Hierarchically three-dimensional ZrO2/Fe3O4/C nanocomposites with Janus structure for high-efficiency electromagnetic wave absorption
Hierarchically three-dimensional (3D) materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects. In this work, α-Fe2O3@ZrO2 with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method. Following calc...
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| Veröffentlicht in: | Journal of materials science & technology Jg. 195; S. 126 - 135 |
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| Format: | Journal Article |
| Sprache: | Englisch |
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Elsevier Ltd
01.10.2024
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| ISSN: | 1005-0302, 1941-1162 |
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| Abstract | Hierarchically three-dimensional (3D) materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects. In this work, α-Fe2O3@ZrO2 with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method. Following calcination, 3D ZrO2/Fe3O4/C nanocomposites with Janus structure have been successfully synthesized. By controlling the lattice match and mismatch in both processes, a core-shell structure of α-Fe2O3@ZrO2 and Janus structure of ZrO2/Fe3O4 have been well-define performed. The composite material ZrO2/Fe3O4/C-700 has a minimum reflection loss (RLmin) of −67.4 dB at a thickness of 2.0 mm. The effective absorption bandwidth (EAB) at a thickness of 2.4 mm is 6.0 GHz (11.0–17.0 GHz). This study provides a novel strategy for fabricating high-efficiency electromagnetic wave absorption materials with dual synergistic effects in nanosized scale. |
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| AbstractList | Hierarchically three-dimensional (3D) materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects. In this work, α-Fe2O3@ZrO2 with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method. Following calcination, 3D ZrO2/Fe3O4/C nanocomposites with Janus structure have been successfully synthesized. By controlling the lattice match and mismatch in both processes, a core-shell structure of α-Fe2O3@ZrO2 and Janus structure of ZrO2/Fe3O4 have been well-define performed. The composite material ZrO2/Fe3O4/C-700 has a minimum reflection loss (RLmin) of −67.4 dB at a thickness of 2.0 mm. The effective absorption bandwidth (EAB) at a thickness of 2.4 mm is 6.0 GHz (11.0–17.0 GHz). This study provides a novel strategy for fabricating high-efficiency electromagnetic wave absorption materials with dual synergistic effects in nanosized scale. |
| Author | Lu, Xianyong Xue, Ying Liu, Xianyuan |
| Author_xml | – sequence: 1 givenname: Ying surname: Xue fullname: Xue, Ying – sequence: 2 givenname: Xianyuan surname: Liu fullname: Liu, Xianyuan – sequence: 3 givenname: Xianyong surname: Lu fullname: Lu, Xianyong email: xylu@buaa.edu.cn |
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| Keywords | Core-shell structure Electromagnetic wave absorption Janus structure Dual synergistic effects Lattice mismatch |
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