Catalytic effect of Mn2+, Fe3+ and Mg2+ ions on desulfurization using phosphate rock slurry as absorbent
[Display omitted] •The promotion effect of Mn2+, Fe3+ and Mg2+ on SO2 removal is revealed.•Trace Mn2+ and Fe3+ ions can enhance about 19%–31.5% SO2 adsorption capacity.•74.1% of activation energy is reduced when Mn2+ and Fe3+ are used to catalyze S(IV).•A radical chain reaction mechanism of S(IV) ca...
Saved in:
| Published in: | Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 390; p. 124568 |
|---|---|
| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Elsevier B.V
15.06.2020
|
| Subjects: | |
| ISSN: | 1385-8947, 1873-3212 |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | [Display omitted]
•The promotion effect of Mn2+, Fe3+ and Mg2+ on SO2 removal is revealed.•Trace Mn2+ and Fe3+ ions can enhance about 19%–31.5% SO2 adsorption capacity.•74.1% of activation energy is reduced when Mn2+ and Fe3+ are used to catalyze S(IV).•A radical chain reaction mechanism of S(IV) catalyzed by Mn2+/Fe3+ is proposed.•The Mn2+/Fe3+ promote the formation of SO3− radicals in the chain-initiating step.
Wet phosphate rock flue gas desulfurization is a new and promising technology, which has drawn increasing attention in recent years. The effect of Mn2+, Fe3+ and Mg2+ dissolved from phosphate rock on removal efficiency of SO2 were systematically investigated in this paper. The XRD, FT-IR, SEM, XPS, IC and ICP were used to characterize the reacted products, demonstrating that these metal ions have promotive effect on the purification of SO2. Especially, trace Mn2+ and Fe3+ ions can rose up about 19%–31.5% SO2 absorption capacity compared to the system without metal ions. Furthermore, the catalytic effect of these metal ions on the oxidation of S(IV) were compared, by adding them to the sodium bisulfite aqueous solution system. The order of catalytic capability of metal ions to S(IV) is: Mn2+ > Fe3+ > Mg2+. Interestingly, in the simultaneous presence of Mn2+ and Fe3+, the catalytic synergism between them toward S(IV) oxidation is exhibited. And only 16.56 kJ/mol of activation energy is needed, which is reduced by 74.1% compared to systems without catalyst. Consequently, a satisfactory result for absorption of SO2 can be obtained although the concentrations of Mn2+ and Fe3+ in phosphate rock slurry is low. Additionally, the catalytic mechanism of Mn2+ and Fe3+ towards S(IV) was investigated by reaction barrier and free energy calculation. |
|---|---|
| AbstractList | [Display omitted]
•The promotion effect of Mn2+, Fe3+ and Mg2+ on SO2 removal is revealed.•Trace Mn2+ and Fe3+ ions can enhance about 19%–31.5% SO2 adsorption capacity.•74.1% of activation energy is reduced when Mn2+ and Fe3+ are used to catalyze S(IV).•A radical chain reaction mechanism of S(IV) catalyzed by Mn2+/Fe3+ is proposed.•The Mn2+/Fe3+ promote the formation of SO3− radicals in the chain-initiating step.
Wet phosphate rock flue gas desulfurization is a new and promising technology, which has drawn increasing attention in recent years. The effect of Mn2+, Fe3+ and Mg2+ dissolved from phosphate rock on removal efficiency of SO2 were systematically investigated in this paper. The XRD, FT-IR, SEM, XPS, IC and ICP were used to characterize the reacted products, demonstrating that these metal ions have promotive effect on the purification of SO2. Especially, trace Mn2+ and Fe3+ ions can rose up about 19%–31.5% SO2 absorption capacity compared to the system without metal ions. Furthermore, the catalytic effect of these metal ions on the oxidation of S(IV) were compared, by adding them to the sodium bisulfite aqueous solution system. The order of catalytic capability of metal ions to S(IV) is: Mn2+ > Fe3+ > Mg2+. Interestingly, in the simultaneous presence of Mn2+ and Fe3+, the catalytic synergism between them toward S(IV) oxidation is exhibited. And only 16.56 kJ/mol of activation energy is needed, which is reduced by 74.1% compared to systems without catalyst. Consequently, a satisfactory result for absorption of SO2 can be obtained although the concentrations of Mn2+ and Fe3+ in phosphate rock slurry is low. Additionally, the catalytic mechanism of Mn2+ and Fe3+ towards S(IV) was investigated by reaction barrier and free energy calculation. |
