Structure and slow magnetic relaxation in a series of dysprosium(III) complexes
•A ligand with pentadentate coordination pocket and two phenolic hydroxyl groups;•Structural diversity from mononuclear, dinuclear, to one-dimensional;•SMM performance tuned through coordination geometry and intermetallic linking modes. With the aim of synthesizing air-stable pentagonal-bipyramidal...
Uloženo v:
| Vydáno v: | Journal of molecular structure Ročník 1348; s. 143398 |
|---|---|
| Hlavní autoři: | , , , , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
| Vydáno: |
Elsevier B.V
25.12.2025
|
| Témata: | |
| ISSN: | 0022-2860 |
| On-line přístup: | Získat plný text |
| Tagy: |
Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
|
| Abstract | •A ligand with pentadentate coordination pocket and two phenolic hydroxyl groups;•Structural diversity from mononuclear, dinuclear, to one-dimensional;•SMM performance tuned through coordination geometry and intermetallic linking modes.
With the aim of synthesizing air-stable pentagonal-bipyramidal Dy(III) complexes with a rigid equatorial plane, a pentadentate chelating ligand was used in this work, namely pyridyl-2,6-diacetylbis(salicylhydrazone) (H4L). Its reactions with Dy(OTf)3 gave three Dy(III) complexes, namely [Dyn(H2L)n][Dy(H2L)2]n (1), [Na3(Dy(H2L)2)3(THF)2]n∙5nCH3CN (2) and [Dy2(H2L)2(OMe)2(MeOH)2] (3). The attempted reactions of 3 with Ph3SiOH in the presence of NEt3 gave [Dyn(HL)n] (4). 1 has chain-structured coordination cation of [Dyn(H2L)n]n+ and mononuclear coordination anion of [Dy(H2L)2]−. The Dy(III) coordination unit of [Dy(H2L)2]− in 2 is similar to that of the anion of 1. Interestingly, three [Dy(H2L)2]− units in 2 sandwich two Na+ ions through Na-O bonds to build a linear pentanuclear heterometallic three-decker cluster unit [Na2(Dy(H2L)2)3]−, which is perpendicularly aligned with the neighboring ones through the linkage of Na+ ions, constructing a chain structure. 3 shows a dinuclear structure with the two [Dy(H2L)]+ units double-bridged by two MeO− linkers. 4 exhbits a chain structure similar to that of the coordination cation of [Dyn(H2L)n]n+ in 1. It is revealed from the magnetic measurements that 1, 2 and 4 show slow magnetic relaxation behaviors, and 3 is a field-induced single-molecule magnet. It revealed a tuning effect of SMM performance through coordination geometry and intermetallic linking modes.
We report here four Dy(III) complexes prepared from the ligand of pyridyl-2,6-diacetylbis(salicylhydrazone) through tuning reaction solvents and their ratio, with their structures diversified from mononuclear, dinuclear to one-dimensional and their SMM performance tuned through coordination geometry and intermetallic linking modes. [Display omitted] |
|---|---|
| AbstractList | •A ligand with pentadentate coordination pocket and two phenolic hydroxyl groups;•Structural diversity from mononuclear, dinuclear, to one-dimensional;•SMM performance tuned through coordination geometry and intermetallic linking modes.
With the aim of synthesizing air-stable pentagonal-bipyramidal Dy(III) complexes with a rigid equatorial plane, a pentadentate chelating ligand was used in this work, namely pyridyl-2,6-diacetylbis(salicylhydrazone) (H4L). Its reactions with Dy(OTf)3 gave three Dy(III) complexes, namely [Dyn(H2L)n][Dy(H2L)2]n (1), [Na3(Dy(H2L)2)3(THF)2]n∙5nCH3CN (2) and [Dy2(H2L)2(OMe)2(MeOH)2] (3). The attempted reactions of 3 with Ph3SiOH in the presence of NEt3 gave [Dyn(HL)n] (4). 1 has chain-structured coordination cation of [Dyn(H2L)n]n+ and mononuclear coordination anion of [Dy(H2L)2]−. The Dy(III) coordination unit of [Dy(H2L)2]− in 2 is similar to that of the anion of 1. Interestingly, three [Dy(H2L)2]− units in 2 sandwich two Na+ ions through Na-O bonds to build a linear pentanuclear heterometallic three-decker cluster unit [Na2(Dy(H2L)2)3]−, which is perpendicularly aligned with the neighboring ones through the linkage of Na+ ions, constructing a chain structure. 3 shows a dinuclear structure with the two [Dy(H2L)]+ units double-bridged by two MeO− linkers. 4 exhbits a chain structure similar to that of the coordination cation of [Dyn(H2L)n]n+ in 1. It is revealed from the magnetic measurements that 1, 2 and 4 show slow magnetic relaxation behaviors, and 3 is a field-induced single-molecule magnet. It revealed a tuning effect of SMM performance through coordination geometry and intermetallic linking modes.
