Biopolymer Nanocomposites Processing, Properties, and Applications
Sets forth the techniques needed to create a vast array of useful biopolymer nanocomposites Interest in biopolymer nanocomposites is soaring. Not only are they green and sustainable materials, they can also be used to develop a broad range of useful products with special properties, from therapeutic...
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| Médium: | E-kniha |
| Jazyk: | angličtina |
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Newark
Wiley
2013
John Wiley & Sons, Incorporated Wiley-Blackwell |
| Vydání: | 1 |
| Edice: | Polymer engineering and technology series |
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| ISBN: | 1118609905, 9781118609903, 9781118218358, 1118218353 |
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| Abstract | Sets forth the techniques needed to create a vast array of useful biopolymer nanocomposites
Interest in biopolymer nanocomposites is soaring. Not only are they green and sustainable materials, they can also be used to develop a broad range of useful products with special properties, from therapeutics to coatings to packaging materials. With contributions from an international team of leading nanoscientists and materials researchers, this book draws together and reviews the most recent developments and techniques in biopolymer nano-composites. It describes the preparation, processing, properties, and applications of bio- polymer nanocomposites developed from chitin, starch, and cellulose, three renewable resources.
Biopolymer Nanocomposites features a logical organization and approach that make it easy for readers to take full advantage of the latest science and technology in designing these materials and developing new products and applications. It begins with a chapter reviewing our current understanding of bionanocomposites. Next, the book covers such topics as:
* Morphological and thermal investigations of chitin-based nanocomposites
* Applications of starch nanoparticle and starch-based bionanocomposites
* Spectroscopic characterization of renewable nanoparticles and their composites
* Nanocellulosic products and their applications
* Protein-based nanocomposites for food packaging
Throughout the book, detailed case studies of industrial applications underscore the unique challenges and opportunities in developing and working with biopolymer nanocomposites. There are also plenty of figures to help readers fully grasp key concepts and techniques.
Exploring the full range of applications, Biopolymer Nanocomposites is recommended for researchers in a broad range of industries and disciplines, including biomedical engineering, materials science, physical chemistry, chemical engineering, and polymer science. All readers will learn how to create green, sustainable products and applications using these tremendously versatile materials. |
|---|---|
| AbstractList | Sets forth the techniques needed to create a vast array of useful biopolymer nanocomposites Interest in biopolymer nanocomposites is soaring. Not only are they green and sustainable materials, they can also be used to develop a broad range of useful products with special properties, from therapeutics to coatings to packaging materials. With contributions from an international team of leading nanoscientists and materials researchers, this book draws together and reviews the most recent developments and techniques in biopolymer nano-composites. It describes the preparation, processing, properties, and applications of bio- polymer nanocomposites developed from chitin, starch, and cellulose, three renewable resources. Biopolymer Nanocomposites features a logical organization and approach that make it easy for readers to take full advantage of the latest science and technology in designing these materials and developing new products and applications. It begins with a chapter reviewing our current understanding of bionanocomposites. Next, the book covers such topics as: Morphological and thermal investigations of chitin-based nanocomposites Applications of starch nanoparticle and starch-based