| ArticleNumber | 124568 |
| Author | Dai, Jinfeng Mei, Yi Li, Shuai He, Dedong Nie, Yunxiang |
| Author_xml | – sequence: 1 givenname: Yunxiang surname: Nie fullname: Nie, Yunxiang organization: Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, PR China – sequence: 2 givenname: Shuai surname: Li fullname: Li, Shuai organization: Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, PR China – sequence: 3 givenname: Jinfeng surname: Dai fullname: Dai, Jinfeng organization: Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, PR China – sequence: 4 givenname: Dedong surname: He fullname: He, Dedong email: dedong.he@qq.com organization: Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, PR China – sequence: 5 givenname: Yi orcidid: 0000-0001-7224-597X surname: Mei fullname: Mei, Yi email: meiyi412@126.com organization: Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, PR China |
| BookMark | eNp9kE1PGzEQhi0UJAjwA7j5nm5Yf6x3rZ6qqEClRFzK2fLHmDgsdmQ7ldJfz0J66oHTzLzSM9L7zNEspggI3ZJ2SVoi7nZLC7slbel0U96J4QxdkqFnDaOEzqadDV0zSN5foHkpu7ZthSTyEm1XuurxWIPF4D3YipPHm0gX3_A9sAXW0eHNC13gkGLBKWIH5TD6Qw5_dZ0yfCghvuD9NpX9VlfAOdlXXMZDzkesC9ampGwg1mt07vVY4ObfvELP9z9_rx6b9dPDr9WPdWMp7WtjpWHet5yTgTApjHAdSOcHLsD0whgCjnHZGam5FVYKIj2zPZeOdMCdMewKkdNfm1MpGbza5_Cm81GRVn2oUjs1qVIfqtRJ1cT0_zE21M96Neswfkl-P5EwVfoTIKtiA0QLLuRJpnIpfEG_A-aNhag |
| CitedBy_id | crossref_primary_10_1016_j_jhazmat_2021_127426 crossref_primary_10_1016_j_cjche_2023_09_001 crossref_primary_10_1016_j_jhazmat_2021_125386 crossref_primary_10_1016_j_cej_2023_144732 crossref_primary_10_1016_j_jhazmat_2021_126673 crossref_primary_10_1016_j_seppur_2022_122980 crossref_primary_10_3390_en13215750 crossref_primary_10_1016_j_petsci_2024_09_021 crossref_primary_10_3390_pr10030537 crossref_primary_10_1016_j_fuel_2021_120881 crossref_primary_10_1016_j_jhazmat_2023_133075 crossref_primary_10_1007_s11771_022_4938_4 crossref_primary_10_1016_j_jhazmat_2024_133431 crossref_primary_10_1080_09593330_2023_2174047 crossref_primary_10_1016_j_arabjc_2024_105728 crossref_primary_10_1080_00986445_2024_2361421 crossref_primary_10_1016_j_seppur_2023_123435 crossref_primary_10_1007_s11356_021_15731_3 crossref_primary_10_1007_s11356_021_16842_7 crossref_primary_10_1016_j_gee_2024_01_006 crossref_primary_10_1016_j_cej_2021_131646 crossref_primary_10_1016_j_jece_2025_118467 crossref_primary_10_1016_j_seppur_2021_119988 crossref_primary_10_1049_mna2_12149 crossref_primary_10_1007_s11356_021_13990_8 crossref_primary_10_1016_j_eti_2022_102931 crossref_primary_10_1016_j_fuel_2021_121562 crossref_primary_10_1016_j_jenvman_2025_124419 crossref_primary_10_1016_j_cej_2024_152053 crossref_primary_10_1016_j_apcatb_2020_119791 crossref_primary_10_1016_j_jes_2021_02_004 crossref_primary_10_1016_j_chemosphere_2022_137592 crossref_primary_10_1002_aic_17236 crossref_primary_10_1016_j_jhazmat_2020_124381 crossref_primary_10_1016_j_seppur_2022_120931 crossref_primary_10_1016_j_cej_2024_149276 |