We report here four Dy(III) complexes prepared from the ligand of pyridyl-2,6-diacetylbis(salicylhydrazone) through tuning reaction solvents and their ratio, with their structures diversified from mononuclear, dinuclear to one-dimensional and their SMM performance tuned through coordination geometry and intermetallic linking modes. [Display omitted] |
| ArticleNumber | 143398 |
| Author | Liang, Yuning Lv, Hongling Chen, Zilu Yao, Zaiheng Hu, Huancheng Liang, Huimin Zhou, Limin Liu, Dongcheng |
| Author_xml | – sequence: 1 givenname: Hongling orcidid: 0009-0009-0386-1176 surname: Lv fullname: Lv, Hongling – sequence: 2 givenname: Limin surname: Zhou fullname: Zhou, Limin – sequence: 3 givenname: Huimin surname: Liang fullname: Liang, Huimin – sequence: 4 givenname: Yuning surname: Liang fullname: Liang, Yuning – sequence: 5 givenname: Dongcheng surname: Liu fullname: Liu, Dongcheng email: ldcheng@mailbox.gxnu.edu.cn – sequence: 6 givenname: Zaiheng surname: Yao fullname: Yao, Zaiheng – sequence: 7 givenname: Huancheng orcidid: 0000-0001-6521-5086 surname: Hu fullname: Hu, Huancheng email: huhc@mailbox.gxnu.edu.cn – sequence: 8 givenname: Zilu orcidid: 0000-0003-1341-2330 surname: Chen fullname: Chen, Zilu email: zlchen@mailbox.gxnu.edu.cn |
| BookMark | eNqFkD1PwzAURT0UibbwF5BHGBLs58ZJNlDFR6RKHYDZcuwX5CqJIzuF9t-TqjAz3eWeq6uzILPe90jIDWcpZ1ze79LOt3EMe5MCgyzlKyHKYkbmjAEkUEh2SRYx7hhjfALmZPt2Ko_7gFT3lsbWf9NOf_Y4OkMDtvqgR-d76nqqacTgMFLfUHuMQ_DR7bvbqqruqPHd0OIB4xW5aHQb8fo3l-Tj-el9_Zpsti_V-nGTGJB8TIQVIDVAbW1ppdRlxqEsV5kUEsEKY0WDGcvqoq5BGFghy-uCS5Yj6Lyoc7Ek8rxrphsxYKOG4DodjoozdVKhdupPhTqpUGcVE_hwBnF69-UwqGgc9gatC2hGZb37b-IHMO1vpA |
| Cites_doi | 10.1021/jacs.6b02638 10.1021/acs.inorgchem.2c02513 10.1039/D0DT02305A 10.1039/C9QI01412H 10.3390/molecules26226908 10.1002/chem.201703755 10.1039/c2cc32360e 10.1021/acs.inorgchem.9b02948 10.1002/anie.201306329 10.1126/science.aav0652 10.1039/C9DT02047K 10.1039/C4CS00095A 10.1021/jacs.7b10130 10.1021/acs.inorgchem.0c00751 10.1021/jacs.4c07412 10.1039/c1dt11582k 10.1039/C7DT02736B 10.1002/advs.202308548 10.1021/jacs.1c05279 10.1002/anie.202407016 10.1002/chem.201705350 10.1039/C7SC04482H 10.1039/c3sc50843a 10.1039/C8DT03565B 10.1002/chem.200800344 10.1038/365141a0 10.1002/chem.200902064 10.1021/acs.inorgchem.1c03768 10.1038/nature23447 10.1021/ja00058a027 10.1039/D2CS00028H 10.1039/D0QI00487A 10.1021/ja0380751 10.1039/D1DT01519B 10.1038/ncomms3425 10.1021/ja309211d 10.1002/anie.201907686 10.1039/C8TC00353J 10.1021/acs.inorgchem.8b00059 10.1002/anie.201705426 10.1039/D0DT02881A 10.1021/acs.inorgchem.0c02148 10.1002/anie.200503564 10.1002/chem.201606029 10.1038/nature09478 10.1002/anie.202014993 10.1021/ja2017009 10.1002/chem.202000646 10.1021/acs.cgd.3c00140 10.1039/C5DT04147C 10.1039/C7CS00266A 10.1039/C9DT03253C |
| ContentType | Journal Article |
| Copyright | 2025 Elsevier B.V. |
| Copyright_xml | – notice: 2025 Elsevier B.V. |
| DBID | AAYXX CITATION |
| DOI | 10.1016/j.molstruc.2025.143398 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry Physics |
| ExternalDocumentID | 10_1016_j_molstruc_2025_143398 S0022286025020666 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JM 9JN AAEDT AAEDW AAIKJ AAKOC AALRI AAOAW AAQFI AARLI AATTM AAXKI AAXUO AAYWO ABGSF ABJNI ABMAC ABNEU ABUDA ACDAQ ACFVG ACGFS ACLOT ACRLP ACVFH ADBBV ADCNI ADECG ADEZE ADUVX AEBSH AEHWI AEIPS AEKER AENEX AEUPX AFJKZ AFPUW AFTJW AFXIZ AFZHZ AGHFR AGUBO AGYEJ AHHHB AIEXJ AIGII AIIUN AIKHN AITUG AIVDX AJSZI AKBMS AKRWK AKYEP ALMA_UNASSIGNED_HOLDINGS AMRAJ ANKPU APXCP AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC EFKBS EFLBG EO8 EO9 EP2 EP3 F5P FDB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA IHE J1W KOM M36 M41 MO0 N9A O-L O9- OAUVE OGIMB OZT P-8 P-9 P2P PC. Q38 RNS ROL RPZ SDF SDG SES SEW SPC SPCBC SSK SSQ SSU SSZ T5K TN5 UPT XPP YK3 YQT ZMT ~02 ~G- ~HD 29L 3O- 53G 9DU AAQXK AAYXX ABEFU ABFNM ABWVN ABXDB ACNNM ACRPL ADIYS ADMUD ADNMO AGQPQ AGRDE AJQLL ASPBG AVWKF AZFZN CITATION EJD FEDTE FGOYB HMU HVGLF HZ~ H~9 R2- SCB SCH UQL WUQ XOL |
| ID | FETCH-LOGICAL-c261t-3d326a22bdd9d66a95129945636e2d3cd3fe505b8bb23c24e07b81607e2a78b73 |
| ISICitedReferencesCount | 0 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=001551931500001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 0022-2860 |
| IngestDate | Thu Nov 27 01:08:19 EST 2025 Sat Nov 29 17:05:00 EST 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Chain Slow magnetic relaxation Dinuclear Dysprosium(III) complexes Pentagonal-bipyramid |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c261t-3d326a22bdd9d66a95129945636e2d3cd3fe505b8bb23c24e07b81607e2a78b73 |
| ORCID | 0000-0001-6521-5086 0009-0009-0386-1176 0000-0003-1341-2330 |
| ParticipantIDs | crossref_primary_10_1016_j_molstruc_2025_143398 elsevier_sciencedirect_doi_10_1016_j_molstruc_2025_143398 |
| PublicationCentury | 2000 |
| PublicationDate | 2025-12-25 |
| PublicationDateYYYYMMDD | 2025-12-25 |
| PublicationDate_xml | – month: 12 year: 2025 text: 2025-12-25 day: 25 |
| PublicationDecade | 2020 |
| PublicationTitle | Journal of molecular structure |
| PublicationYear | 2025 |
| Publisher | Elsevier B.V |
| Publisher_xml | – name: Elsevier B.V |