bionanocomposites Spectroscopic characterization of renewable nanoparticles and their composites Nanocellulosic products and their applications Protein-based nanocomposites for food packaging Throughout the book, detailed case studies of industrial applications underscore the unique challenges and opportunities in developing and working with biopolymer nanocomposites. There are also plenty of figures to help readers fully grasp key concepts and techniques. Exploring the full range of applications, Biopolymer Nanocomposites is recommended for researchers in a broad range of industries and disciplines, including biomedical engineering, materials science, physical chemistry, chemical engineering, and polymer science. All readers will learn how to create green, sustainable products and applications using these tremendously versatile materials. Sets forth the techniques needed to create a vast array of useful biopolymer nanocomposites Interest in biopolymer nanocomposites is soaring. Not only are they green and sustainable materials, they can also be used to develop a broad range of useful products with special properties, from therapeutics to coatings to packaging materials. With contributions from an international team of leading nanoscientists and materials researchers, this book draws together and reviews the most recent developments and techniques in biopolymer nano-composites. It describes the preparation, processing, properties, and applications of bio- polymer nanocomposites developed from chitin, starch, and cellulose, three renewable resources. Biopolymer Nanocomposites features a logical organization and approach that make it easy for readers to take full advantage of the latest science and technology in designing these materials and developing new products and applications. It begins with a chapter reviewing our current understanding of bionanocomposites. Next, the book covers such topics as: * Morphological and thermal investigations of chitin-based nanocomposites * Applications of starch nanoparticle and starch-based bionanocomposites * Spectroscopic characterization of renewable nanoparticles and their composites * Nanocellulosic products and their applications * Protein-based nanocomposites for food packaging Throughout the book, detailed case studies of industrial applications underscore the unique challenges and opportunities in developing and working with biopolymer nanocomposites. There are also plenty of figures to help readers fully grasp key concepts and techniques. Exploring the full range of applications, Biopolymer Nanocomposites is recommended for researchers in a broad range of industries and disciplines, including biomedical engineering, materials science, physical chemistry, chemical engineering, and polymer science. All readers will learn how to create green, sustainable products and applications using these tremendously versatile materials. |
| Author | Alain Dufresne, Sabu Thomas, Laly A. Pothan, Richard F Grossman, Domasius Nwabunma |
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| Snippet | Sets forth the techniques needed to create a vast array of useful biopolymer nanocomposites
Interest in biopolymer nanocomposites is soaring. Not only are they... Sets forth the techniques needed to create a vast array of useful biopolymer nanocomposites Interest in biopolymer nanocomposites is soaring. Not only are they... |
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| SubjectTerms | Biopolymers Nanocomposites (Materials) |
| Subtitle | Processing, Properties, and Applications |
