Boron-incorporated IrO2-Ta2O5 coating as an efficient electrocatalyst for acidic oxygen evolution reaction

[Display omitted] •The incorporation of boron species dramatically boosts the intrinsic activity of high-stabilized IrO2-Ta2O5.•The incorporation of boron species modulates the energy barrier of Ir sites for acidic OER.•A nearly complete rutile-type crystal structure ensures ultrahigh durability of...

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Vydáno v:Chemical engineering journal (Lausanne, Switzerland : 1996) Ročník 491; s. 152040
Hlavní autoři: Huang, Quanbo, Zhuang, Shaojie, Zheng, Yuexi, Peng, Xinyuan, Ye, Zhiguo, Li, Duosheng
Médium: Journal Article
Jazyk:angličtina
Vydáno: Elsevier B.V 01.07.2024
Témata:
Durability
Electrocatalytic activity
IrO2
Oxygen evolution reaction
Ta2O5
Durability
Electrocatalytic activity
Oxygen evolution reaction
IrO2
Ta2O5
ISSN:1385-8947, 1873-3212
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Shrnutí:[Display omitted] •The incorporation of boron species dramatically boosts the intrinsic activity of high-stabilized IrO2-Ta2O5.•The incorporation of boron species modulates the energy barrier of Ir sites for acidic OER.•A nearly complete rutile-type crystal structure ensures ultrahigh durability of the electrocatalysts. The Ir-based electrocatalysts for the acidic oxygen evolution reaction (OER) have demonstrated remarkable durability. Enhancing the Ir-based electrocatalytic activity still remains crucial owing to the scarcity of iridium. Here, a high-temperature sintering technique is employed to fabricate a boron (B)-incorporated IrO2-Ta2O5 coating with an almost perfect rutile-type crystal structure on a corrosion-resistant titanium substrate, ensuring exceptional stability for the acidic OER. The B-incorporated IrO2-Ta2O5 electrode fabricated in a mixed solution of 0.6 M H3BO3, exhibits an overpotential of 210 mV at a current density of 10 mA cm−2 and a lower Tafel slope of 34.2 mV dec−1 in a 0.5 M H2SO4 solution, which is far lower than the 272 mV overpotential and the 45.3 mV dec−1 of the IrO2-Ta2O5/Ti electrode. The electrode possesses a minimal potential increase even after undergoing continuous OER for 400 h at a high current density of 100 mA cm−2 in a 0.5 M H2SO4 solution. The incorporation of B species into IrO2-Ta2O5 effectively fine-tunes the electronic structure of Ir active sites, leading to a substantial enhancement of the intrinsic electrocatalytic activity. This study provides promising prospects for reducing the energy consumption of noble IrO2-based electrocatalysts in the practical application of electrochemical industry for the acidic OER.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2024.152040