| References | Kalita, Ahmed, Bar, Dey, Jana, Rajaraman, Sutter, Chandrasekhar (bib0047) 2020; 59 Díaz-Ortega, Herrera, Dey, Nojiri, Rajaraman, Colacio (bib0011) 2020; 7 Castro-Alvarez, Gil, Llanos, Aravena (bib0012) 2020; 7 Bazhenova, Kopotkov, Korchagin, Manakin, Zorina, Simonov, Yakushev, Mironov, Vasiliev, Maximova, Yagubskii (bib0035) 2021; 26 Sutter, Béreau, Jubault, Bretosh, Pichon, Duhayon (bib0027) 2022; 51 Luo, Liao, Song, Huang, Tian, Sun, Zhu, Yuan, Luo, Liu, Xu, Feng (bib0015) 2011; 40 Xu, Luo, Li, Zhai, Zheng (bib0020) 2024; 11 Zhu, Paul, Zhao, Wu, Ying, Ungur, Wernsdorfer, Meyer, Tang (bib0024) 2024; 146 Sessoli, Gatteschi, Caneschi, Novak (bib0001) 1993; 365 Acharya, Ahmed, Gonzalez, Kumar, Cador, Singh, Pointillart, Chandrasekhar (bib0045) 2020; 49 Bhanja, Schulze, Herchel, Moreno-Pineda, Wernsdorfer, Ray (bib0016) 2020; 59 Zhu, Xiong, Gao, Li, Zhang, Wang, Zhang, Powell, Gao (bib0049) 2017; 46 Habib, Lin, Long, Korobkov, Wernsdorfer, Murugesu (bib0007) 2011; 133 Goodwin, Ortu, Reta, Chilton, Mills (bib0021) 2017; 548 Zhu, Zhao, Feng, Liu, Ying, Li, Zhang, Tang (bib0019) 2021; 143 Yu, Hu, Zou, Liu, Liang, Liang, Chen (bib0037) 2022; 61 Abbasi, Quinn, Alexandropoulos, Damjanović, Wernsdorfer, Escuer, Mayans, Pilkington, Stamatatos (bib0010) 2017; 139 Liu, Chen, Liu, Vieru, Ungur, Jia, Chibotaru, Lan, Wernsdorfer, Gao, Chen, Tong (bib0028) 2016; 138 Ungur, Lin, Tang, Chibotaru (bib0003) 2014; 43 Li, Wu, Yang, Ke, Yin, Shi, Wang, Wei, Xie, Chen (bib0050) 2017; 23 Mannini, Pineider, Danieli, Totti, Sorace, Sainctavit, Arrio, Otero, Joly, Cezar, Cornia, Sessoli (bib0005) 2010; 468 Zhang, Liu, Vieru, Xu, Gao, Wang, Shi, Chibotaru, Gao, Cheng, Powell (bib0052) 2018; 24 Yu, Chen, Hu, Li, Liang, Liu, Zou, Yao, Liang (bib0040) 2019; 48 Huang, Wang, Jiang, Gao, Wu, Gao, Wei, Hong (bib0013) 2008; 14 Guo, Day, Chen, Tong, Mansikkamäki, Layfield (bib0023) 2017; 56 Liu, Chen, Zheng, Lin, Ungur, Wernsdorfer, Chibotaru, Tong (bib0025) 2013; 4 Jiang, Sun, Yang, Yin, Ke, Han, Wei, Xie, Chen (bib0048) 2018; 6 Canaj, Dey, Martí, Wilson, Rajaraman, Murrie (bib0030) 2019; 58 Xiong, Wang, Jiang, Gai, Xu, Su, Li, Yuan, Hong (bib0034) 2012; 48 Liu, Fu, Gao, Zhang, Sun, Su, Liu (bib0008) 2003; 125 Wang, Li, Wu, Chen, Wan, Huang, Liu, Liu, Reta, Giansiracusa, Wang, Chilton, Tong (bib0018) 2021; 60 Li, Wang, Sun, Zhang, Wang (bib0042) 2022; 61 Tang, Hewitt, Madhu, Chastanet, Wernsdorfer, Anson, Benelli, Sessoli, Powell (bib0044) 2006; 45 Ungur, Langley, Hooper, Moubaraki, Brechin, Murray, Chibotaru (bib0004) 2012; 134 Bar, Kalita, Sutter, Chandrasekhar (bib0041) 2018; 57 Long, Tolpygin, Cherkasov, Lyssenko, Guari, Larionova, Trifonov (bib0033) 2020; 49 Langley, Wielechowski, Vieru, Chilton, Moubaraki, Abrahams, Chibotaru, Murray (bib0017) 2013; 52 Fahrendorf, Atodiresei, Besson, Caciuc, Matthes, Blügel, Kögerler, Bürgler, Schneider (bib0006) 2013; 4 Bhowmick, Roehl, Neilson, Rappé, Shores (bib0009) 2018; 9 Ding, Han, Zhai, Reta, Chilton, Winpenny, Zheng (bib0039) 2020; 26 Guo, Day, Chen, Tong, Mansikkamäki, Layfield (bib0022) 2018; 362 Li, Su, Liu, Xu, Wang (bib0036) 2019; 48 Bartolomé, Arauzo, Luzón, Melnic, Shova, Prodius, Nlebedim, Bartolomé, Bartolomé (bib0051) 2019; 48 Huang, Zhang, Wu, Shao, Zhao, Huang, Wang (bib0046) 2015; 44 Liu, Chen, Liu, Chen, Huang, Wu, Wang, Liu, Tong (bib0038) 2020; 59 Rosado Piquer, Dreiser, Sañudo (bib0053) 2021; 50 Zhong, Hu, Luo, Peng, Liu, Anson, Powell, Wen (bib0043) 2023; 23 Chen, Liu, Lan, Zhong, Mansikkamäki, Ungur, Li, Jia, Chibotaru, Han, Wernsdorfer, Chen, Tong (bib0029) 2017; 23 Sachse, Penkova, Noël, Dechert, Varzatskii, Fritsky, Meyer (bib0032) 2008 Sessoli, Tsai, Schake, Wang, Vincent, Folting, Gatteschi, Christou, Hendrickson (bib0002) 1993; 115 Liu, Chen, Tong (bib0026) 2018; 47 Zheng, Lan, Wernsdorfer, Anson, Powell (bib0014) 2009; 15 Wang, Luo, Zheng (bib0031) 2024; 63 Fahrendorf (10.1016/j.molstruc.2025.143398_bib0006) 2013; 4 Huang (10.1016/j.molstruc.2025.143398_bib0013) 2008; 14 Li (10.1016/j.molstruc.2025.143398_bib0050) 2017; 23 Abbasi (10.1016/j.molstruc.2025.143398_bib0010) 2017; 139 Díaz-Ortega (10.1016/j.molstruc.2025.143398_bib0011) 2020; 7 Li (10.1016/j.molstruc.2025.143398_bib0036) 2019; 48 Bar (10.1016/j.molstruc.2025.143398_bib0041) 2018; 57 Bhowmick (10.1016/j.molstruc.2025.143398_bib0009) 2018; 9 Zhong (10.1016/j.molstruc.2025.143398_bib0043) 2023; 23 Sessoli (10.1016/j.molstruc.2025.143398_bib0001) 1993; 365 Mannini (10.1016/j.molstruc.2025.143398_bib0005) 2010; 468 Ungur (10.1016/j.molstruc.2025.143398_bib0003) 2014; 43 Castro-Alvarez (10.1016/j.molstruc.2025.143398_bib0012) 2020; 7 Canaj (10.1016/j.molstruc.2025.143398_bib0030) 2019; 58 Chen (10.1016/j.molstruc.2025.143398_bib0029) 2017; 23 Tang (10.1016/j.molstruc.2025.143398_bib0044) 2006; 45 Zheng (10.1016/j.molstruc.2025.143398_bib0014) 2009; 15 Liu (10.1016/j.molstruc.2025.143398_bib0028) 2016; 138 Bhanja (10.1016/j.molstruc.2025.143398_bib0016) 2020; 59 Bazhenova (10.1016/j.molstruc.2025.143398_bib0035) 2021; 26 Zhang (10.1016/j.molstruc.2025.143398_bib0052) 2018; 24 Wang (10.1016/j.molstruc.2025.143398_bib0018) 2021; 60 Guo (10.1016/j.molstruc.2025.143398_bib0022) 2018; 362 Ungur (10.1016/j.molstruc.2025.143398_bib0004) 2012; 134 Liu (10.1016/j.molstruc.2025.143398_bib0025) 2013; 4 Sutter (10.1016/j.molstruc.2025.143398_bib0027) 2022; 51 Goodwin (10.1016/j.molstruc.2025.143398_bib0021) 2017; 548 Kalita (10.1016/j.molstruc.2025.143398_bib0047) 2020; 59 Liu (10.1016/j.molstruc.2025.143398_bib0026) 2018; 47 Huang (10.1016/j.molstruc.2025.143398_bib0046) 2015; 44 Zhu (10.1016/j.molstruc.2025.143398_bib0024) 2024; 146 Acharya (10.1016/j.molstruc.2025.143398_bib0045) 2020; 49 Luo (10.1016/j.molstruc.2025.143398_bib0015) 2011; 40 Xu (10.1016/j.molstruc.2025.143398_bib0020) 2024; 11 Long (10.1016/j.molstruc.2025.143398_bib0033) 2020; 49 Zhu (10.1016/j.molstruc.2025.143398_bib0049) 2017; 46 Wang (10.1016/j.molstruc.2025.143398_bib0031) 