| TableOfContents | 10.5.2 Melt Intercalation Technique -- 10.5.3 In Situ Intercalative Polymerization -- 10.6 Conclusion -- References -- CHAPTER 11: Morphological and Thermal Investigations of Starch-Based Nanocomposites -- 11.1 Introduction -- 11.2 Morphologies of Starch-Based Nanocomposites -- 11.2.1 Factors Affecting Nanofiller Distribution -- 11.2.2 Fracture Morphologies -- 11.2.3 Crystalline Structure of the Starch Matrix -- 11.3 Thermal Behavior of Starch-Based Nanocomposites -- 11.3.1 Glass Transition of Plasticized Starch-Based Nanocomposites -- 11.3.2 Thermal Decomposition Behavior of Starch-Based Nanocomposites -- 11.4 Conclusions and Prospects -- References -- CHAPTER 12: Mechanical Properties of Starch-Based Nanocomposites -- 12.1 Introduction -- 12.2 Starch as Matrix in Nanocomposites -- 12.2.1 Mechanical Properties of Starch-Based Materials -- 12.2.2 Fillers -- 12.2.3 Mechanical Properties of Nanocomposites Based on Starch and Inorganic Reinforcements -- 12.2.4 Mechanical Properties of Nanocomposites Based on Starch and Organic Reinforcements -- 12.3 Starch as Filler in Nanocomposites -- 12.3.1 Reinforcing Effect of Starch Nanocrystals -- 12.3.2 Effect of Starch Nanocrystal Surface Chemical Modification -- 12.3.3 Reinforcing Mechanisms -- 12.4 Conclusion -- References -- CHAPTER 13: Applications of Starch Nanoparticles and Starch-Based Bionanocomposites -- 13.1 Introduction -- 13.2 Applications of Starch Nanoparticle -- 13.2.1 Starch Nanofillers Used in Natural Polymer Matrices -- 13.2.2 Starch Nanofillers Used in Synthetic Polymer Matrix -- 13.3 Applications of Starch-Based Composites -- 13.3.1 In Food Industry -- 13.3.2 Biomedical Applications -- 13.3.3 Agricultural Applications -- 13.4 Conclusion -- References -- CHAPTER 14: Preparation of Nanofibrillated Cellulose and Cellulose Whiskers -- 14.1 Introduction -- 14.1.1 Cellulose -- 14.1.2 Nanocellulose Cover -- Title page -- Copyright page -- Contents -- Foreword -- Contributors -- CHAPTER 1: Bionanocomposites: State of the Art, Challenges, and Opportunities -- 1.1 Introduction -- 1.2 Nanocrystalline Cellulose -- References -- CHAPTER 2: Preparation of Chitin Nanofibers and Their Composites -- 2.1 Introduction -- 2.2 Isolation of Chitin Nanofibers from Different Sources -- 2.2.1 Processing of Chitin Nanofibers from Crab Shells -- 2.2.2 Chitin Nanofibers from Prawn Shells -- 2.2.3 Facile Preparation of Chitin Nanofibers from Dry Chitin -- 2.3 Characterization of Chitin Nanofibers Obtained from Crab, Prawn, and Dry Chitin Powder -- 2.4 Preparation of Chitin Nanofibers from Edible Mushrooms -- 2.5 Preparation of Chitin Nanofiber Nanocomposites -- 2.6 Acetylation of Chitin Nanofibers -- 2.6.1 Study of Degree of Substitution -- 2.6.2 SEM Images of Substituted Chitin Nanofibers -- 2.6.3 Acetylated Chitin Nanofiber Composites -- 2.7 Conclusion -- References -- CHAPTER 3: Chemical Modification of Chitosan and Its Biomedical Application -- 3.1 Introduction -- 3.2 Structure of Chitosan -- 3.3 Chemical Modifications of Chitosan -- 3.3.1 Chitosan-Grafted Copolymers -- 3.3.2 Cyclodextrin-Linked Chitosan -- 3.3.3 Crown Ether Bound Chitosan -- 3.3.4 Thiol-Containing Chitosan -- 3.3.5 Carbohydrate Branched Chitosans -- 3.3.6 Carboxymethylated Chitosans -- 3.3.7 Alkylated Chitosans -- 3.3.8 Quaternized Chitosan Derivatives -- 3.3.9 Chitosan Hydrogels -- 3.4 Biomedical Applications of Chitosan Derivatives -- 3.4.1 Tissue Engineering -- 3.4.2 Wound Healing -- 3.4.3 Drug Delivery -- 3.5 Conclusion -- References -- CHAPTER 4: Biomimetic Lessons for Processing Chitin-Based Composites -- 4.1 Introduction -- 4.2 Physicochemical Properties of Chitin -- 4.2.1 Chitin Hierarchical Structure -- 4.2.2 Chitin Crystallinity -- 4.2.3 Liquid Crystal Behavior of Chitin 4.2.4 Chitin and Proteins -- 4.3 Biomimetic Lessons from Natural Chitin Nanocomposites -- 4.3.1 Chitin Synthesis in Mollusk and Crustacean Hard Tissue -- 4.3.2 Jumbo Squid Beak -- 4.4 Bioinspired Lessons for Processing Chitin Nanocomposites -- 4.4.1 Chitin Nanocomposite Processing -- 4.4.2 Chitin Nanocomposites in Biomedical Engineering -- 4.4.3 Inorganic Chitin-Based Nanocomposites -- 4.5 Conclusions -- Acknowledgments -- References -- CHAPTER 5: Morphological and Thermal Investigations of Chitin-Based Nanocomposites -- 5.1 Morphological Investigations of Chitin-Based Nanocomposites -- 5.1.1 Optical Microscopy -- 5.1.2 Scanning Electron Microscopy and Transmittance Electron Microscopy -- 5.1.3 Atomic Force Microscopy -- 5.2 Thermal Investigations of Chitin-Based Nanocomposites -- 5.2.1 Differential Scanning Calorimetry -- 5.2.2 Dynamic Thermal Mechanical Analysis -- 5.2.3 Thermogravimetric Analysis -- 5.2.4 Thermomechanical