Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework

The manganese-nitronyl-nitroxide two-dimensional coordination polymer {[Mn (NITIm) ]ClO } (1) (NITImH = 2-(2-imidazolyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-3-oxide-1-oxyl) undergoes an unusual hysteretic thermo-induced valence tautomeric transition near room temperature, during which the manganese(I...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 138; no. 50; p. 16493
Main Authors:	Lannes, Anthony, Suffren, Yan, Tommasino, Jean Bernard, Chiriac, Rodica, Toche, François, Khrouz, Lhoussain, Molton, Florian, Duboc, Carole, Kieffer, Isabelle, Hazemann, Jean-Louis, Reber, Christian, Hauser, Andreas, Luneau, Dominique
Format:	Journal Article
Language:	English
Published:	United States 21.12.2016
ISSN:	1520-5126, 1520-5126
Online Access:	Get more information
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