2024; 63 Sachse (10.1016/j.molstruc.2025.143398_bib0032) 2008 Xiong (10.1016/j.molstruc.2025.143398_bib0034) 2012; 48 Liu (10.1016/j.molstruc.2025.143398_bib0038) 2020; 59 Li (10.1016/j.molstruc.2025.143398_bib0042) 2022; 61 Rosado Piquer (10.1016/j.molstruc.2025.143398_bib0053) 2021; 50 Yu (10.1016/j.molstruc.2025.143398_bib0040) 2019; 48 Sessoli (10.1016/j.molstruc.2025.143398_bib0002) 1993; 115 Langley (10.1016/j.molstruc.2025.143398_bib0017) 2013; 52 Zhu (10.1016/j.molstruc.2025.143398_bib0019) 2021; 143 Ding (10.1016/j.molstruc.2025.143398_bib0039) 2020; 26 Bartolomé (10.1016/j.molstruc.2025.143398_bib0051) 2019; 48 Jiang (10.1016/j.molstruc.2025.143398_bib0048) 2018; 6 Yu (10.1016/j.molstruc.2025.143398_bib0037) 2022; 61 Habib (10.1016/j.molstruc.2025.143398_bib0007) 2011; 133 Liu (10.1016/j.molstruc.2025.143398_bib0008) 2003; 125 Guo (10.1016/j.molstruc.2025.143398_bib0023) 2017; 56 |
| References_xml | – volume: 46 start-page: 14114 year: 2017 end-page: 14121 ident: bib0049 article-title: A family of one-dimensional lanthanide complexes bridged by two distinct carboxylate ligands with the Dy analogue displaying magnetic relaxation behaviour publication-title: Dalton Trans – volume: 40 start-page: 12651 year: 2011 end-page: 12655 ident: bib0015 article-title: Chiral 1D Dy(III) compound showing slow magnetic relaxation publication-title: Dalton Trans. – volume: 138 start-page: 5441 year: 2016 end-page: 5450 ident: bib0028 article-title: A stable pentagonal bipyramidal Dy(III) single-ion magnet with a record magnetization reversal barrier over 1000 K publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 16679 year: 2019 end-page: 16686 ident: bib0040 article-title: Two mononuclear dysprosium(III) complexes with their slow magnetic relaxation behaviors tuned by coordination geometry publication-title: Dalton Trans. – volume: 7 start-page: 2478 year: 2020 end-page: 2486 ident: bib0012 article-title: High performance single-molecule magnets, orbach or Raman relaxation suppression? publication-title: Inorg. Chem. Front. – volume: 49 start-page: 13110 year: 2020 end-page: 13122 ident: bib0045 article-title: Slow magnetic relaxation in a homo dinuclear Dy(III) complex in a pentagonal bipyramidal geometry publication-title: Dalton Trans. – volume: 56 start-page: 11445 year: 2017 end-page: 11449 ident: bib0023 article-title: A dysprosium metallocene single-molecule magnet functioning at the axial limit publication-title: Angew. Chem., Int. Ed. – volume: 44 start-page: 20834 year: 2015 end-page: 20838 ident: bib0046 article-title: Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D publication-title: Dalton Trans. – volume: 14 start-page: 10340 year: 2008 end-page: 10347 ident: bib0013 article-title: Cobalt–Lanthanide coordination polymers constructed with metalloligands: a ferromagnetic coupled Quasi-1D Dy publication-title: Chem. Eur. J. – volume: 548 start-page: 439 year: 2017 end-page: 442 ident: bib0021 article-title: Molecular magnetic hysteresis at 60 kelvin in dysprosocenium publication-title: Nature – volume: 365 start-page: 141 year: 1993 end-page: 143 ident: bib0001 article-title: Magnetic bistability in a metal-ion cluster publication-title: Nature – volume: 146 start-page: 18899 year: 2024 end-page: 18904 ident: bib0024 article-title: Record quantum tunneling time in an air-stable exchange-bias dysprosium macrocycle publication-title: J. Am. Chem. Soc. – volume: 51 start-page: 3280 year: 2022 end-page: 3313 ident: bib0027 article-title: Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry publication-title: Chem. Soc. Rev. – volume: 9 start-page: 6564 year: 2018 end-page: 6571 ident: bib0009 article-title: Slow magnetic relaxation in octahedral low-spin Ni(III) complexes publication-title: Chem. Sci. – volume: 59 start-page: 17929 year: 2020 end-page: 17944 ident: bib0016 article-title: Selective coordination of self-assembled hexanuclear [Ni publication-title: Inorg. Chem – start-page: 800 year: 2008 end-page: 806 ident: bib0032 article-title: Efficient syntheses of some versatile 3,5-bifunctional pyrazole building blocks publication-title: Synthesis – volume: 24 start-page: 6079 year: 2018 end-page: 6086 ident: bib0052 article-title: Coupling Influences SMM Properties for Pure 4 f Systems publication-title: Chem. Eur. J. – volume: 115 start-page: 1804 year: 1993 end-page: 1816 ident: bib0002 article-title: High-spin molecules: [Mn publication-title: J. Am. Chem. Soc. – volume: 468 start-page: 417 year: 2010 end-page: 421 ident: bib0005 article-title: Quantum tunnelling of the magnetization in a monolayer of oriented single-molecule magnets publication-title: Nature – volume: 11 year: 2024 ident: bib0020 article-title: Bis-Alkoxide Dysprosium(III) crown ether complexes exhibit tunable air stability and record energy barrier publication-title: Adv. Sci – volume: 48 start-page: 15386 year: 2019 end-page: 15396 ident: bib0051 article-title: High relaxation barrier in neodymium furoate-based field-induced SMMs publication-title: Dalton Trans. – volume: 23 start-page: 5708 year: 2017 end-page: 5715 ident: bib0029 article-title: Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy publication-title: Chem. Eur. J. – volume: 23 start-page: 17775 year: 2017 end-page: 17787 ident: bib0050 article-title: Experimental and theoretical interpretation on the magnetic behavior in a series of pentagonal-bipyramidal Dy publication-title: Chem. Eur. J. – volume: 4 start-page: 3310 year: 2013 end-page: 3316 ident: bib0025 article-title: Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D