Tuning Pt II ‐Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis

Asymmetric platinum donor–acceptor complexes [(pimp)Pt(Q 2− )] are presented in this work, in which pimp=[(2,4,6‐trimethylphenylimino)methyl]pyridine and Q 2− =catecholate‐type donor ligands. The properties of the complexes are evaluated as a function of the donor ligands, and correlations are drawn...

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Vydané v:	Chemistry : a European journal Ročník 26; číslo 6; s. 1314 - 1327
Hlavní autori:	Sobottka, Sebastian, Nößler, Maite, Ostericher, Andrew L., Hermann, Gunter, Subat, Noah Z., Beerhues, Julia, Behr‐van der Meer, Margarethe, Suntrup, Lisa, Albold, Uta, Hohloch, Stephan, Tremblay, Jean Christophe, Sarkar, Biprajit
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Germany Wiley-VCH Verlag 27.01.2020
Predmet:	Chemical Sciences or physical chemistry Physics Quantum Physics Theoretical and redox-active ligands spectroelectrochemistry donor-acceptor systems platinum electrochemistry
ISSN:	0947-6539, 1521-3765
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