| Cites_doi | 10.1016/0960-1686(92)90170-P 10.1039/C4GC02445A 10.1016/S0959-6526(98)00020-1 10.1002/aic.15503 10.1021/ic951141i 10.3155/1047-3289.60.6.675 10.1016/j.cej.2014.09.085 10.1016/j.resconrec.2015.10.004 10.1016/j.cej.2019.122601 10.1016/j.cej.2019.04.028 10.1007/BF00750803 10.1021/ie010887n 10.1016/S0009-2509(03)00231-8 10.1016/S1385-8947(96)03168-3 10.1016/j.apenergy.2014.05.006 10.1016/j.fuel.2008.05.025 10.1021/ef301806x 10.1007/s10874-008-9105-2 10.1080/009083190910280 10.1016/S0009-2509(05)80038-7 10.1016/S0016-2361(01)00124-7 10.1002/aic.10403 10.1016/S0304-386X(99)00082-1 10.1007/BF00704313 10.1016/j.cej.2007.04.004 10.1021/acs.iecr.8b03223 10.1016/0004-6981(87)90317-9 10.1016/j.resconrec.2016.08.011 10.1021/ie9602365 |
| ContentType | Journal Article |
| Copyright | 2020 Elsevier B.V. |
| Copyright_xml | – notice: 2020 Elsevier B.V. |
| DBID | AAYXX CITATION |
| DOI | 10.1016/j.cej.2020.124568 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1873-3212 |
| ExternalDocumentID | 10_1016_j_cej_2020_124568 S1385894720305593 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 29B 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAXUO ABFNM ABFYP ABLST ABMAC ABNUV ABUDA ABYKQ ACDAQ ACRLP ADBBV ADEWK ADEZE AEBSH AEKER AENEX AFKWA AFTJW AFXIZ AGHFR AGUBO AGYEJ AHEUO AHPOS AIEXJ AIKHN AITUG AJOXV AKIFW AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLECG BLXMC CS3 DU5 EBS EFJIC EFLBG ENUVR EO8 EO9 EP2 EP3 F5P FDB FIRID FNPLU FYGXN G-Q GBLVA IHE J1W KCYFY KOM M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 ROL RPZ SDF SDG SES SPC SPCBC SSG SSJ SSZ T5K ~G- 9DU AATTM AAXKI AAYWO AAYXX ABXDB ACLOT ACVFH ADCNI AEIPS AEUPX AFFNX AFJKZ AFPUW AIGII AIIUN AKBMS AKRWK AKYEP ANKPU APXCP ASPBG AVWKF AZFZN BKOMP CITATION EFKBS EJD FEDTE FGOYB HVGLF HZ~ R2- SEW ZY4 ~HD |
| ID | FETCH-LOGICAL-c227t-c9b3ff044181396b6d5e9df846eb76bb1ed3495b9a4c6c9619f3c749d15e4dbb3 |
| ISICitedReferencesCount | 37 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000522640100013&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 1385-8947 |
| IngestDate | Tue Nov 18 22:10:12 EST 2025 Sat Nov 29 07:06:09 EST 2025 Fri Feb 23 02:47:39 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Flue gas desulfurization Activation energy Phosphate rock Catalytic mechanism Metal ions |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c227t-c9b3ff044181396b6d5e9df846eb76bb1ed3495b9a4c6c9619f3c749d15e4dbb3 |
| ORCID | 0000-0001-7224-597X |
| ParticipantIDs | crossref_primary_10_1016_j_cej_2020_124568 crossref_citationtrail_10_1016_j_cej_2020_124568 elsevier_sciencedirect_doi_10_1016_j_cej_2020_124568 |
| PublicationCentury | 2000 |
| PublicationDate | 2020-06-15 |
| PublicationDateYYYYMMDD | 2020-06-15 |
| PublicationDate_xml | – month: 06 year: 2020 text: 2020-06-15 day: 15 |
| PublicationDecade | 2020 |
| PublicationTitle | Chemical engineering journal (Lausanne, Switzerland : 1996) |
| PublicationYear | 2020 |
| Publisher | Elsevier B.V |
| Publisher_xml | – name: Elsevier B.V |
| References | Kang, Shin, Yu, Hwang (b0005) 2020; 381 Sınırkaya, Bayrakçeken, Özer, Gülaboglu (b0060) 2008; 87 Zafar, Anwar, Pritchard (b0040) 1996; 46 Liu, Wang (b0105) 2016; 63 Yang, Teng (b0010) 2018; 129 Connick, Zhang (b0160) 1996; 35 Steiner, Geissler, Watson, Mew (b0035) 2015; 105 Lancia, Musmarra, Pepe (b0055) 1997; 36 Zafar, Anwar, Pritchard (b0025) 1996; 44 Nie, Li, Wu, Wang, He, Mei (b0020) 2018; 57 Sun, Ding, Zeng, Su, Jiang (b0110) 2011; 192 Withers, Elser, Hilton, Ohtake, Schippere, van Dijkf (b0030) 2015; 17 Liu, Wang, Zhu, Lv, Li, Che (b0015) 2019; 371 Karatza, Prisciandaro, Lancia, Musmarra (b0150) 2010; 60 Lancia, Musmarra, Pepe, Volpicelli (b0050) 1994; 49 Naktiyok, Bayrakçeken, Özer, Gülaboğlu (b0090) 2013; 27 Nie, Dai, Hou, Zhu, Wang, He, Mei (b0125) 2019 Ebrahimi, Picioreanu, Kleerebezem, Heijnen, Van Loosdrecht (b0080) 2003; 58 Wang, Zhao (b0130) 2008; 136 Ho, Shih, Liu, Chu, Lee (b0065) 2002; 41 Wilkosz, Mainka (b0120) 2008; 60 Valle-zermeño, Niubó, Formosa, Guembe, Aparicio, Chimenos (b0075) 2015; 262 Zhang, Singh, Muir (b0155) 2000; 55 Sun, Ning, Song (b0100) 1998; 6 Özer, Gülaboğlu, Bayrakceken, Weosweiler (b0085) 2002; 81 Zheng, Xu, Zhang, Zhang, Gao, Luo, Cen (b0045) 2014; 129 Kar, Kar (b0095) 2006; 28 Ibusuki, Takeuchi (b0140) 1987; 21 Karatza, Prisciandaro, Lancia, Musmarra (b0115) 2004; 43 Grgić, Hudnik, Bizjak, Levec (b0145) 1992; 26 Lancia, Musmarra, Pepe, Prisciandaro (b0135) 1997; 66 Bausach, Pera-Titus, Fité, Cunill, Izquierdo, Tejero, Iborra (b0070) 2005; 51 Kang (10.1016/j.cej.2020.124568_b0005) 2020; 381 Zafar (10.1016/j.cej.2020.124568_b0025) 1996; 44 Ho (10.1016/j.cej.2020.124568_b0065) 2002; 41 Steiner (10.1016/j.cej.2020.124568_b0035) 2015; 105 Karatza (10.1016/j.cej.2020.124568_b0115) 2004; 43 Liu (10.1016/j.cej.2020.124568_b0015) 2019; 371 Nie (10.1016/j.cej.2020.124568_b0020) 2018; 57 Karatza (10.1016/j.cej.2020.124568_b0150) 2010; 60 Wilkosz (10.1016/j.cej.2020.124568_b0120) 2008; 60 Zafar (10.1016/j.cej.2020.124568_b0040) 1996; 46 Valle-zermeño (10.1016/j.cej.2020.124568_b0075) 2015; 262 Yang (10.1016/j.cej.2020.124568_b0010) 2018; 129 Nie (10.1016/j.cej.2020.124568_b0125) 2019 Özer (10.1016/j.cej.2020.124568_b0085) 2002; 81 Grgić (10.1016/j.cej.2020.124568_b0145) 1992; 26 Sınırkaya (10.1016/j.cej.2020.124568_b0060) 2008; 87 Lancia (10.1016/j.cej.2020.124568_b0055) 1997; 36 Lancia (10.1016/j.cej.2020.124568_b0135) 1997; 66 Zhang (10.1016/j.cej.2020.124568_b0155) 2000; 55 Lancia (10.1016/j.cej.2020.124568_b0050) 1994; 49 Ibusuki (10.1016/j.cej.2020.124568_b0140) 1987; 21 Ebrahimi (10.1016/j.cej.2020.124568_b0080) 2003; 58 Sun (10.1016/j.cej.2020.124568_b0100) 1998; 6 Bausach (10.1016/j.cej.2020.124568_b0070) 2005; 51 Kar (10.1016/j.cej.2020.124568_b0095) 2006; 28 Liu (10.1016/j.cej.2020.124568_b0105) 2016; 63 Zheng (10.1016/j.cej.2020.124568_b0045) 2014; 129 Wang (10.1016/j.cej.2020.124568_b0130) 2008; 136 Sun (10.1016/j.cej.2020.124568_b0110) 2011; 192 Naktiyok (10.1016/j.cej.2020.124568_b0090) 2013; 27 Withers (10.1016/j.cej.2020.124568_b0030) 2015; 17 Connick (10.1016/j.cej.2020.124568_b0160) 1996; 35 |
| References_xml | – volume: 58 start-page: 3589 year: 2003 end-page: 3600 ident: b0080 article-title: Rate-based modelling of SO publication-title: Chem. Eng. Sci. – volume: 371 start-page: 486 year: 2019 end-page: 499 ident: b0015 article-title: Simultaneous removal of NOx and SO publication-title: Chem. Eng. J. – volume: 136 start-page: 221 year: 2008 end-page: 226 ident: b0130 article-title: Kinetics of sulfite oxidation in wet desulfurization with catalyst of organic acid publication-title: Chem. Eng. J. – volume: 105 start-page: 235 year: 2015 end-page: 245 ident: b0035 article-title: Efficiency developments in phosphate rock mining over the last three decades publication-title: Resour. Conserv. Recycl. – volume: 41 start-page: 3357 year: 2002 end-page: 3364 ident: b0065 article-title: Kinetics of the sulfation of Ca(OH) publication-title: Ind. Eng. Chem. Res. – volume: 66 start-page: 123 year: 1997 end-page: 129 ident: b0135 article-title: Model of oxygen absorption into calcium sulfite solutions publication-title: Chem. Eng. J. – volume: 129 start-page: 373 year: 2018 end-page: 382 ident: b0010 article-title: The air quality co-benefit of coal control strategy in China publication-title: Resour. Conserv. Recycl. – volume: 55 start-page: 229 year: 2000 end-page: 245 ident: b0155 article-title: Iron(II) oxidation by SO publication-title: Hydrometallurgy. – volume: 60 start-page: 1 year: 2008 end-page: 17 ident: b0120 article-title: Mn(II)-catalysed S(IV) oxidation and its inhibition by acetic acid in acidic aqueous solutions publication-title: J. Atmos. Chem. – volume: 17 start-page: 2087 year: 2015 end-page: 2099 ident: b0030 