publication-title: Chem. Sci. – volume: 63 year: 2024 ident: bib0031 article-title: Organolanthanide single-molecule magnets with heterocyclic ligands publication-title: Angew. Chem., Int. Ed – volume: 23 start-page: 4912 year: 2023 end-page: 4920 ident: bib0043 article-title: Nine-Coordinate LnIII-based one-dimensional complexes: synthesis and magnetic properties publication-title: Cryst. Growth Des. – volume: 7 start-page: 689 year: 2020 end-page: 699 ident: bib0011 article-title: The effect of the electronic structure and flexibility of the counteranions on magnetization relaxation in [Dy(L) publication-title: Inorg. Chem. Front. – volume: 15 start-page: 12566 year: 2009 end-page: 12570 ident: bib0014 article-title: Polymerisation of the dysprosium acetate dimer switches on single-chain magnetism publication-title: Chem. Eur. J. – volume: 61 start-page: 3655 year: 2022 end-page: 3663 ident: bib0037 article-title: Two heterometallic nanoclusters [Dy publication-title: Inorg. Chem. – volume: 49 start-page: 11890 year: 2020 end-page: 11901 ident: bib0033 article-title: Single-molecule magnet behavior in heterolopetic Dy publication-title: Dalton Trans. – volume: 48 start-page: 7456 year: 2012 end-page: 7458 ident: bib0034 article-title: Heterometallic thiacalix[4]arene-supported Na publication-title: Chem. Commun. – volume: 60 start-page: 5299 year: 2021 end-page: 5306 ident: bib0018 article-title: Opening magnetic hysteresis by axial ferromagnetic coupling: from mono-decker to double-decker metallacrown publication-title: Angew. Chem., Int. Ed – volume: 26 start-page: 6908 year: 2021 ident: bib0035 article-title: A Series of Novel Pentagonal-Bipyramidal Erbium(III) Complexes with Acyclic Chelating N publication-title: Molecules – volume: 58 start-page: 14146 year: 2019 end-page: 14151 ident: bib0030 article-title: Insight into publication-title: Angew. Chem., Int. Ed – volume: 59 start-page: 6603 year: 2020 end-page: 6612 ident: bib0047 article-title: Pentagonal bipyramidal Ln(III) complexes containing an axial phosphine oxide ligand: field-induced single-ion magnetism behavior of the Dy(III) analogues publication-title: Inorg. Chem. – volume: 4 start-page: 2425 year: 2013 ident: bib0006 article-title: Accessing 4f-states in single-molecule spintronics publication-title: Nat. Commun. – volume: 139 start-page: 15644 year: 2017 end-page: 15647 ident: bib0010 article-title: Transition metal single-molecule magnets: a {Mn publication-title: J. Am. Chem. Soc. – volume: 59 start-page: 687 year: 2020 end-page: 694 ident: bib0038 article-title: Cyanometallate-bridged didysprosium single-molecule magnets constructed with single-ion magnet building block publication-title: Inorg. Chem. – volume: 133 start-page: 8830 year: 2011 end-page: 8833 ident: bib0007 article-title: The use of magnetic dilution to elucidate the slow magnetic relaxation effects of a Dy publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 2213 year: 2019 end-page: 2219 ident: bib0036 article-title: A new air and moisture-stable pentagonal-bipyramidal Dy publication-title: Dalton Trans. – volume: 52 start-page: 12014 year: 2013 end-page: 12019 ident: bib0017 article-title: A {Cr publication-title: Angew. Chem., Int. Ed. – volume: 143 start-page: 10077 year: 2021 end-page: 10082 ident: bib0019 article-title: Air-Stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K publication-title: J. Am. Chem. Soc. – volume: 50 start-page: 9589 year: 2021 end-page: 9597 ident: bib0053 article-title: Heterometallic Co–Dy SMMs grafted on iron oxide nanoparticles publication-title: Dalton Trans. – volume: 134 start-page: 18554 year: 2012 end-page: 18557 ident: bib0004 article-title: Net Toroidal Magnetic Moment in the Ground State of a {Dy publication-title: J. Am. Chem. Soc. – volume: 61 start-page: 17537 year: 2022 end-page: 17549 ident: bib0042 article-title: Solvent modification of the structures and magnetic properties of a series of dysprosium(III) single-molecule magnets publication-title: Inorg. Chem. – volume: 47 start-page: 2431 year: 2018 end-page: 2453 ident: bib0026 article-title: Symmetry strategies for high performance lanthanide-based single-molecule magnets publication-title: Chem. Soc. Rev. – volume: 26 start-page: 5893 year: 2020 end-page: 5902 ident: bib0039 article-title: A study of magnetic relaxation in dysprosium(III) single-molecule magnets publication-title: Chem. Eur. J. – volume: 43 start-page: 6894 year: 2014 end-page: 6905 ident: bib0003 article-title: Single-molecule toroics in Ising-type lanthanide molecular clusters publication-title: Chem. Soc. Rev. – volume: 6 start-page: 4273 year: 2018 end-page: 4280 ident: bib0048 article-title: Excess axial electrostatic repulsion as a criterion for pentagonal bipyramidal Dy publication-title: J. Mater. Chem. C. – volume: 57 start-page: 2398 year: 2018 end-page: 2401 ident: bib0041 article-title: Pentagonal-Bipyramid Ln(III) complexes exhibiting single-ion-magnet behavior: a rational synthetic approach for a rigid equatorial plane publication-title: Inorg. Chem. – volume: 125 start-page: 13976 year: 2003 end-page: 13977 ident: bib0008 article-title: An azide-bridged homospin single-chain magnet: [Co(2,2′-bithiazoline)(N publication-title: J. Am. Chem. Soc. – volume: 362 start-page: 1400 year: 2018 end-page: 1403 ident: bib0022 article-title: Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet publication-title: Science – volume: 45 start-page: 1729 year: 2006 end-page: 1733 ident: bib0044 article-title: