Cover Feature: Theoretical Insights into Bifurcated Intramolecular Dihydrogen Bonds (ChemPhysChem 4/2024)

The Cover Feature presents three conformers of (1Z,4Z)‐1,4‐dipentene‐3‐bora‐1,5‐diol corresponding to local energetic minima. The most energetically stable is the conformer with two intramolecular dihydrogen bonds, DHBs, that possess the same hydride Lewis base centre (bifurcated dihydrogen bond). T...

Full description

Saved in:
Bibliographic Details
Published in:Chemphyschem Vol. 25; no. 4
Main Authors: Gholami, Samira, Aarabi, Mohammad, Grabowski, Sławomir J.
Format: Journal Article
Language:English
Published: Weinheim Wiley Subscription Services, Inc 16.02.2024
Subjects:
Bifurcation theory
Lewis base
ISSN:1439-4235, 1439-7641
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The Cover Feature presents three conformers of (1Z,4Z)‐1,4‐dipentene‐3‐bora‐1,5‐diol corresponding to local energetic minima. The most energetically stable is the conformer with two intramolecular dihydrogen bonds, DHBs, that possess the same hydride Lewis base centre (bifurcated dihydrogen bond). The opening of one of the intramolecular dihydrogen bonded rings leads to the conformer of the higher energy with the single DHB. The conformer without DHBs is characterised by the highest energy. More information can be found in the Research Article by Samira Gholami, Mohammad Aarabi, and Sławomir J. Grabowski .
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.202400058