Toward a three-dimensional vision of the different compositions and the stratigraphy of the painting L’Homme blessé by G. Courbet: coupling SEM–EDX and confocal micro-XRF
Examination of Gustave Courbet’s L’Homme blessé (Musee d’Orsay, Paris), a painting with three successive compositions on a single canvas, was undertaken with scanning electron microscopy coupled with an energy-dispersive X-ray analyzing system (SEM–EDX) on cross sections taken in the 1970s at the La...
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| Veröffentlicht in: | Applied physics. A, Materials science & processing Jg. 121; H. 3; S. 903 - 913 |
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01.11.2015
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| Abstract | Examination of Gustave Courbet’s
L’Homme blessé
(Musee d’Orsay, Paris), a painting with three successive compositions on a single canvas, was undertaken with scanning electron microscopy coupled with an energy-dispersive X-ray analyzing system (SEM–EDX) on cross sections taken in the 1970s at the Laboratoire de Recherche de Musées de France, Paris and confocal X-ray fluorescence spectroscopy (CXRF) analysis adjacent to the sample locations of the three previously removed cross sections. Recent developments of in situ techniques such as CXRF have enabled investigation of the chemical composition of complicated paint layering without sampling. Here, we compare depth profiling by CXRF analysis with SEM–EDX data from cross sections with the goal of understanding how well CXRF data represent such a complicated paint stratigraphy. Beyond suggesting the paint palettes for Courbet’s three compositions, this new data provide insight into the complex paint layer stratigraphy of eight or more layers and serve as the basis for interpreting further analyses by scanning XRF and CXRF of additional areas of interest on the painting. Data from these additional locations will be discussed in a forthcoming paper. |
|---|---|
| AbstractList | Examination of Gustave Courbet’s
L’Homme blessé
(Musee d’Orsay, Paris), a painting with three successive compositions on a single canvas, was undertaken with scanning electron microscopy coupled with an energy-dispersive X-ray analyzing system (SEM–EDX) on cross sections taken in the 1970s at the Laboratoire de Recherche de Musées de France, Paris and confocal X-ray fluorescence spectroscopy (CXRF) analysis adjacent to the sample locations of the three previously removed cross sections. Recent developments of in situ techniques such as CXRF have enabled investigation of the chemical composition of complicated paint layering without sampling. Here, we compare depth profiling by CXRF analysis with SEM–EDX data from cross sections with the goal of understanding how well CXRF data represent such a complicated paint stratigraphy. Beyond suggesting the paint palettes for Courbet’s three compositions, this new data provide insight into the complex paint layer stratigraphy of eight or more layers and serve as the basis for interpreting further analyses by scanning XRF and CXRF of additional areas of interest on the painting. Data from these additional locations will be discussed in a forthcoming paper. |
| Author | Reiche, Ina Mysak, Erin Mottin, Bruno Müller, Katharina Eveno, Myriam |
| Author_xml | – sequence: 1 givenname: Ina surname: Reiche fullname: Reiche, Ina email: ina.reiche@upmc.fr, i.reiche@smb.spk-berlin.de organization: Laboratoire d’Archéologie Moléculaire et Structurale, UMR 8220 CNRS UPMC, Université Paris 06 - Sorbonne Universités, Rathgen Research Laboratory, National Museums in Berlin-Prussian Cultural Heritage Foundation – sequence: 2 givenname: Katharina surname: Müller fullname: Müller, Katharina organization: Laboratoire d’Archéologie Moléculaire et Structurale, UMR 8220 CNRS UPMC, Université Paris 06 - Sorbonne Universités – sequence: 3 givenname: Erin surname: Mysak fullname: Mysak, Erin organization: Centre de Recherche et de Restauration des Musées de France (C2RMF), Straus Center for Conservation and Technical Studies, Harvard Art Museums, Institute for the Preservation of Cultural Heritage, Yale University – sequence: 4 givenname: Myriam surname: Eveno fullname: Eveno, Myriam organization: Centre de Recherche et de Restauration des Musées de France (C2RMF) – sequence: 5 givenname: Bruno surname: Mottin fullname: Mottin, Bruno organization: Centre de Recherche et de Restauration des Musées de France (C2RMF) |
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| Cites_doi | 10.1021/ac701774d 10.1021/ac800965g 10.1039/c0ja00257g 10.1016/j.sab.2013.07.009 10.1016/j.nimb.2007.09.019 10.1021/ac049274l 10.1039/c2ja30157a 10.1039/c3ja30341a 10.1016/j.sab.2006.12.002 10.1016/j.sab.2004.07.025 10.1021/ar900248e 10.1016/j.sab.2004.10.012 10.1016/S0168-583X(03)01321-1 10.1179/sic.2008.53.2.93 10.1039/b915912f |
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| Keywords | Lead White Prussian Blue Alum Substrate Paint Layer Barium Sulfate |
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L’Homme blessé
(Musee d’Orsay, Paris), a painting with three successive compositions on a single canvas, was undertaken with... |
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| Title | Toward a three-dimensional vision of the different compositions and the stratigraphy of the painting L’Homme blessé by G. Courbet: coupling SEM–EDX and confocal micro-XRF |
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