Dysprosium triangles showing single-molecule magnet behavior of thermally excited spin states publication-title: Angew. Chem., Int. Ed. – volume: 138 start-page: 5441 issue: 16 year: 2016 ident: 10.1016/j.molstruc.2025.143398_bib0028 article-title: A stable pentagonal bipyramidal Dy(III) single-ion magnet with a record magnetization reversal barrier over 1000 K publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.6b02638 – volume: 61 start-page: 17537 issue: 44 year: 2022 ident: 10.1016/j.molstruc.2025.143398_bib0042 article-title: Solvent modification of the structures and magnetic properties of a series of dysprosium(III) single-molecule magnets publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.2c02513 – volume: 49 start-page: 11890 issue: 34 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0033 article-title: Single-molecule magnet behavior in heterolopetic Dy3+-chloro-diazabutadiene complexes: influence of the nuclearity and ligand redox state publication-title: Dalton Trans. doi: 10.1039/D0DT02305A – volume: 7 start-page: 689 issue: 3 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0011 article-title: The effect of the electronic structure and flexibility of the counteranions on magnetization relaxation in [Dy(L)2(H2O)5]3+ (L = phosphine oxide derivative) pentagonal bipyramidal SIMs publication-title: Inorg. Chem. Front. doi: 10.1039/C9QI01412H – volume: 26 start-page: 6908 issue: 22 year: 2021 ident: 10.1016/j.molstruc.2025.143398_bib0035 article-title: A Series of Novel Pentagonal-Bipyramidal Erbium(III) Complexes with Acyclic Chelating N3O2 Schiff-Base Ligands: Synthesis, Structure, and Magnetism publication-title: Molecules doi: 10.3390/molecules26226908 – volume: 23 start-page: 17775 issue: 70 year: 2017 ident: 10.1016/j.molstruc.2025.143398_bib0050 article-title: Experimental and theoretical interpretation on the magnetic behavior in a series of pentagonal-bipyramidal DyIII single-ion magnets publication-title: Chem. Eur. J. doi: 10.1002/chem.201703755 – volume: 48 start-page: 7456 issue: 60 year: 2012 ident: 10.1016/j.molstruc.2025.143398_bib0034 article-title: Heterometallic thiacalix[4]arene-supported Na2NiII12LnIII2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb) publication-title: Chem. Commun. doi: 10.1039/c2cc32360e – volume: 59 start-page: 687 issue: 1 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0038 article-title: Cyanometallate-bridged didysprosium single-molecule magnets constructed with single-ion magnet building block publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.9b02948 – volume: 52 start-page: 12014 issue: 46 year: 2013 ident: 10.1016/j.molstruc.2025.143398_bib0017 article-title: A {CrIII2DyIII2} single-molecule magnet: enhancing the blocking temperature through 3D magnetic exchange publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201306329 – volume: 362 start-page: 1400 issue: 6421 year: 2018 ident: 10.1016/j.molstruc.2025.143398_bib0022 article-title: Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet publication-title: Science doi: 10.1126/science.aav0652 – volume: 48 start-page: 15386 issue: 41 year: 2019 ident: 10.1016/j.molstruc.2025.143398_bib0051 article-title: High relaxation barrier in neodymium furoate-based field-induced SMMs publication-title: Dalton Trans. doi: 10.1039/C9DT02047K – volume: 43 start-page: 6894 issue: 20 year: 2014 ident: 10.1016/j.molstruc.2025.143398_bib0003 article-title: Single-molecule toroics in Ising-type lanthanide molecular clusters publication-title: Chem. Soc. Rev. doi: 10.1039/C4CS00095A – volume: 139 start-page: 15644 issue: 44 year: 2017 ident: 10.1016/j.molstruc.2025.143398_bib0010 article-title: Transition metal single-molecule magnets: a {Mn31} nanosized cluster with a large energy barrier of ∼60 K and magnetic hysteresis at ∼5 K publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.7b10130 – volume: 59 start-page: 6603 issue: 9 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0047 article-title: Pentagonal bipyramidal Ln(III) complexes containing an axial phosphine oxide ligand: field-induced single-ion magnetism behavior of the Dy(III) analogues publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.0c00751 – volume: 146 start-page: 18899 issue: 28 year: 2024 ident: 10.1016/j.molstruc.2025.143398_bib0024 article-title: Record quantum tunneling time in an air-stable exchange-bias dysprosium macrocycle publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.4c07412 – volume: 40 start-page: 12651 issue: 47 year: 2011 ident: 10.1016/j.molstruc.2025.143398_bib0015 article-title: Chiral 1D Dy(III) compound showing slow magnetic relaxation publication-title: Dalton Trans. doi: 10.1039/c1dt11582k – volume: 46 start-page: 14114 issue: 41 year: 2017 ident: 10.1016/j.molstruc.2025.143398_bib0049 article-title: A family of one-dimensional lanthanide complexes bridged by two distinct carboxylate ligands with the Dy analogue displaying magnetic relaxation behaviour publication-title: Dalton Trans doi: 10.1039/C7DT02736B – volume: 11 issue: 17 year: 2024 ident: 10.1016/j.molstruc.2025.143398_bib0020 article-title: Bis-Alkoxide Dysprosium(III) crown ether complexes exhibit tunable air stability and record energy barrier publication-title: Adv. Sci doi: 10.1002/advs.202308548 – volume: 143 start-page: 10077 issue: 27 year: 2021 ident: 10.1016/j.molstruc.2025.143398_bib0019 article-title: Air-Stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.1c05279 – volume: 63 issue: 38 year: 2024 ident: 10.1016/j.molstruc.2025.143398_bib0031 