article-title: Greening the global phosphorus cycle: how green chemistry can help achieve planetary P sustainability publication-title: Green Chem. – volume: 129 start-page: 187 year: 2014 end-page: 194 ident: b0045 article-title: Nitrogen oxide absorption and nitrite/nitrate formation in limestone slurry for WFGD system publication-title: Appl. Energy. – volume: 81 start-page: 41 year: 2002 end-page: 49 ident: b0085 article-title: Flue gas desulfurization with phosphate rock in a fluidized bed publication-title: Fuel. – volume: 6 start-page: 323 year: 1998 end-page: 327 ident: b0100 article-title: Liquid-phase catalytic oxidation of smelting-gases containing SO2 in low concentration publication-title: J. Cleaner Prod. – volume: 192 start-page: 124 year: 2011 end-page: 130 ident: b0110 article-title: Simultaneous absorption of NOx and SO2 from flue gas with pyrolusite slurry combined with gas-phase oxidation of NO using ozone publication-title: J. Hazard. Mater. – volume: 60 start-page: 675 year: 2010 end-page: 680 ident: b0150 article-title: Sulfite oxidation catalyzed by cobalt ions in flue gas desulfurization processes publication-title: J. Air Waste Manage. Assoc. – volume: 44 start-page: 133 year: 1996 end-page: 142 ident: b0025 article-title: A new route for the beneficiation of low grade calcareous phosphate rocks publication-title: Fert. Res. – volume: 28 start-page: 587 year: 2006 end-page: 595 ident: b0095 article-title: Effect of modified phosphate rock saturated by various salts on stack gas desulfurization in a fluidized bed reactor publication-title: Energy Sources, Part A – volume: 46 start-page: 135 year: 1996 end-page: 151 ident: b0040 article-title: Innovations in beneficiation technology for low grade phosphate rocks publication-title: Nutr. Cycling Agroecosyst. – volume: 63 start-page: 1287 year: 2016 end-page: 1302 ident: b0105 article-title: Simultaneous removal of NO and SO2 using aqueous peroxymonosulfate with coactivation of Cu2+/Fe3+ and high temperature publication-title: AIChE J. – volume: 21 start-page: 1555 year: 1987 end-page: 1560 ident: b0140 article-title: Sulfur dioxide oxidation by oxygen catalyzed by mixtures of manganese (Ⅱ) and iron(III) in aqueous solutions at environmental reaction conditions publication-title: Atmos. Environ. – volume: 43 start-page: 4876 year: 2004 end-page: 4882 ident: b0115 article-title: Calcium bisulfite oxidation in the flue gas desulfurization process catalyzed by iron and manganese ions publication-title: J. Air Waste Manage. Assoc. – volume: 87 start-page: 3200 year: 2008 end-page: 3206 ident: b0060 article-title: The effect of carbon dioxide during the desulfurization of flue gas with Mardin-Mazıdagı phosphate rock publication-title: Fuel – volume: 27 start-page: 1466 year: 2013 end-page: 1472 ident: b0090 article-title: Flue gas desulfurization by calcined phosphate rock and reaction kinetics publication-title: Energy Fuels. – volume: 381 year: 2020 ident: b0005 article-title: Simultaneous removal of gaseous NOx and SO publication-title: Chem. Eng. J. – volume: 49 start-page: 4523 year: 1994 end-page: 4532 ident: b0050 article-title: SO publication-title: Chem. Eng. Sci. – volume: 262 start-page: 268 year: 2015 end-page: 277 ident: b0075 article-title: Synergistic effect of the parameters affecting wet flue gas desulfurization using magnesium oxides by-products publication-title: Chem. Eng. J. – year: 2019 ident: b0125 article-title: An efficient and environmentally friendly process for the reduction of SO2 by using waste phosphate mine tailings as adsorbent publication-title: J. Hazard. Mater. – volume: 36 start-page: 197 year: 1997 end-page: 203 ident: b0055 article-title: Modeling of SO publication-title: Ind. Eng. Chem. Res. – volume: 57 start-page: 15138 year: 2018 end-page: 15146 ident: b0020 article-title: Efficient removal of SO publication-title: Ind. Eng. Chem. Res. – volume: 51 start-page: 1455 year: 2005 end-page: 1466 ident: b0070 article-title: Kinetic modeling of the reaction between hydrated lime and SO publication-title: AIChE J. – volume: 26 start-page: 571 year: 1992 end-page: 577 ident: b0145 article-title: Aqueous S(IV) oxidation—II. Synergistic effects of some metal ions publication-title: Atmos. Environ., Part A. – volume: 35 start-page: 4613 year: 1996 end-page: 4621 ident: b0160 article-title: Kinetics and mechanism of the oxidation of HSO publication-title: Inorg. Chem. – volume: 26 start-page: 571 year: 1992 ident: 10.1016/j.cej.2020.124568_b0145 article-title: Aqueous S(IV) oxidation—II. Synergistic effects of some metal ions publication-title: Atmos. Environ., Part A. doi: 10.1016/0960-1686(92)90170-P – volume: 17 start-page: 2087 year: 2015 ident: 10.1016/j.cej.2020.124568_b0030 article-title: Greening the global phosphorus cycle: how green chemistry can help achieve planetary P sustainability publication-title: Green Chem. doi: 10.1039/C4GC02445A – volume: 6 start-page: 323 year: 1998 ident: 10.1016/j.cej.2020.124568_b0100 article-title: Liquid-phase catalytic oxidation of smelting-gases containing SO2 in low concentration publication-title: J. Cleaner Prod. doi: 10.1016/S0959-6526(98)00020-1 – volume: 63 start-page: 1287 year: 2016 ident: 10.1016/j.cej.2020.124568_b0105 article-title: Simultaneous removal of NO and SO2 using aqueous peroxymonosulfate with coactivation of Cu2+/Fe3+ and high temperature publication-title: AIChE J. doi: 10.1002/aic.15503 – volume: 35 start-page: 4613 year: 1996 ident: 10.1016/j.cej.2020.124568_b0160 article-title: Kinetics and mechanism of the oxidation of HSO3- by O2. 2. The manganese(II)-catalyzed reaction publication-title: Inorg. Chem. doi: 10.1021/ic951141i – volume: 60 start-page: 675 year: 2010 ident: 10.1016/j.cej.2020.124568_b0150 article-title: Sulfite oxidation catalyzed by cobalt ions in flue gas desulfurization processes publication-title: J. Air Waste Manage. Assoc. doi: 10.3155/1047-3289.60.6.675 – year: 2019 ident: 10.1016/j.cej.2020.124568_b0125 article-title: An efficient and environmentally friendly process for the reduction of SO2 by using waste phosphate mine tailings as adsorbent publication-title: J. Hazard. Mater. – volume: 262 start-page: 268 year: 2015 ident: 10.1016/j.cej.2020.124568_b0075 article-title: Synergistic effect of the parameters affecting wet flue gas desulfurization using magnesium oxides by-products publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2014.09.085 – volume: 105 start-page: 235 year: 2015 ident: 10.1016/j.cej.2020.124568_b0035 article-title: Efficiency developments in phosphate rock mining over the last three decades publication-title: Resour. Conserv. Recycl. doi: 10.1016/j.resconrec.2015.10.004 – volume: 381 year: 2020 ident: 10.1016/j.cej.2020.124568_b0005 article-title: Simultaneous removal of gaseous NOx and SO2 by gas-phase oxidation with ozone and wet scrubbing with sodium hydroxide publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2019.122601 – volume: 371 start-page: 486 year: 2019 ident: 10.1016/j.cej.2020.124568_b0015 article-title: Simultaneous removal of NOx and SO2 from coal- fired flue gas based on the catalytic decomposition of H2O2 over Fe2 (MoO4)3 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2019.04.028 – volume: 44 start-page: 133 year: 1996 ident: 10.1016/j.cej.2020.124568_b0025 article-title: A new route for the beneficiation of low grade calcareous phosphate rocks publication-title: Fert. Res. doi: 10.1007/BF00750803 – volume: 41 start-page: 3357 year: 