Regulation of Surface Terminal Hydroxyl Coverage of FeOCl Catalyst via Crystal Facet Protection for Enhanced H 2 O 2 Activation

The unique Fe coordination environment in the FeOCl catalyst confers superior reducible electronic properties, rendering them attractive Fenton-like active sites. DFT calculations reveal that the U-shaped coordinated Fe sites formed with 50% terminal hydroxyl coverage exhibit the best H O activation...

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Veröffentlicht in:Environmental science & technology Jg. 59; H. 21; S. 10620
Hauptverfasser: Chen, Shuxun, Liang, Jianxing, Li, Jingdong, Bao, Chenyu, Chen, Yushan, Yue, Dongting, Fan, Maohong, Li, Kan, Jia, Jinping
Format: Journal Article
Sprache:Englisch
Veröffentlicht: United States 03.06.2025
Schlagworte:
Catalysis
Hydrogen Peroxide - chemistry
Iron - chemistry
FeOCl
H2O2 activation
DFT calculation
surface terminal hydroxyl coverage
crystal facet
ISSN:1520-5851
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Zusammenfassung:The unique Fe coordination environment in the FeOCl catalyst confers superior reducible electronic properties, rendering them attractive Fenton-like active sites. DFT calculations reveal that the U-shaped coordinated Fe sites formed with 50% terminal hydroxyl coverage exhibit the best H O activation performance, which allows the adsorbed H O to form a ·OH directly with much lower activation energy. Herein, a crystal facet protection strategy induced by rapid high-temperature annealing is developed to synthesize FeOCl with high exposure of Fe atoms while regulating the surface hydroxyl coverage. The dominant expression of the (021) facet resulted in an optimized surface terminal hydroxyl coverage of 58.3%, increasing the intrinsic activity of FeOCl by 4.3 times. The d-band center of FeOCl with optimized terminal hydroxyl coverage is closer to the Fermi level, thus exhibiting higher affinity for H O , and the increased amount of U-shaped coordinated Fe sites enables sufficient ·OH generation for enhanced decontamination performance. Since the terminal hydroxyl groups can be consumed by Ca and Mg through coprecipitation, preremoving the hardness of actual wastewater is indispensable in the application of the FeOCl/H O system. Our finding provides a new way to improve the intrinsic activity of FeOCl catalyst, which is helpful for its application in other environmental remediations.
ISSN:1520-5851
DOI:10.1021/acs.est.5c02303