article-title: Organolanthanide single-molecule magnets with heterocyclic ligands publication-title: Angew. Chem., Int. Ed doi: 10.1002/anie.202407016 – volume: 24 start-page: 6079 issue: 23 year: 2018 ident: 10.1016/j.molstruc.2025.143398_bib0052 article-title: Coupling Influences SMM Properties for Pure 4 f Systems publication-title: Chem. Eur. J. doi: 10.1002/chem.201705350 – volume: 9 start-page: 6564 issue: 31 year: 2018 ident: 10.1016/j.molstruc.2025.143398_bib0009 article-title: Slow magnetic relaxation in octahedral low-spin Ni(III) complexes publication-title: Chem. Sci. doi: 10.1039/C7SC04482H – volume: 4 start-page: 3310 issue: 8 year: 2013 ident: 10.1016/j.molstruc.2025.143398_bib0025 article-title: Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh publication-title: Chem. Sci. doi: 10.1039/c3sc50843a – volume: 48 start-page: 2213 issue: 6 year: 2019 ident: 10.1016/j.molstruc.2025.143398_bib0036 article-title: A new air and moisture-stable pentagonal-bipyramidal DyIII single-ion magnet based on the HMPA ligand publication-title: Dalton Trans. doi: 10.1039/C8DT03565B – volume: 14 start-page: 10340 issue: 33 year: 2008 ident: 10.1016/j.molstruc.2025.143398_bib0013 article-title: Cobalt–Lanthanide coordination polymers constructed with metalloligands: a ferromagnetic coupled Quasi-1D Dy3+ chain showing slow relaxation publication-title: Chem. Eur. J. doi: 10.1002/chem.200800344 – volume: 365 start-page: 141 issue: 6442 year: 1993 ident: 10.1016/j.molstruc.2025.143398_bib0001 article-title: Magnetic bistability in a metal-ion cluster publication-title: Nature doi: 10.1038/365141a0 – volume: 15 start-page: 12566 issue: 46 year: 2009 ident: 10.1016/j.molstruc.2025.143398_bib0014 article-title: Polymerisation of the dysprosium acetate dimer switches on single-chain magnetism publication-title: Chem. Eur. J. doi: 10.1002/chem.200902064 – volume: 61 start-page: 3655 issue: 8 year: 2022 ident: 10.1016/j.molstruc.2025.143398_bib0037 article-title: Two heterometallic nanoclusters [DyIII4NiII8] and [DyIII10MnIII4MnII2]: structure, assembly mechanism, and magnetic properties publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.1c03768 – volume: 548 start-page: 439 issue: 7668 year: 2017 ident: 10.1016/j.molstruc.2025.143398_bib0021 article-title: Molecular magnetic hysteresis at 60 kelvin in dysprosocenium publication-title: Nature doi: 10.1038/nature23447 – volume: 115 start-page: 1804 issue: 5 year: 1993 ident: 10.1016/j.molstruc.2025.143398_bib0002 article-title: High-spin molecules: [Mn12O12(O2CR)16(H2O)4] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00058a027 – volume: 51 start-page: 3280 issue: 8 year: 2022 ident: 10.1016/j.molstruc.2025.143398_bib0027 article-title: Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry publication-title: Chem. Soc. Rev. doi: 10.1039/D2CS00028H – volume: 7 start-page: 2478 issue: 13 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0012 article-title: High performance single-molecule magnets, orbach or Raman relaxation suppression? publication-title: Inorg. Chem. Front. doi: 10.1039/D0QI00487A – volume: 125 start-page: 13976 issue: 46 year: 2003 ident: 10.1016/j.molstruc.2025.143398_bib0008 article-title: An azide-bridged homospin single-chain magnet: [Co(2,2′-bithiazoline)(N3)2]n publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0380751 – volume: 50 start-page: 9589 issue: 27 year: 2021 ident: 10.1016/j.molstruc.2025.143398_bib0053 article-title: Heterometallic Co–Dy SMMs grafted on iron oxide nanoparticles publication-title: Dalton Trans. doi: 10.1039/D1DT01519B – volume: 4 start-page: 2425 issue: 1 year: 2013 ident: 10.1016/j.molstruc.2025.143398_bib0006 article-title: Accessing 4f-states in single-molecule spintronics publication-title: Nat. Commun. doi: 10.1038/ncomms3425 – volume: 134 start-page: 18554 issue: 45 year: 2012 ident: 10.1016/j.molstruc.2025.143398_bib0004 article-title: Net Toroidal Magnetic Moment in the Ground State of a {Dy6}-Triethanolamine Ring publication-title: J. Am. Chem. Soc. doi: 10.1021/ja309211d – volume: 58 start-page: 14146 issue: 40 year: 2019 ident: 10.1016/j.molstruc.2025.143398_bib0030 article-title: Insight into D6h symmetry: targeting strong axiality in stable dysprosium(III) hexagonal bipyramidal single-ion magnets publication-title: Angew. Chem., Int. Ed doi: 10.1002/anie.201907686 – volume: 6 start-page: 4273 issue: 15 year: 2018 ident: 10.1016/j.molstruc.2025.143398_bib0048 article-title: Excess axial electrostatic repulsion as a criterion for pentagonal bipyramidal DyIII single-ion magnets with high Ueff and TB publication-title: J. Mater. Chem. C. doi: 10.1039/C8TC00353J – volume: 57 start-page: 2398 issue: 5 year: 2018 ident: 10.1016/j.molstruc.2025.143398_bib0041 article-title: Pentagonal-Bipyramid Ln(III) complexes exhibiting single-ion-magnet behavior: a rational synthetic approach for a rigid equatorial plane publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.8b00059 – volume: 56 start-page: 11445 issue: 38 year: 2017 ident: 10.1016/j.molstruc.2025.143398_bib0023 article-title: A dysprosium metallocene single-molecule magnet functioning at the axial limit publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201705426 – volume: 49 start-page: 13110 issue: 37 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0045 article-title: Slow magnetic relaxation in a homo dinuclear Dy(III) complex in a pentagonal bipyramidal geometry publication-title: Dalton Trans. doi: 10.1039/D0DT02881A – volume: 59 start-page: 17929 issue: 24 