2002 ident: 10.1016/j.cej.2020.124568_b0065 article-title: Kinetics of the sulfation of Ca(OH)2 at low temperatures publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie010887n – volume: 58 start-page: 3589 year: 2003 ident: 10.1016/j.cej.2020.124568_b0080 article-title: Rate-based modelling of SO2 absorption into aqueous NaHCO3/Na2CO3 solutions accompanied by the desorption of CO2 publication-title: Chem. Eng. Sci. doi: 10.1016/S0009-2509(03)00231-8 – volume: 66 start-page: 123 year: 1997 ident: 10.1016/j.cej.2020.124568_b0135 article-title: Model of oxygen absorption into calcium sulfite solutions publication-title: Chem. Eng. J. doi: 10.1016/S1385-8947(96)03168-3 – volume: 129 start-page: 187 year: 2014 ident: 10.1016/j.cej.2020.124568_b0045 article-title: Nitrogen oxide absorption and nitrite/nitrate formation in limestone slurry for WFGD system publication-title: Appl. Energy. doi: 10.1016/j.apenergy.2014.05.006 – volume: 87 start-page: 3200 year: 2008 ident: 10.1016/j.cej.2020.124568_b0060 article-title: The effect of carbon dioxide during the desulfurization of flue gas with Mardin-Mazıdagı phosphate rock publication-title: Fuel doi: 10.1016/j.fuel.2008.05.025 – volume: 43 start-page: 4876 year: 2004 ident: 10.1016/j.cej.2020.124568_b0115 article-title: Calcium bisulfite oxidation in the flue gas desulfurization process catalyzed by iron and manganese ions publication-title: J. Air Waste Manage. Assoc. – volume: 27 start-page: 1466 year: 2013 ident: 10.1016/j.cej.2020.124568_b0090 article-title: Flue gas desulfurization by calcined phosphate rock and reaction kinetics publication-title: Energy Fuels. doi: 10.1021/ef301806x – volume: 60 start-page: 1 year: 2008 ident: 10.1016/j.cej.2020.124568_b0120 article-title: Mn(II)-catalysed S(IV) oxidation and its inhibition by acetic acid in acidic aqueous solutions publication-title: J. Atmos. Chem. doi: 10.1007/s10874-008-9105-2 – volume: 28 start-page: 587 year: 2006 ident: 10.1016/j.cej.2020.124568_b0095 article-title: Effect of modified phosphate rock saturated by various salts on stack gas desulfurization in a fluidized bed reactor publication-title: Energy Sources, Part A doi: 10.1080/009083190910280 – volume: 49 start-page: 4523 year: 1994 ident: 10.1016/j.cej.2020.124568_b0050 article-title: SO2 absorption in a bubbling reactor using limestone suspensions publication-title: Chem. Eng. Sci. doi: 10.1016/S0009-2509(05)80038-7 – volume: 81 start-page: 41 year: 2002 ident: 10.1016/j.cej.2020.124568_b0085 article-title: Flue gas desulfurization with phosphate rock in a fluidized bed publication-title: Fuel. doi: 10.1016/S0016-2361(01)00124-7 – volume: 192 start-page: 124 year: 2011 ident: 10.1016/j.cej.2020.124568_b0110 article-title: Simultaneous absorption of NOx and SO2 from flue gas with pyrolusite slurry combined with gas-phase oxidation of NO using ozone publication-title: J. Hazard. Mater. – volume: 51 start-page: 1455 year: 2005 ident: 10.1016/j.cej.2020.124568_b0070 article-title: Kinetic modeling of the reaction between hydrated lime and SO2 at low temperature publication-title: AIChE J. doi: 10.1002/aic.10403 – volume: 55 start-page: 229 year: 2000 ident: 10.1016/j.cej.2020.124568_b0155 article-title: Iron(II) oxidation by SO2/O2 in acidic media: Part I. Kinetics and mechanism publication-title: Hydrometallurgy. doi: 10.1016/S0304-386X(99)00082-1 – volume: 46 start-page: 135 year: 1996 ident: 10.1016/j.cej.2020.124568_b0040 article-title: Innovations in beneficiation technology for low grade phosphate rocks publication-title: Nutr. Cycling Agroecosyst. doi: 10.1007/BF00704313 – volume: 136 start-page: 221 year: 2008 ident: 10.1016/j.cej.2020.124568_b0130 article-title: Kinetics of sulfite oxidation in wet desulfurization