Adsorption kinetics and thermodynamics of metal complex acid dyes on silk fabric
This study reports the adsorption phenomena of metal complex acid dyes onto silk fabric. Two commercial metal complex acid dyes namely Bestalan Yellow SF and Bestalan Navy SF were adsorbed onto degummed silk fabric. The functional properties and surface morphology of silk fabric were investigated wi...
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| Published in: | The Journal of The Textile Institute Vol. 116; no. 8; pp. 1512 - 1520 |
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| Main Authors: | , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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Taylor & Francis
03.08.2025
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| ISSN: | 0040-5000, 1754-2340 |
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| Abstract | This study reports the adsorption phenomena of metal complex acid dyes onto silk fabric. Two commercial metal complex acid dyes namely Bestalan Yellow SF and Bestalan Navy SF were adsorbed onto degummed silk fabric. The functional properties and surface morphology of silk fabric were investigated with FT-IR spectroscopy and FE-SEM respectively. The typical absorption band of C = O stretching was found at 1620 cm
−1
indicating amide I structure and C-N stretching as well as N-H bending vibrations were observed at 1510 cm
−1
suggesting the β-sheet crystallites of amide I and amide II silk proteins. The effectiveness of degumming performance was confirmed by SEM images. The adsorption of dyes by silk fabric was investigated with respect to pH, initial dye bath concentration, and contact time. It was found that the adsorption of dye onto silk fabric was highly influenced by the dye bath pH, initial dye concentration, and contact time. The higher dye adsorption was observed at acidic dye bath condition (pH = 3.5). The adsorption of dye was also increased with the increase of the initial dye bath concentration. The dyes adsorption reached at equilibrium condition after 80 min. The adsorption isotherm and kinetics were also evaluated based on the experimental results. The adsorption pattern fitted well to the Langmuir adsorption isotherm with high correlation coefficient (R
2
>0.97) for both dyes. The kinetic parameters suggested that the pseudo-second-order model is more suitable compare to the pseudo-first-order model considering the higher regression coefficients (
R
2
=
∼
0.99
)
.
The maximum adsorption of Bestalan Yellow SF and Bestalan Navy SF was found to be 232.5 and 222.2 mg/g respectively. The thermodynamic data were studied at 25, 40 and 60 °C. The change of Gibbs free energy of the system was positive indicating the spontaneous nature of the adsorption. The values of ΔH (-4.68 kJ/mole −3.65 kJ/mole) suggested the exothermic environment and the negative values of ΔS (-0.035 and −0.034 kJ/mole/k) advocated the good interaction between the metal complex acid dyes and silk fabric. The Langmuir adsorption model and pseudo-second-order kinetic suggested that the dyeing of metal complex acid dyes on silk fabric was controlled by ion-exchange chemical reaction. |
|---|---|
| AbstractList | This study reports the adsorption phenomena of metal complex acid dyes onto silk fabric. Two commercial metal complex acid dyes namely Bestalan Yellow SF and Bestalan Navy SF were adsorbed onto degummed silk fabric. The functional properties and surface morphology of silk fabric were investigated with FT-IR spectroscopy and FE-SEM respectively. The typical absorption band of C = O stretching was found at 1620 cm
−1
indicating amide I structure and C-N stretching as well as N-H bending vibrations were observed at 1510 cm
−1
suggesting the β-sheet crystallites of amide I and amide II silk proteins. The effectiveness of degumming performance was confirmed by SEM images. The adsorption of dyes by silk fabric was investigated with respect to pH, initial dye bath concentration, and contact time. It was found that the adsorption of dye onto silk fabric was highly influenced by the dye bath pH, initial dye concentration, and contact time. The higher dye adsorption was observed at acidic dye bath condition (pH = 3.5). The adsorption of dye was also increased with the increase of the initial dye bath concentration. The dyes adsorption reached at equilibrium condition after 80 min. The adsorption isotherm and kinetics were also evaluated based on the experimental results. The adsorption pattern fitted well to the Langmuir adsorption isotherm with high correlation coefficient (R
2
>0.97) for both dyes. The kinetic parameters suggested that the pseudo-second-order model is more suitable compare to the pseudo-first-order model considering the higher regression coefficients (
R
2
=
∼
0.99
)
.
