Calcium Carbonate and Ettringite Induced Efflorescence in CAC- Anhydrite Binary Systems
We focused on the efflorescence induced microstructural evolution of ettringite-rich systems prepared with calcium aluminate cement (CAC) and anhydrite. The effects of anhydrite on the visible efflorescence, and the corresponding capillary absorption of CAC-anhydrite mortars were revealed. The compo...
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| Published in: | Journal of Wuhan University of Technology. Materials science edition Vol. 39; no. 5; pp. 1129 - 1137 |
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| Main Authors: | , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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Wuhan
Wuhan University of Technology
01.10.2024
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education,School of Materials Science and Engineering,Tongji University,Shanghai 201804,China%Shanghai Construction No.5(Group)Co.,Ltd.,Shanghai 200063,China%School of Material Sci-ence and Engineering,Chongqing Jiaotong University,Chongqing 400074,China |
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| ISSN: | 1000-2413, 1993-0437 |
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| Abstract | We focused on the efflorescence induced microstructural evolution of ettringite-rich systems prepared with calcium aluminate cement (CAC) and anhydrite. The effects of anhydrite on the visible efflorescence, and the corresponding capillary absorption of CAC-anhydrite mortars were revealed. The composition and microstructure of efflorescence-causing substances were investigated by optical microscope,
in-situ
Raman spectroscopy, scanning electron microscope, energy dispersive spectrometer, thermogravimetric analysis, and differential scanning calorimetry, at multi-scales. Results indicate that, besides the calcium carbonate, ettringite is another main component of efflorescence-causing substances. Compared with the neat CAC mortars, the addition of anhydrite has a significant effect on the degree of efflorescence by acting on the composition of hydration products and pore structure. In addition, methods are proposed for the prevention of efflorescence of CAC-anhydrite binary system. |
|---|---|
| AbstractList | We focused on the efflorescence induced microstructural evolution of ettringite-rich systems prepared with calcium aluminate cement (CAC) and anhydrite. The effects of anhydrite on the visible efflorescence, and the corresponding capillary absorption of CAC-anhydrite mortars were revealed. The composition and microstructure of efflorescence-causing substances were investigated by optical microscope,
in-situ
Raman spectroscopy, scanning electron microscope, energy dispersive spectrometer, thermogravimetric analysis, and differential scanning calorimetry, at multi-scales. Results indicate that, besides the calcium carbonate, ettringite is another main component of efflorescence-causing substances. Compared with the neat CAC mortars, the addition of anhydrite has a significant effect on the degree of efflorescence by acting on the composition of hydration products and pore structure. In addition, methods are proposed for the prevention of efflorescence of CAC-anhydrite binary system. We focused on the efflorescence induced microstructural evolution of ettringite-rich systems prepared with calcium aluminate cement(CAC)and anhydrite.The effects of anhydrite on the visible efflorescence,and the corresponding capillary absorption of CAC-anhydrite mortars were revealed.The composition and microstructure of efflorescence-causing substances were investigated by optical microscope,in-situ Raman spectroscopy,scanning electron microscope,energy dispersive spectrometer,thermogravimetric analysis,and differential scanning calorimetry,at multi-scales.Results indicate that,besides the calcium carbonate,ettringite is another main component of efflorescence-causing substances.Compared with the neat CAC mortars,the addition of anhydrite has a significant effect on the degree of efflorescence by acting on the composition of hydration products and pore structure.In addition,methods are proposed for the prevention of efflorescence of CAC-anhydrite binary system. |
| Author | Xu, Linglin Wu, Kai Yu, Long Pan, Feng Sun, Zixuan Chen, Yuting Wang, Chaoqiang Liu, Siyu Yang, Zhenghong |
| AuthorAffiliation | Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education,School of Materials Science and Engineering,Tongji University,Shanghai 201804,China%Shanghai Construction No.5(Group)Co.,Ltd.,Shanghai 200063,China%School of Material Sci-ence and Engineering,Chongqing Jiaotong University,Chongqing 400074,China |
| AuthorAffiliation_xml | – name: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education,School of Materials Science and Engineering,Tongji University,Shanghai 201804,China%Shanghai Construction No.5(Group)Co.,Ltd.,Shanghai 200063,China%School of Material Sci-ence and Engineering,Chongqing Jiaotong University,Chongqing 400074,China |
| Author_xml | – sequence: 1 givenname: Zixuan surname: Sun fullname: Sun, Zixuan organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University – sequence: 2 givenname: Yuting surname: Chen fullname: Chen, Yuting organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University – sequence: 3 givenname: Linglin surname: Xu fullname: Xu, Linglin email: xulinglin@126.com organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University – sequence: 4 givenname: Siyu surname: Liu fullname: Liu, Siyu organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University – sequence: 5 givenname: Long surname: Yu fullname: Yu, Long organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University – sequence: 6 givenname: Feng surname: Pan fullname: Pan, Feng organization: Shanghai Construction No. 5 (Group) Co., Ltd – sequence: 7 givenname: Chaoqiang surname: Wang fullname: Wang, Chaoqiang organization: School of Material Science and Engineering, Chongqing Jiaotong University – sequence: 8 givenname: Kai surname: Wu fullname: Wu, Kai organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University – sequence: 9 givenname: Zhenghong surname: Yang fullname: Yang, Zhenghong organization: Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University |
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| Keywords | ettringite pore structure efflorescence phase assemblage anhydrite calcium aluminate cement |
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| Snippet | We focused on the efflorescence induced microstructural evolution of ettringite-rich systems prepared with calcium aluminate cement (CAC) and anhydrite. The... We focused on the efflorescence induced microstructural evolution of ettringite-rich systems prepared with calcium aluminate cement(CAC)and anhydrite.The... |
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| SubjectTerms | Cementitious Materials Chemistry and Materials Science Materials Science |
| Title | Calcium Carbonate and Ettringite Induced Efflorescence in CAC- Anhydrite Binary Systems |
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