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0016 article-title: Selective coordination of self-assembled hexanuclear [Ni4Ln2] and [Ni2Mn2Ln2] (Ln = DyIII, TbIII, and HoIII) complexes: stepwise synthesis, structures, and magnetic properties publication-title: Inorg. Chem doi: 10.1021/acs.inorgchem.0c02148 – volume: 45 start-page: 1729 issue: 11 year: 2006 ident: 10.1016/j.molstruc.2025.143398_bib0044 article-title: Dysprosium triangles showing single-molecule magnet behavior of thermally excited spin states publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200503564 – volume: 23 start-page: 5708 issue: 24 year: 2017 ident: 10.1016/j.molstruc.2025.143398_bib0029 article-title: Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal DyIII Single-Ion Magnet publication-title: Chem. Eur. J. doi: 10.1002/chem.201606029 – volume: 468 start-page: 417 issue: 7322 year: 2010 ident: 10.1016/j.molstruc.2025.143398_bib0005 article-title: Quantum tunnelling of the magnetization in a monolayer of oriented single-molecule magnets publication-title: Nature doi: 10.1038/nature09478 – volume: 60 start-page: 5299 issue: 10 year: 2021 ident: 10.1016/j.molstruc.2025.143398_bib0018 article-title: Opening magnetic hysteresis by axial ferromagnetic coupling: from mono-decker to double-decker metallacrown publication-title: Angew. Chem., Int. Ed doi: 10.1002/anie.202014993 – volume: 133 start-page: 8830 issue: 23 year: 2011 ident: 10.1016/j.molstruc.2025.143398_bib0007 article-title: The use of magnetic dilution to elucidate the slow magnetic relaxation effects of a Dy2 single-molecule magnet publication-title: J. Am. Chem. Soc. doi: 10.1021/ja2017009 – start-page: 800 issue: 05 year: 2008 ident: 10.1016/j.molstruc.2025.143398_bib0032 article-title: Efficient syntheses of some versatile 3,5-bifunctional pyrazole building blocks publication-title: Synthesis – volume: 26 start-page: 5893 issue: 26 year: 2020 ident: 10.1016/j.molstruc.2025.143398_bib0039 article-title: A study of magnetic relaxation in dysprosium(III) single-molecule magnets publication-title: Chem. Eur. J. doi: 10.1002/chem.202000646 – volume: 23 start-page: 4912 issue: 7 year: 2023 ident: 10.1016/j.molstruc.2025.143398_bib0043 article-title: Nine-Coordinate LnIII-based one-dimensional complexes: synthesis and magnetic properties publication-title: Cryst. Growth Des. doi: 10.1021/acs.cgd.3c00140 – volume: 44 start-page: 20834 issue: 48 year: 2015 ident: 10.1016/j.molstruc.2025.143398_bib0046 article-title: Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D5h symmetry publication-title: Dalton Trans. doi: 10.1039/C5DT04147C – volume: 47 start-page: 2431 issue: 7 year: 2018 ident: 10.1016/j.molstruc.2025.143398_bib0026 article-title: Symmetry strategies for high performance lanthanide-based single-molecule magnets publication-title: Chem. Soc. Rev. doi: 10.1039/C7CS00266A – volume: 48 start-page: 16679 issue: 44 year: 2019 ident: 10.1016/j.molstruc.2025.143398_bib0040 article-title: Two mononuclear dysprosium(III) complexes with their slow magnetic relaxation behaviors tuned by coordination geometry publication-title: Dalton Trans. doi: 10.1039/C9DT03253C |
| SSID | ssj0001101 |
| Score | 2.4502795 |
| Snippet | •A ligand with pentadentate coordination pocket and two phenolic hydroxyl groups;•Structural diversity from mononuclear, dinuclear, to one-dimensional;•SMM... |
| SourceID | crossref elsevier |
| SourceType | Index Database Publisher |
| StartPage | 143398 |
| SubjectTerms | Chain Dinuclear Dysprosium(III) complexes Pentagonal-bipyramid Slow magnetic relaxation |
| Title | Structure and slow magnetic relaxation in a series of dysprosium(III) complexes |
| URI | https://dx.doi.org/10.1016/j.molstruc.2025.143398 |
| Volume | 1348 |
| WOSCitedRecordID | wos001551931500001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVESC databaseName: Elsevier SD Freedom Collection Journals 2021 issn: 0022-2860 databaseCode: AIEXJ dateStart: 19950101 customDbUrl: isFulltext: true dateEnd: 99991231 titleUrlDefault: https://www.sciencedirect.com omitProxy: false ssIdentifier: ssj0001101 providerName: Elsevier |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3Nb9MwFLfKBoILggFifMkHDqAqpbXT2j5O09DKYSAxpHKK7NhGmdpkWtauiH-e59hOCquAHbhElas8x3k_vffr6_tA6LUELzeSWiVKCp2AP04TmRKbgOuyjFluU2WbYRPs5ITPZuJTr_cj1sKs5qws-Xotzv-rqmENlO1KZ2-g7lYoLMBnUDpcQe1w_SfFf246wsb_Bep5ddVfyG-l8c2a53ItY36j7LsH8l1n9fcabGlduLHHfDqdumhBk25u1iHL8DqDXcTRuv067tnm96wan1a5IuHgG5vodLX0gYBF0aUCFSFkfbzcuvx1WUYRITpBxi7Tw1cyb1QLEO5nBrQWl_rumsFoAmWjfhT1NXvuQwtnAzhQc5KB22PQ3fBrA-3fHFubbhgz2c6yKCdzcjIv5xbaJWwswCTuHkyPZh9aRw7MaBSbzbsjbBSYb3-i7dxmg6-cPkD3g5rwgQfIQ9Qz5R66exjn--2hO03yb14_Qh9byGCADHaQwREyuIMMLkossYcMrizuIPMGAPMWt3B5jL68Pzo9PE7CoI0khx_QlwnVQOIlIUproScTKRwLFECt6cQQTXNNrQGmrLhShOYkNUOmuOtMaIhkXDH6BO2UVWmeIsxSnXIr7Ijlw9SkQ26VttRIq8bAvIncR-_iK8rOfT-V7M_q2UcivskssELP9jIAyV_ufXbj3Z6jex2MX6Ad-N68RLfz1WVRX7wKCPkJFCGJHw |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Structure+and+slow+magnetic+relaxation+in+a+series+of+dysprosium%28III%29+complexes&rft.jtitle=Journal+of+molecular+structure&rft.au=Lv%2C+Hongling&rft.au=Zhou%2C+Limin&rft.au=Liang%2C+Huimin&rft.au=Liang%2C+Yuning&rft.date=2025-12-25&rft.issn=0022-2860&rft.volume=1348&rft.spage=143398&rft_id=info:doi/10.1016%2Fj.molstruc.2025.143398&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_j_molstruc_2025_143398 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0022-2860&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0022-2860&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0022-2860&client=summon |