The maximum adsorption of Bestalan Yellow SF and Bestalan Navy SF was found to be 232.5 and 222.2 mg/g respectively. The thermodynamic data were studied at 25, 40 and 60 °C. The change of Gibbs free energy of the system was positive indicating the spontaneous nature of the adsorption. The values of ΔH (-4.68 kJ/mole −3.65 kJ/mole) suggested the exothermic environment and the negative values of ΔS (-0.035 and −0.034 kJ/mole/k) advocated the good interaction between the metal complex acid dyes and silk fabric. The Langmuir adsorption model and pseudo-second-order kinetic suggested that the dyeing of metal complex acid dyes on silk fabric was controlled by ion-exchange chemical reaction. |
| Author | Hasan, Md. Zahid Roy, Manindra Nath Bashar, M. Mahbubul Rokonuzzaman, Md Khan, Rashedul Hasan Islam, Khairul Hossain, Md. Tofazzal Islam, Md. Azharul Khandaker, Shahjalal |
| Author_xml | – sequence: 1 givenname: Rashedul Hasan surname: Khan fullname: Khan, Rashedul Hasan organization: Department of Textile Engineering, Mawlana Bhashani Science and Technology University – sequence: 2 givenname: Manindra Nath surname: Roy fullname: Roy, Manindra Nath organization: Department of Textile Engineering, Northern University Bangladesh – sequence: 3 givenname: Md. Tofazzal surname: Hossain fullname: Hossain, Md. Tofazzal organization: Department of Textile Engineering, BGMEA University of Fashion Technology – sequence: 4 givenname: Khairul surname: Islam fullname: Islam, Khairul organization: Department of Textile Engineering, Mawlana Bhashani Science and Technology University – sequence: 5 givenname: Md surname: Rokonuzzaman fullname: Rokonuzzaman, Md organization: Department of Textile Engineering, Mawlana Bhashani Science and Technology University – sequence: 6 givenname: Md. Azharul orcidid: 0000-0002-8521-0765 surname: Islam fullname: Islam, Md. Azharul organization: Department of Textile Engineering, Mawlana Bhashani Science and Technology University – sequence: 7 givenname: Md. Zahid surname: Hasan fullname: Hasan, Md. Zahid organization: Department of Textile Engineering, Mawlana Bhashani Science and Technology University – sequence: 8 givenname: Shahjalal surname: Khandaker fullname: Khandaker, Shahjalal organization: Department of Textile Engineering, Dhaka University of Engineering & Technology – sequence: 9 givenname: M. Mahbubul orcidid: 0000-0001-8054-809X surname: Bashar fullname: Bashar, M. Mahbubul organization: Department of Textile Engineering, Mawlana Bhashani Science and Technology University |
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| Cites_doi | 10.3390/ma14226919 10.1016/j.jclepro.2022.132705 10.1016/j.ijbiomac.2007.12.001 10.1533/9781782421580.1 10.1016/S0143-7208(01)00056-0 10.1016/0143-7208(91)87006-9 10.1155/2013/546839 10.3390/polym11060970 10.1016/j.dyepig.2004.06.009 10.1063/1.5091442 10.1016/j.dyepig.2017.09.015 10.1080/15440478.2019.1616650 10.1533/9780857093974.2.446 10.1021/acsbiomaterials.5b00461 10.1016/j.jece.2019.102958 10.1002/9781118725658 10.1021/acs.iecr.7b04915 10.1080/15440478.2018.1546638 10.1021/ie300201j 10.1021/acsomega.1c04111 10.1021/acs.biomac.6b00887 10.1111/j.1478-4408.1995.tb01681.x 10.1201/b18243 10.35812/CelluloseChemTechnol.2020.54.79 10.1007/s12221-015-5302-1 10.1016/j.jwpe.2019.101055 10.1080/00032719.2012.673098 10.1021/ja02242a004 10.1016/j.jmgm.2021.107934 10.1016/j.jhazmat.2010.07.015 10.1080/15440478.2024.2324302 10.1242/jeb.128306 10.1016/j.jenvman.2018.05.059 10.1080/00405000.2021.1992912 10.14504/ajr.5.3.2 10.1002/marc.201800390 10.1021/acs.langmuir.2c00314 10.14504/ajr.8.5.3 10.1016/S0032-9592(98)00112-5 10.1021/acs.macromol.9b02630 10.1002/app.13714 |
