N‐Doped Graphene‐SnO 2 Sandwich Paper for High‐Performance Lithium‐Ion Batteries
A new facile route to fabricate N‐doped graphene‐SnO 2 sandwich papers is developed. The 7,7,8,8‐tetracyanoquinodimethane anion (TCNQ − ) plays a key role for the formation of such structures as it acts as both the nitrogen source and complexing agent. If used in lithium‐ion batteries (LIBs), the ma...
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| Vydáno v: | Advanced functional materials Ročník 22; číslo 13; s. 2682 - 2690 |
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| Hlavní autoři: | , , , , , , , , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
| Vydáno: |
10.07.2012
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| ISSN: | 1616-301X, 1616-3028 |
| On-line přístup: | Získat plný text |
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| Shrnutí: | A new facile route to fabricate N‐doped graphene‐SnO 2 sandwich papers is developed. The 7,7,8,8‐tetracyanoquinodimethane anion (TCNQ − ) plays a key role for the formation of such structures as it acts as both the nitrogen source and complexing agent. If used in lithium‐ion batteries (LIBs), the material exhibits a large capacity, high rate capability, and excellent cycling stability. The superior electrochemical performance of this novel material is the result from its unique features: excellent electronic conductivity related to the sandwich structure, short transportation length for both lithium ions and electrons, and elastomeric space to accommodate volume changes upon Li insertion/extraction. |
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| ISSN: | 1616-301X 1616-3028 |
| DOI: | 10.1002/adfm.201103110 |