Luminescent Imidazo[1,5‐a]pyridine Scaffold: Synthetic Heterocyclization Strategies‐Overview and Promising Applications

In the last few years, imidazo[1,5‐a]pyridine derivatives have attracted growing attention due to their remarkable emissive behaviours, structural modification and biological properties. Previously published works emphasize the possible technological applications of this luminescent scaffold and dem...

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Published in:Asian journal of organic chemistry Vol. 11; no. 6
Main Author: Volpi, Giorgio
Format: Journal Article
Language:English
Published: 01.06.2022
Subjects:
emission
fluorescence
heterocyclization
imidazo[1,5-a]pyridine
ligand
ISSN:2193-5807, 2193-5815
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Abstract In the last few years, imidazo[1,5‐a]pyridine derivatives have attracted growing attention due to their remarkable emissive behaviours, structural modification and biological properties. Previously published works emphasize the possible technological applications of this luminescent scaffold and demonstrate the stringent relationship between chemical substituents and optical properties. The main goal of this work is to provide a complete list of the reported achievements concerning these promising heterocyclization reactions obtained starting from a huge variety of reagents, catalysts, oxidants, dehydrating agents involved in various reaction conditions. Particular attention is focused on the final possible substitutions, conjugations and structural modifications of the reported synthetic approaches, a powerful aspect to design innovative and employable new luminescent imidazo[1,5‐a]pyridine products. The main goal of this review is to provide a complete list of the reported achievements concerning the heterocyclization reactions to obtain imidazo[1,5‐a]pyridine derivatives starting from a huge variety of reagents, catalysts, oxidants, dehydrating agents involved in various reaction conditions. Particular attention is focused on the final possible substitutions and structural modifications of the reported synthetic approaches, a powerful aspect to design innovative emitters.
AbstractList In the last few years, imidazo[1,5‐ a ]pyridine derivatives have attracted growing attention due to their remarkable emissive behaviours, structural modification and biological properties. Previously published works emphasize the possible technological applications of this luminescent scaffold and demonstrate the stringent relationship between chemical substituents and optical properties. The main goal of this work is to provide a complete list of the reported achievements concerning these promising heterocyclization reactions obtained starting from a huge variety of reagents, catalysts, oxidants, dehydrating agents involved in various reaction conditions. Particular attention is focused on the final possible substitutions, conjugations and structural modifications of the reported synthetic approaches, a powerful aspect to design innovative and employable new luminescent imidazo[1,5‐ a ]pyridine products.
In the last few years, imidazo[1,5‐a]pyridine derivatives have attracted growing attention due to their remarkable emissive behaviours, structural modification and biological properties. Previously published works emphasize the possible technological applications of this luminescent scaffold and demonstrate the stringent relationship between chemical substituents and optical properties. The main goal of this work is to provide a complete list of the reported achievements concerning these promising heterocyclization reactions obtained starting from a huge variety of reagents, catalysts, oxidants, dehydrating agents involved in various reaction conditions. Particular attention is focused on the final possible substitutions, conjugations and structural modifications of the reported synthetic approaches, a powerful aspect to design innovative and employable new luminescent imidazo[1,5‐a]pyridine products. The main goal of this review is to provide a complete list of the reported achievements concerning the heterocyclization reactions to obtain imidazo[1,5‐a]pyridine derivatives starting from a huge variety of reagents, catalysts, oxidants, dehydrating agents involved in various reaction conditions. Particular attention is focused on the final possible substitutions and structural modifications of the reported synthetic approaches, a powerful aspect to design innovative emitters.
Author Volpi, Giorgio
Author_xml – sequence: 1
  givenname: Giorgio
  orcidid: 0000-0002-9695-9202
  surname: Volpi
  fullname: Volpi, Giorgio
  email: giorgio.volpi@unito.it
  organization: University of Turin
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Snippet In the last few years, imidazo[1,5‐a]pyridine derivatives have attracted growing attention due to their remarkable emissive behaviours, structural modification...
In the last few years, imidazo[1,5‐ a ]pyridine derivatives have attracted growing attention due to their remarkable emissive behaviours, structural...
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Publisher
SubjectTerms emission
fluorescence
heterocyclization
imidazo[1,5-a]pyridine
ligand
Title Luminescent Imidazo[1,5‐a]pyridine Scaffold: Synthetic Heterocyclization Strategies‐Overview and Promising Applications
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fajoc.202200171
Volume 11
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