Multinuclear PFGSTE NMR description of 39K, 23Na, 7Li, and 1H specific activation energies governing diffusion in alkali nitrite solutions
[Display omitted] •Established feasibility of 39K PFGSTE NMR in concentrated potassium nitrite solutions despite unfavorable NMR properties•Identified viable spin-lattice and spin-spin relaxation coefficients permissive for 39K NMR diffusometry•Found links between alkali cation self-diffusion, water...
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| Vydané v: | Journal of magnetic resonance (1997) Ročník 364; s. 107707 |
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| Hlavní autori: | , , , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
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United States
Elsevier Inc
01.07.2024
Elsevier |
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| ISSN: | 1090-7807, 1096-0856, 1096-0856 |
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| Abstract | [Display omitted]
•Established feasibility of 39K PFGSTE NMR in concentrated potassium nitrite solutions despite unfavorable NMR properties•Identified viable spin-lattice and spin-spin relaxation coefficients permissive for 39K NMR diffusometry•Found links between alkali cation self-diffusion, water activation energy, and hydration enthalpy in concentrated alkali nitrite solutions
While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of self-diffusivity for many NMR-active nuclei, extending this technique to uncommon nuclei with unfavorable NMR properties remains an active area of research. Potassium-39 (39K) is an archetypical NMR nucleus exhibiting an unfavorable gyromagnetic ratio combined with a very low Larmor frequency. Despite these unfavorable properties, this work demonstrates that 39K PFGSTE NMR experiments are possible in aqueous solutions of concentrated potassium nitrite. Analysis of the results indicates that 39K NMR diffusometry is feasible when the nuclei exhibit spin–lattice and spin–spin relaxation coefficients on the order of 60–100 ms and 50–100 ms, respectively. The diffusivity of 39K followed Arrhenius behavior, and comparative 23Na, 7Li, and 1H PFGSTE NMR studies of equimolal sodium nitrite and lithium nitrite solutions led to correlations between the enthalpy of hydration with the activation energy governing self-diffusion of the cations and also of water. Realizing the feasibility of 39K PFGSTE NMR spectroscopy has a widespread impact across energy sciences because potassium is a common alkali element in energy storage materials and other applications. |
|---|---|
| AbstractList | While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of self-diffusivity for many NMR-active nuclei, extending this technique to uncommon nuclei with unfavorable NMR properties remains an active area of research. Potassium-39 (39K) is an archetypical NMR nucleus exhibiting an unfavorable gyromagnetic ratio combined with a very low Larmor frequency. Despite these unfavorable properties, this work demonstrates that 39K PFGSTE NMR experiments are possible in aqueous solutions of concentrated potassium nitrite. Analysis of the results indicates that 39K NMR diffusometry is feasible when the nuclei exhibit spin-lattice and spin-spin relaxation coefficients on the order of 60-100 ms and 50-100 ms, respectively. The diffusivity of 39K followed Arrhenius behavior, and comparative 23Na, 7Li, and 1H PFGSTE NMR studies of equimolal sodium nitrite and lithium nitrite solutions led to correlations between the enthalpy of hydration with the activation energy governing self-diffusion of the cations and also of water. Realizing the feasibility of 39K PFGSTE NMR spectroscopy has a widespread impact across energy sciences because potassium is a common alkali element in energy storage materials and other applications.While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of self-diffusivity for many NMR-active nuclei, extending this technique to uncommon nuclei with unfavorable NMR properties remains an active area of research. Potassium-39 (39K) is an archetypical NMR nucleus exhibiting an unfavorable gyromagnetic ratio combined with a very low Larmor frequency. Despite these unfavorable properties, this work demonstrates that 39K PFGSTE NMR experiments are possible in aqueous solutions of concentrated potassium nitrite. Analysis of the results indicates that 39K NMR diffusometry is feasible when the nuclei exhibit spin-lattice and spin-spin relaxation coefficients on the order of 60-100 ms and 50-100 ms, respectively. The diffusivity of 39K followed Arrhenius behavior, and comparative 23Na, 7Li, and 1H PFGSTE NMR studies of equimolal sodium nitrite and lithium nitrite solutions led to correlations between the enthalpy of hydration with the activation energy governing self-diffusion of the cations and also of water. Realizing the feasibility of 39K PFGSTE NMR spectroscopy has a widespread impact across energy sciences because potassium is a common alkali element in energy storage materials and other applications. While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of self-diffusivity for many NMR-active nuclei, extending this technique to uncommon nuclei with unfavorable NMR properties remains an active area of research. Potassium-39 (39K) is an archetypical NMR nucleus exhibiting an unfavorable gyromagnetic ratio combined with a