N 2 Binding to the FeMo‐Cofactor of Nitrogenase
Nitrogenase converts gaseous dinitrogen into biologically accessible ammonia. The binding of N 2 to a reduced and protonated form of the FeMo‐cofactor of nitrogenase including its central carbon ligand was investigated by means of density functional calculations. It was found the central ligand to s...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) Jg. 641; H. 1; S. 118 - 122 |
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| Format: | Journal Article |
| Sprache: | Englisch |
| Veröffentlicht: |
01.01.2015
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| ISSN: | 0044-2313, 1521-3749 |
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| Abstract | Nitrogenase converts gaseous dinitrogen into biologically accessible ammonia. The binding of N
2
to a reduced and protonated form of the FeMo‐cofactor of nitrogenase including its central carbon ligand was investigated by means of density functional calculations. It was found the central ligand to stabilize the cluster. N
2
can associate to iron or molybdenum with iron being the preferred binding site. While
endo
and
exo
binding modes were investigated the
exo
modes are more stable. Implications on the mechanism of N
2
reduction are discussed. |
|---|---|
| AbstractList | Nitrogenase converts gaseous dinitrogen into biologically accessible ammonia. The binding of N
2
to a reduced and protonated form of the FeMo‐cofactor of nitrogenase including its central carbon ligand was investigated by means of density functional calculations. It was found the central ligand to stabilize the cluster. N
2
can associate to iron or molybdenum with iron being the preferred binding site. While
endo
and
exo
binding modes were investigated the
exo
modes are more stable. Implications on the mechanism of N
2
reduction are discussed. |
| Author | Hallmen, Philipp P. Kästner, Johannes |
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| CitedBy_id | crossref_primary_10_1002_jccs_202300062 crossref_primary_10_1016_j_jcat_2020_08_028 crossref_primary_10_1039_D2DT01920E crossref_primary_10_1021_jacs_6b00747 crossref_primary_10_1016_j_jallcom_2021_159907 crossref_primary_10_1007_s00775_020_01780_5 crossref_primary_10_1039_C9SC03610E crossref_primary_10_1002_chem_202103933 crossref_primary_10_1002_cbic_201900636 crossref_primary_10_1021_jacs_9b05353 crossref_primary_10_1039_C8CC01950A crossref_primary_10_1093_ce_zkac095 crossref_primary_10_1002_chem_202202502 crossref_primary_10_3390_inorganics7010008 crossref_primary_10_1088_2516_1075_ac1a63 |
| Cites_doi | 10.1039/c2dt00049k 10.1021/cr950055x 10.1016/S0010-8545(99)00240-4 10.1103/PhysRevLett.80.3622 10.1021/ic7022743 10.1039/c2dt30518f 10.1021/ja0367997 10.1021/ic0500311 10.1007/BF02712785 10.1021/ja0301572 10.1002/cphc.200400474 10.1126/science.1214025 10.1103/PhysRev.140.A1133 10.1103/PhysRev.136.B864 10.1021/ja068618h 10.1021/ic102446n 10.1007/s007750050094 10.1042/bj2240877 10.1021/ja029041g 10.1103/PhysRevLett.55.2471 10.1146/annurev.arplant.52.1.269 10.1063/1.2008227 10.1021/ja910613m 10.1021/cr00106a002 10.1103/PhysRevB.50.17953 10.1007/s11244-006-0002-0 10.1126/science.1529353 10.1021/bi00840a064 10.1002/jcc.20413 10.1016/S0010-8545(99)00108-3 10.1038/360553a0 10.1021/ic401818k 10.1103/PhysRevB.62.11556 10.1042/bj2240895 10.1103/PhysRevLett.77.3865 10.1039/c3cc46864j 10.1021/ja043596p 10.1063/1.470314 10.1126/science.1073877 10.1088/0305-4608/18/3/018 10.1021/ic0301371 10.1073/pnas.52.2.272 10.1021/bi025623z 10.1126/science.1085326 10.1038/nature12435 10.1021/cr400641x 10.1002/anie.200502667 10.1021/ja0644428 10.1039/b211036a 10.1126/science.1206445 10.1042/bj2240887 10.1021/cr950057h 10.1021/ja030541z 10.1021/ar300267m 10.1002/chem.200400709 10.1073/pnas.0610975104 10.1042/bj2240903 |
