 4012_CR16 – volume-title: Angarmonicheskie effekty i fiziko-mekhanicheskie svoistva polimerov year: 1994 ident: 4012_CR11 – volume-title: Water in Polymers year: 1980 ident: 4012_CR5 – volume-title: Uspekhi v oblasti fiziko-khimii polimerov year: 2004 ident: 4012_CR10 – volume: 33 start-page: 2538 issue: 12 year: 1991 ident: 4012_CR3 publication-title: Highmol. Com. – volume-title: Sinergetika deformiruemogo tela year: 1991 ident: 4012_CR12 – volume-title: Svoistva i pererabotka termoplastov year: 1983 ident: 4012_CR13 – volume: 42 start-page: L625 issue: 17 year: 1982 ident: 4012_CR8 publication-title: J. Phys. Lett. (Paris) doi: 10.1051/jphyslet:019820043017062500 – volume: 45 start-page: 1197 issue: 7 year: 2003 ident: 4012_CR7 publication-title: Highmol. Com. – volume: 4 start-page: 3331 issue: 12 year: 1992 ident: 4012_CR14 publication-title: J. Phys.: Condens. Matter – volume-title: Engineering Design for Plastics year: 1964 ident: 4012_CR1 – ident: 4012_CR2 – volume-title: Engineering Design for Plastics year: 1964 ident: 4012_CR4 – volume-title: Water in Polymers year: 1980 ident: 4012_CR6 – ident: 4012_CR9 – volume: 171 start-page: 717 issue: 7 year: 2001 ident: 4012_CR15 publication-title: Usp. Fiz. Nauk doi: 10.3367/UFNr.0171.200107b.0717 |
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| SubjectTerms | Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering |
| Title | Fractal model of the cracking resistance of modified polyethylene |
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