Tuning Pt II ‐Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis

Asymmetric platinum donor–acceptor complexes [(pimp)Pt(Q 2− )] are presented in this work, in which pimp=[(2,4,6‐trimethylphenylimino)methyl]pyridine and Q 2− =catecholate‐type donor ligands. The properties of the complexes are evaluated as a function of the donor ligands, and correlations are drawn...

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Bibliographic Details

Published in:	Chemistry : a European journal Vol. 26; no. 6; pp. 1314 - 1327
Main Authors:	Sobottka, Sebastian, Nößler, Maite, Ostericher, Andrew L., Hermann, Gunter, Subat, Noah Z., Beerhues, Julia, Behr‐van der Meer, Margarethe, Suntrup, Lisa, Albold, Uta, Hohloch, Stephan, Tremblay, Jean Christophe, Sarkar, Biprajit
Format:	Journal Article
Language:	English
Published:	Germany Wiley-VCH Verlag 27.01.2020
Subjects:	Chemical Sciences or physical chemistry Physics Quantum Physics Theoretical and redox-active ligands spectroelectrochemistry donor-acceptor systems platinum electrochemistry
ISSN:	0947-6539, 1521-3765
Online Access:	Get full text
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