C-H activation of alkanes on Rh+ n (n=1-30) clusters: size effects on dehydrogenation

The rate coefficients for the dehydrogenation of ethane, propane, and isobutane with cationic rhodium atoms Rh+ and clusters Rh+ n of up to 30 atoms were measured under single-collision conditions in a Fourier-transform ion cyclotron resonance mass spectrometer. The reaction rates are cluster size d...

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Bibliographic Details
Published in:The Journal of chemical physics Vol. 123; no. 21; p. 214709
Main Authors: Adlhart, Christian, Uggerud, Einar
Format: Journal Article
Language:English
Published: United States 01.12.2005
ISSN:0021-9606
Online Access:Get more information
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