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| References | e_1_3_2_27_1 e_1_3_2_28_1 e_1_3_2_29_1 e_1_3_2_42_1 e_1_3_2_20_1 e_1_3_2_41_1 e_1_3_2_21_1 e_1_3_2_44_1 e_1_3_2_22_1 e_1_3_2_43_1 e_1_3_2_23_1 e_1_3_2_46_1 e_1_3_2_24_1 e_1_3_2_45_1 e_1_3_2_25_1 e_1_3_2_26_1 e_1_3_2_40_1 Broadbent A. D. (e_1_3_2_7_1) 2001 Muntean S. G. (e_1_3_2_33_1) 2015; 60 e_1_3_2_16_1 e_1_3_2_39_1 e_1_3_2_9_1 Freundlich H. M. F. (e_1_3_2_17_1) 1906; 57 e_1_3_2_38_1 e_1_3_2_8_1 e_1_3_2_18_1 e_1_3_2_19_1 e_1_3_2_2_1 e_1_3_2_31_1 Arildii D. (e_1_3_2_3_1) 2019; 44 e_1_3_2_30_1 e_1_3_2_10_1 e_1_3_2_11_1 e_1_3_2_32_1 e_1_3_2_6_1 e_1_3_2_12_1 e_1_3_2_35_1 e_1_3_2_5_1 e_1_3_2_13_1 e_1_3_2_34_1 e_1_3_2_4_1 e_1_3_2_14_1 e_1_3_2_37_1 e_1_3_2_15_1 e_1_3_2_36_1 |
| References_xml | – ident: e_1_3_2_4_1 doi: 10.3390/ma14226919 – ident: e_1_3_2_46_1 doi: 10.1016/j.jclepro.2022.132705 – ident: e_1_3_2_25_1 doi: 10.1016/j.ijbiomac.2007.12.001 – ident: e_1_3_2_34_1 doi: 10.1533/9781782421580.1 – ident: e_1_3_2_23_1 doi: 10.1016/S0143-7208(01)00056-0 – ident: e_1_3_2_14_1 doi: 10.1016/0143-7208(91)87006-9 – ident: e_1_3_2_42_1 doi: 10.1155/2013/546839 – ident: e_1_3_2_45_1 doi: 10.3390/polym11060970 – ident: e_1_3_2_9_1 doi: 10.1016/j.dyepig.2004.06.009 – ident: e_1_3_2_18_1 doi: 10.1063/1.5091442 – ident: e_1_3_2_40_1 doi: 10.1016/j.dyepig.2017.09.015 – ident: e_1_3_2_15_1 doi: 10.1080/15440478.2019.1616650 – ident: e_1_3_2_10_1 doi: 10.1533/9780857093974.2.446 – ident: e_1_3_2_44_1 doi: 10.1021/acsbiomaterials.5b00461 – ident: e_1_3_2_35_1 doi: 10.1016/j.jece.2019.102958 – ident: e_1_3_2_8_1 doi: 10.1002/9781118725658 – ident: e_1_3_2_2_1 doi: 10.1021/acs.iecr.7b04915 – ident: e_1_3_2_16_1 doi: 10.1080/15440478.2018.1546638 – ident: e_1_3_2_22_1 doi: 10.1021/ie300201j – ident: e_1_3_2_39_1 doi: 10.1021/acsomega.1c04111 – ident: e_1_3_2_5_1 doi: 10.1021/acs.biomac.6b00887 – ident: e_1_3_2_37_1 doi: 10.1111/j.1478-4408.1995.tb01681.x – volume-title: Basic principles of textile coloration year: 2001 ident: e_1_3_2_7_1 – ident: e_1_3_2_11_1 doi: 10.1201/b18243 – ident: e_1_3_2_24_1 doi: 10.35812/CelluloseChemTechnol.2020.54.79 – ident: e_1_3_2_38_1 doi: 10.1007/s12221-015-5302-1 – ident: e_1_3_2_27_1 doi: 10.1016/j.jwpe.2019.101055 – ident: e_1_3_2_30_1 doi: 10.1080/00032719.2012.673098 – ident: e_1_3_2_28_1 doi: 10.1021/ja02242a004 – ident: e_1_3_2_13_1 doi: 10.1016/j.jmgm.2021.107934 – ident: e_1_3_2_41_1 doi: 10.1016/j.jhazmat.2010.07.015 – ident: e_1_3_2_19_1 doi: 10.1080/15440478.2024.2324302 – ident: e_1_3_2_6_1 doi: 10.1242/jeb.128306 – ident: e_1_3_2_26_1 doi: 10.1016/j.jenvman.2018.05.059 – ident: e_1_3_2_29_1 doi: 10.1080/00405000.2021.1992912 – ident: e_1_3_2_20_1 doi: 10.14504/ajr.5.3.2 – ident: e_1_3_2_31_1 doi: 10.1002/marc.201800390 – volume: 44 start-page: 230 issue: 2 year: 2019 ident: e_1_3_2_3_1 article-title: Thermodynamics and kinetics of cashmere dyeing with metal complex dye publication-title: Indian Journal of Fibre and Textile Research, – volume: 57 start-page: 385 year: 1906 ident: e_1_3_2_17_1 article-title: Over the adsorption in solution publication-title: The Journal of Physical Chemistry, – ident: e_1_3_2_32_1 doi: 10.1021/acs.langmuir.2c00314 – volume: 60 start-page: 37 issue: 74 year: 2015 ident: e_1_3_2_33_1 article-title: Synthesis and characterization of new metal complex dye publication-title: Chemical Bulletin of Politehnica University of Timisoara – ident: e_1_3_2_12_1 doi: 10.14504/ajr.8.5.3 – ident: e_1_3_2_21_1 doi: 10.1016/S0032-9592(98)00112-5 – ident: e_1_3_2_36_1 doi: 10.1021/acs.macromol.9b02630 – ident: e_1_3_2_43_1 doi: 10.1002/app.13714 |
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| SubjectTerms | Adsorption dyeing kinetics Langmuir isotherm metal complex dyes silk fiber |
| Title | Adsorption kinetics and thermodynamics of metal complex acid dyes on silk fabric |
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