Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the br...

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Vydáno v:Chemical reviews Ročník 122; číslo 2; s. 1485
Hlavní autoři: Chan, Amy Y, Perry, Ian B, Bissonnette, Noah B, Buksh, Benito F, Edwards, Grant A, Frye, Lucas I, Garry, Olivia L, Lavagnino, Marissa N, Li, Beryl X, Liang, Yufan, Mao, Edna, Millet, Agustin, Oakley, James V, Reed, Nicholas L, Sakai, Holt A, Seath, Ciaran P, MacMillan, David W C
Médium: Journal Article
Jazyk:angličtina
Vydáno: United States 26.01.2022
Témata:
Catalysis
Electrons
Nickel - chemistry
Oxidation-Reduction
Transition Elements
ISSN:1520-6890, 1520-6890
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Shrnutí:The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. This Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.
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ISSN:1520-6890
1520-6890
DOI:10.1021/acs.chemrev.1c00383