M 2 (H 2 O)[μ 10 ‐C 6 H 2 (COO) 4 ] ( M = Ba 2+ , Pb 2+ ) – Two Isotypic Three‐Dimensional Coordination Polymers with a Layer‐like Separation between Anions and Cations
Monoclinic single crystals of Ba 2 (H 2 O)[μ 10 ‐C 6 H 2 (COO) 4 ] ( 1 ) and Pb 2 (H 2 O)[μ 10 ‐C 6 H 2 (COO) 4 ] ( 2 ) were obtained using the silica gel method [space group C 2/ c (no. 15), Z = 4; 1 : a = 780.89(4), b = 1756.19(8), c = 914.80(5) pm, β = 114.512(5)°; 2 : a = 756.70(10), b = 1772.8(...
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| Published in: | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 641; no. 6; pp. 1150 - 1155 |
|---|---|
| Main Authors: | , |
| Format: | Journal Article |
| Language: | English |
| Published: |
01.05.2015
|
| ISSN: | 0044-2313, 1521-3749 |
| Online Access: | Get full text |
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| Summary: | Monoclinic single crystals of Ba
2
(H
2
O)[μ
10
‐C
6
H
2
(COO)
4
] (
1
) and Pb
2
(H
2
O)[μ
10
‐C
6
H
2
(COO)
4
] (
2
) were obtained using the silica gel method [space group
C
2/
c
(no. 15),
Z
= 4;
1
:
a
= 780.89(4),
b
= 1756.19(8),
c
= 914.80(5) pm,
β
= 114.512(5)°;
2
:
a
= 756.70(10),
b
= 1772.8(2),
c
= 890.2(2) pm,
β
= 113.590(10)°]. There are two crystallographically independent
M
2+
ions (
M
= Ba, Pb).
M
(1) is surrounded by eight carboxylate oxygen atoms and one water molecule forming a tricapped trigonal prism.
M
(2) is coordinated by ten carboxylate oxygen atoms in the shape of a tetracapped octahedron. The connection between the
M
(1) and
M
(2) polyhedra leads to infinite layers parallel to (010), which are linked by [C
6
H
2
(COO)
4
]
4–
anions to form a three‐dimensional framework. The [C
6
H
2
(COO)
4
]
4–
anion adopts a μ
10
coordination mode. Compound
1
reveals short Ba–Ba contacts of 426.46(2) pm, whereas the Pb–Pb distance of 411.01(6) pm in
2
is larger than twice the van der Waals radius. |
|---|---|
| ISSN: | 0044-2313 1521-3749 |
| DOI: | 10.1002/zaac.201500050 |