A2B′B″O6 perovskites: A review

The B-site substituted perovskite oxides A2B′B″O6 have in the recent decades gained an increasing amount of interest due to their various interesting properties and possible applications. Here we survey the literature for ca. one thousand A2B′B″O6 perovskite compounds. Crystal structures and the var...

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Published in:	Progress in solid state chemistry Vol. 43; no. 1-2; pp. 1 - 36
Main Authors:	Vasala, Sami, Karppinen, Maarit
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 01.05.2015
Subjects:	Cation ordering Crystal structure Double perovskite oxides Electronic properties Magnetic properties Valence mixing Cation ordering Electronic properties Double perovskite oxides Valence mixing Crystal structure Magnetic properties
ISSN:	0079-6786, 1873-1643
Online Access:	Get full text
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Abstract	The B-site substituted perovskite oxides A2B′B″O6 have in the recent decades gained an increasing amount of interest due to their various interesting properties and possible applications. Here we survey the literature for ca. one thousand A2B′B″O6 perovskite compounds. Crystal structures and the various crystal chemistry features such as ordering and valence mixing of the B cations characteristic to these compounds are reviewed, together with their electronic and magnetic properties. Most importantly, the thorough examination of the research so far carried out allows us to make predictions for a number of new A2B′B″O6 compounds yet to be synthesized and reveal exciting but not yet fully explored puzzles related to this family of functional oxide materials.
AbstractList	The B-site substituted perovskite oxides A2B′B″O6 have in the recent decades gained an increasing amount of interest due to their various interesting properties and possible applications. Here we survey the literature for ca. one thousand A2B′B″O6 perovskite compounds. Crystal structures and the various crystal chemistry features such as ordering and valence mixing of the B cations characteristic to these compounds are reviewed, together with their electronic and magnetic properties. Most importantly, the thorough examination of the research so far carried out allows us to make predictions for a number of new A2B′B″O6 compounds yet to be synthesized and reveal exciting but not yet fully explored puzzles related to this family of functional oxide materials.
Author	Vasala, Sami Karppinen, Maarit
Author_xml	– sequence: 1 givenname: Sami surname: Vasala fullname: Vasala, Sami – sequence: 2 givenname: Maarit surname: Karppinen fullname: Karppinen, Maarit email: maarit.karppinen@aalto.fi
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Snippet	The B-site substituted perovskite oxides A2B′B″O6 have in the recent decades gained an increasing amount of interest due to their various interesting...
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SubjectTerms	Cation ordering Crystal structure Double perovskite oxides Electronic properties Magnetic properties Valence mixing
Title	A2B′B″O6 perovskites: A review
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