very low Larmor frequency. Despite these unfavorable properties, this work demonstrates that 39K PFGSTE NMR experiments are possible in aqueous solutions of concentrated potassium nitrite. Further, analysis of the results indicates that 39K NMR diffusometry is feasible when the nuclei exhibit spin–lattice and spin–spin relaxation coefficients on the order of 60–100 ms and 50–100 ms, respectively. The diffusivity of 39K followed Arrhenius behavior, and comparative 23Na, 7Li, and 1H PFGSTE NMR studies of equimolal sodium nitrite and lithium nitrite solutions led to correlations between the enthalpy of hydration with the activation energy governing self-diffusion of the cations and also of water. Realizing the feasibility of 39K PFGSTE NMR spectroscopy has a widespread impact across energy sciences because potassium is a common alkali element in energy storage materials and other applications. [Display omitted] •Established feasibility of 39K PFGSTE NMR in concentrated potassium nitrite solutions despite unfavorable NMR properties•Identified viable spin-lattice and spin-spin relaxation coefficients permissive for 39K NMR diffusometry•Found links between alkali cation self-diffusion, water activation energy, and hydration enthalpy in concentrated alkali nitrite solutions While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of self-diffusivity for many NMR-active nuclei, extending this technique to uncommon nuclei with unfavorable NMR properties remains an active area of research. Potassium-39 (39K) is an archetypical NMR nucleus exhibiting an unfavorable gyromagnetic ratio combined with a very low Larmor frequency. Despite these unfavorable properties, this work demonstrates that 39K PFGSTE NMR experiments are possible in aqueous solutions of concentrated potassium nitrite. Analysis of the results indicates that 39K NMR diffusometry is feasible when the nuclei exhibit spin–lattice and spin–spin relaxation coefficients on the order of 60–100 ms and 50–100 ms, respectively. The diffusivity of 39K followed Arrhenius behavior, and comparative 23Na, 7Li, and 1H PFGSTE NMR studies of equimolal sodium nitrite and lithium nitrite solutions led to correlations between the enthalpy of hydration with the activation energy governing self-diffusion of the cations and also of water. Realizing the feasibility of 39K PFGSTE NMR spectroscopy has a widespread impact across energy sciences because potassium is a common alkali element in energy storage materials and other applications. |
| ArticleNumber | 107707 |
| Author | Colina-Ruiz, Roberto A. Graham, Trent R. Reynolds, Jacob G. Kennedy, Ashley R. Pearce, Carolyn I. Felsted, Robert G. Nienhuis, Emily T. |
| Author_xml | – sequence: 1 givenname: Trent R. orcidid: 0000-0001-8907-8004 surname: Graham fullname: Graham, Trent R. email: trent.graham@pnnl.gov organization: Pacific Northwest National Laboratory, Richland, WA 99354, USA – sequence: 2 givenname: Ashley R. surname: Kennedy fullname: Kennedy, Ashley R. organization: Pacific Northwest National Laboratory, Richland, WA 99354, USA – sequence: 3 givenname: Robert G. surname: Felsted fullname: Felsted, Robert G. organization: Pacific Northwest National Laboratory, Richland, WA 99354, USA – sequence: 4 givenname: Roberto A. surname: Colina-Ruiz fullname: Colina-Ruiz, Roberto A. organization: Pacific Northwest National Laboratory, Richland, WA 99354, USA – sequence: 5 givenname: Emily T. surname: Nienhuis fullname: Nienhuis, Emily T. organization: Pacific Northwest National Laboratory, Richland, WA 99354, USA – sequence: 6 givenname: Jacob G. surname: Reynolds fullname: Reynolds, Jacob G. organization: Washington River Protection Solutions, LLC, Richland, WA 99354, USA – sequence: 7 givenname: Carolyn I. surname: Pearce fullname: Pearce, Carolyn I. organization: Pacific Northwest National Laboratory, Richland, WA 99354, USA |
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| Cites_doi | 10.1039/C9CP04714J 10.1021/acs.chemmater.8b03944 10.1063/1.1695690 10.1021/je3003089 10.1039/D3CC04168A 10.1021/ed054p540 10.1515/zna-1974-1208 10.1021/ac50048a040 10.1002/mrc.5218 10.1021/je00028a014 10.1002/mrc.1079 10.1021/acs.jpclett.9b01416 10.1161/01.RES.84.8.913 10.1002/(SICI)1099-0534(1998)10:4<197::AID-CMR1>3.0.CO;2-S 10.1002/eem2.12174 10.1039/D1RA02301B 10.1021/acs.chemmater.1c02891 10.1002/(SICI)1099-0534(1997)9:5<299::AID-CMR2>3.0.CO;2-U 10.1021/acs.analchem.1c04197 10.1021/acs.jpcb.8b10145 10.1039/D0EE02917C |
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B doi: 10.1021/acs.jpcb.8b10145 – start-page: 158 year: 2023 ident: 10.1016/j.jmr.2024.107707_b0100 publication-title: J. Chem. Phys. – volume: 14 start-page: 2186 year: 2021 ident: 10.1016/j.jmr.2024.107707_b0110 publication-title: Energ. Environ. Sci. doi: 10.1039/D0EE02917C |
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•Established feasibility of 39K PFGSTE NMR in concentrated potassium nitrite solutions despite unfavorable NMR properties•Identified viable... While pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has found widespread use in the quantification of... |
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| Title | Multinuclear PFGSTE NMR description of 39K, 23Na, 7Li, and 1H specific activation energies governing diffusion in alkali nitrite solutions |
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