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| References | e_1_2_5_27_2 e_1_2_5_48_2 e_1_2_5_25_2 e_1_2_5_46_2 e_1_2_5_23_2 e_1_2_5_44_2 e_1_2_5_21_2 e_1_2_5_42_2 e_1_2_5_29_2 e_1_2_5_40_2 e_1_2_5_13_2 e_1_2_5_38_2 e_1_2_5_59_2 e_1_2_5_9_2 e_1_2_5_15_2 e_1_2_5_36_2 e_1_2_5_57_2 e_1_2_5_7_2 e_1_2_5_34_2 e_1_2_5_55_2 e_1_2_5_5_2 e_1_2_5_11_2 e_1_2_5_32_2 e_1_2_5_53_2 e_1_2_5_3_2 e_1_2_5_1_2 e_1_2_5_17_2 e_1_2_5_19_2 e_1_2_5_30_2 e_1_2_5_51_2 Kim J. (e_1_2_5_8_2) 1992; 257 e_1_2_5_26_2 e_1_2_5_49_2 e_1_2_5_24_2 e_1_2_5_47_2 e_1_2_5_22_2 e_1_2_5_45_2 e_1_2_5_20_2 e_1_2_5_43_2 e_1_2_5_28_2 e_1_2_5_41_2 e_1_2_5_14_2 e_1_2_5_37_2 e_1_2_5_16_2 e_1_2_5_35_2 e_1_2_5_58_2 e_1_2_5_10_2 e_1_2_5_33_2 e_1_2_5_6_2 e_1_2_5_12_2 e_1_2_5_31_2 e_1_2_5_54_2 Sandratskii L. (e_1_2_5_56_2) 1986 e_1_2_5_4_2 e_1_2_5_2_2 e_1_2_5_18_2 e_1_2_5_39_2 e_1_2_5_52_2 e_1_2_5_50_2 |
| References_xml | – ident: e_1_2_5_39_2 doi: 10.1039/c2dt00049k – ident: e_1_2_5_2_2 doi: 10.1021/cr950055x – ident: e_1_2_5_47_2 doi: 10.1016/S0010-8545(99)00240-4 – ident: e_1_2_5_58_2 doi: 10.1103/PhysRevLett.80.3622 – ident: e_1_2_5_37_2 doi: 10.1021/ic7022743 – ident: e_1_2_5_40_2 doi: 10.1039/c2dt30518f – ident: e_1_2_5_24_2 doi: 10.1021/ja0367997 – ident: e_1_2_5_29_2 doi: 10.1021/ic0500311 – ident: e_1_2_5_52_2 doi: 10.1007/BF02712785 – ident: e_1_2_5_25_2 doi: 10.1021/ja0301572 – ident: e_1_2_5_30_2 doi: 10.1002/cphc.200400474 – ident: e_1_2_5_12_2 doi: 10.1126/science.1214025 – ident: e_1_2_5_50_2 doi: 10.1103/PhysRev.140.A1133 – ident: e_1_2_5_49_2 doi: 10.1103/PhysRev.136.B864 – ident: e_1_2_5_36_2 doi: 10.1021/ja068618h – ident: e_1_2_5_38_2 doi: 10.1021/ic102446n – ident: e_1_2_5_45_2 doi: 10.1007/s007750050094 – ident: e_1_2_5_14_2 doi: 10.1042/bj2240877 – ident: e_1_2_5_23_2 doi: 10.1021/ja029041g – ident: e_1_2_5_55_2 doi: 10.1103/PhysRevLett.55.2471 – ident: e_1_2_5_4_2 doi: 10.1146/annurev.arplant.52.1.269 – volume: 257 start-page: 1667 year: 1992 ident: e_1_2_5_8_2 publication-title: Science – ident: e_1_2_5_31_2 doi: 10.1063/1.2008227 – ident: e_1_2_5_20_2 doi: 10.1021/ja910613m – ident: e_1_2_5_1_2 doi: 10.1021/cr00106a002 – ident: e_1_2_5_51_2 doi: 10.1103/PhysRevB.50.17953 – ident: e_1_2_5_32_2 doi: 10.1007/s11244-006-0002-0 – ident: e_1_2_5_9_2 doi: 10.1126/science.1529353 – ident: e_1_2_5_13_2 doi: 10.1021/bi00840a064 – ident: e_1_2_5_34_2 doi: 10.1002/jcc.20413 – ident: e_1_2_5_46_2 doi: 10.1016/S0010-8545(99)00108-3 – ident: e_1_2_5_7_2 doi: 10.1038/360553a0 – ident: e_1_2_5_41_2 doi: 10.1021/ic401818k – ident: e_1_2_5_59_2 doi: 10.1103/PhysRevB.62.11556 – ident: e_1_2_5_16_2 doi: 10.1042/bj2240895 – ident: e_1_2_5_53_2 doi: 10.1103/PhysRevLett.77.3865 – ident: e_1_2_5_42_2 doi: 10.1039/c3cc46864j – ident: e_1_2_5_18_2 doi: 10.1021/ja043596p – ident: e_1_2_5_54_2 doi: 10.1063/1.470314 – ident: e_1_2_5_10_2 doi: 10.1126/science.1073877 – ident: e_1_2_5_57_2 doi: 10.1088/0305-4608/18/3/018 – ident: e_1_2_5_28_2 doi: 10.1021/ic0301371 – ident: e_1_2_5_6_2 doi: 10.1073/pnas.52.2.272 – year: 1986 ident: e_1_2_5_56_2 publication-title: J. Phys. F – ident: e_1_2_5_22_2 doi: 10.1021/bi025623z – ident: e_1_2_5_43_2 doi: 10.1126/science.1085326 – ident: e_1_2_5_44_2 doi: 10.1038/nature12435 – ident: e_1_2_5_5_2 doi: 10.1021/cr400641x – ident: e_1_2_5_33_2 doi: 10.1002/anie.200502667 – ident: e_1_2_5_35_2 doi: 10.1021/ja0644428 – ident: e_1_2_5_27_2 doi: 10.1039/b211036a – ident: e_1_2_5_11_2 doi: 10.1126/science.1206445 – ident: e_1_2_5_15_2 doi: 10.1042/bj2240887 – ident: e_1_2_5_3_2 doi: 10.1021/cr950057h – ident: e_1_2_5_26_2 doi: 10.1021/ja030541z – ident: e_1_2_5_21_2 doi: 10.1021/ar300267m – ident: e_1_2_5_48_2 doi: 10.1002/chem.200400709 – ident: e_1_2_5_19_2 doi: 10.1073/pnas.0610975104 – ident: e_1_2_5_17_2 doi: 10.1042/bj2240903 |
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| Snippet | Nitrogenase converts gaseous dinitrogen into biologically accessible ammonia. The binding of N
2
to a reduced and protonated form of the FeMo‐cofactor of... |
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| Title | N 2 Binding to the FeMo‐Cofactor of Nitrogenase |
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