with catalyst of organic acid publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2007.04.004 – volume: 57 start-page: 15138 year: 2018 ident: 10.1016/j.cej.2020.124568_b0020 article-title: Efficient removal of SO2 from flue gas with phosphate rock slurry and investigation of reaction mechanism publication-title: Ind. Eng. Chem. Res. doi: 10.1021/acs.iecr.8b03223 – volume: 21 start-page: 1555 year: 1987 ident: 10.1016/j.cej.2020.124568_b0140 article-title: Sulfur dioxide oxidation by oxygen catalyzed by mixtures of manganese (Ⅱ) and iron(III) in aqueous solutions at environmental reaction conditions publication-title: Atmos. Environ. doi: 10.1016/0004-6981(87)90317-9 – volume: 129 start-page: 373 year: 2018 ident: 10.1016/j.cej.2020.124568_b0010 article-title: The air quality co-benefit of coal control strategy in China publication-title: Resour. Conserv. Recycl. doi: 10.1016/j.resconrec.2016.08.011 – volume: 36 start-page: 197 year: 1997 ident: 10.1016/j.cej.2020.124568_b0055 article-title: Modeling of SO2 absorption into limestone suspensions publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie9602365 |
| SSID | ssj0006919 |
| Score | 2.4800115 |
| Snippet | [Display omitted]
•The promotion effect of Mn2+, Fe3+ and Mg2+ on SO2 removal is revealed.•Trace Mn2+ and Fe3+ ions can enhance about 19%–31.5% SO2 adsorption... |
| SourceID | crossref elsevier |
| SourceType | Enrichment Source Index Database Publisher |
| StartPage | 124568 |
| SubjectTerms | Activation energy Catalytic mechanism Flue gas desulfurization Metal ions Phosphate rock |
| Title | Catalytic effect of Mn2+, Fe3+ and Mg2+ ions on desulfurization using phosphate rock slurry as absorbent |
| URI | https://dx.doi.org/10.1016/j.cej.2020.124568 |
| Volume | 390 |
| WOSCitedRecordID | wos000522640100013&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVESC databaseName: Elsevier SD Freedom Collection Journals 2021 customDbUrl: eissn: 1873-3212 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0006919 issn: 1385-8947 databaseCode: AIEXJ dateStart: 19970115 isFulltext: true titleUrlDefault: https://www.sciencedirect.com providerName: Elsevier |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3Pb9MwFLZKxwEOiJ9iDJAPcCGkSuMkjo9jGho7VEgbUjlFsWOvLVVSJc3W8T_xP_IcO0mpNsQOXKLIcpwo75Pf5-fP7yH0TvIAWL3ywAJUuYEcK5gHBXWp5ysSpEpGqWiKTdDJJJ5O2dfB4Fd7FuZySfM83mzY6r-aGtrA2Pro7B3M3Q0KDXAPRocrmB2u_2T4Ix2QudZ5WI1WoxG55P57_1NDVCWBOyOvuNCNjlHCaU1sVS9VXdqDmU7dRBFWs6JazYCQOuDpfjjVsi7La12cJuVVUfJWNtPmOmjTD8g-zWGXnEIXD0m1CMgEUc-u5uuf5qyxjUuwaCsuMTEbJ9_rfAMIvuiEQ4364GxWp_M-yN60nWpdWd_xRJrpNCtsmw1t-LoCjmsOd9rZmMShGzOTkrOdrokpL2on3LHeuI1v9AUmLLEYCbkY6dFHfd8_827v-MNOpdgK4BYJDJHoIRIzxD2059OQxUO0d_jleHrauf6INZVkuu9ut9EbQeHOd9xMhLbIzflj9MiuSvChQdMTNJD5U_RwK1flMzTrcIUNrnChMODK-YgBUw4GM2JAlIM1nnCR4x084QZPuMMT1njCBk84rXCHp-fo2-fj86MT15bpcIXv07UrGCdKecCrY1hORDzKQskyBcRWchpxPpYZgWU4Z2kgIsFgxa6IoAHLxqEMMs7JCzTMi1y-RFgyTgUBJ-zRLKAqBJ_ABXBy4NiRF5BsH3ntP0uEzWGvS6ksk1tttY8-dI-sTAKXv3UOWkMkloEaZpkAqG5_7NVd3nGAHvRYf42G67KWb9B9cbmeV-Vbi6jfeGWiUg |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Catalytic+effect+of+Mn2%2B%2C+Fe3%2B+and+Mg2%2B+ions+on+desulfurization+using+phosphate+rock+slurry+as+absorbent&rft.jtitle=Chemical+engineering+journal+%28Lausanne%2C+Switzerland+%3A+1996%29&rft.au=Nie%2C+Yunxiang&rft.au=Li%2C+Shuai&rft.au=Dai%2C+Jinfeng&rft.au=He%2C+Dedong&rft.date=2020-06-15&rft.issn=1385-8947&rft.volume=390&rft.spage=124568&rft_id=info:doi/10.1016%2Fj.cej.2020.124568&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_j_cej_2020_124568 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1385-8947&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1385-8947&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1385-8947&client=summon |