Analysis -- References -- CHAPTER 6: Mechanical Properties of Chitin-Based Nanocomposites -- 6.1 Introduction -- 6.2 Mechanical Properties of Chitin/Chitosan Nanocomposites -- 6.2.1 Chitosan-Hydroxyapatite Nanocomposites -- 6.2.2 Chitosan-Clay Nanocomposites -- 6.2.3 Chitosan-Carbon Nanotube Nanocomposites -- 6.2.4 Chitosan-Graphene Oxide Nanocomposites -- 6.2.5 Chitin/Chitosan as Nanofiller in PolymerNanocomposites -- 6.3 Conclusion -- References -- CHAPTER 7: Preparation and Applications of Chitin Nanofibers/Nanowhiskers -- 7.1 Introduction -- 7.2 Chitin Nanowhiskers by Acid Hydrolysis -- 7.3 Chitin Nanofibers/Nanocrystals by TEMPO-Mediated Oxidation -- 7.4 Chitin Nanofibers/Nanowhiskers by Regeneration from Chitin Solutions -- 7.5 Chitin Nanofibers by Electrospinning -- 7.6 Other Methods for Chitin Nanofibers -- References -- CHAPTER 8: Preparation of Starch Nanoparticles -- 8.1 Introduction -- 8.2 Starch -- 8.2.1 Content 17.1.4 Microcrystalline Cellulose 14.2 Preparation of Nanofibrillated Cellulose -- 14.2.1 Mechanical Treatments -- 14.2.2 Pretreatments -- 14.3 Characterization of Nanofibrillated Cellulose -- 14.3.1 Morphology and Dimensions -- 14.3.2 Physical Properties of Nanofibrillated Cellulose -- 14.4 Preparation of Cellulose Whiskers -- 14.4.1 Acid Hydrolysis -- 14.5 Characterization of Cellulose Whiskers -- 14.5.1 Morphology -- 14.5.2 Physical Properties of Cellulose Whiskers -- 14.6 Commercial Development of Nanocelluloses -- 14.6.1 Nanofibrillated Cellulose -- 14.6.2 Cellulose Whiskers -- 14.7 Summary -- 14.8 Further Reading -- References -- CHAPTER 15: Bacterial Cellulose -- 15.1 Introduction -- 15.2 Producing Microorganisms -- 15.2.1 Isolation of Producing Microorganisms and Cellulose Identification -- 15.2.2 Production of Bacterial Cellulose -- 15.3 Static and Agitated Cultures -- 15.3.1 Shaking Cultivation -- 15.3.2 Static Process -- 15.4 Carbon and Nitrogen Sources -- 15.5 Production of Bacterial Cellulose from Food and Agro-Forestry Residues -- 15.6 Purification -- 15.7 Structure of Bacterial Cellulose -- 15.8 Properties of Bacterial Cellulose -- 15.9 Applications -- 15.9.1 Food Industry -- 15.9.2 Bacterial Cellulose Composites -- 15.10 Conclusions -- References -- CHAPTER 16: Chemical Modification of Nanocelluloses -- 16.1 Introduction -- 16.2 Nanocellulose Substrates -- 16.3 Chemical Modifications -- 16.3.1 Noncovalent Surface Chemical Modifications -- 16.3.2 TEMPO-Mediated Oxidation -- 16.3.3 Cationization -- 16.3.4 Esterification -- 16.3.5 Silylation -- 16.3.6 Urethanization -- 16.3.7 Amidation -- 16.3.8 Clicking -- 16.3.9 Polymer Grafting -- 16.4 Conclusions -- References -- CHAPTER 17: Cellulose-Based Nanocomposites: Processing Techniques -- 17.1 Introduction -- 17.1.1 Cellulose Structure and Properties -- 17.1.2 Cellulose Solubility -- 17.1.3 Electrospun Cellulose Fibers 8.2.2 Structure -- 8.2.3 Crystalline Type -- 8.3 Starch Nanoparticles -- 8.3.1 Preparation -- 8.3.2 Patented Starch Nanoparticles -- 8.4 Starch Nanocrystals -- 8.4.1 General Description -- 8.4.2 Acid Hydrolysis Kinetics -- 8.4.3 Preparation Protocol -- 8.4.4 Starch Nanocrystal Characterization -- 8.4.5 Starch Nanocrystals from Different Starch Sources -- 8.5 Comparison of rSNP and SNC -- 8.6 Conclusions and Prospects -- References -- CHAPTER 9: Chemical Modification of Starch Nanoparticles -- 9.1 Introduction -- 9.2 Chemical Modification of Starch Nanocrystals Pertaining to Hydrolysis and Regeneration-Co-crystallization -- 9.2.1 Conjugation of Small Molecules onto the Surface of Starch Nanocrystals -- 9.2.2 Polymer Grafting onto the Surface of Starch Nanocrystals -- 9.3 Chemical Modification of Starch Nanoparticles, Nanomicelles, and Nanocolloids -- 9.3.1 Nanoparticle Formation from Chemically Modified Starch -- 9.3.2 Nanomicelle Assembly from Chemically Modified Starch -- 9.3.3 Chemical Modification of Cross-Linked Starch Nanoparticles -- 9.3.4 Chemical Modification of Starch Nanocolloids -- 9.4 Role of Chemical Modification in the Application of Starch Nanoparticles -- 9.4.1 Compatibilization at the Filler-Matrix Interface in Nanocomposites -- 9.4.2 Function Development Based on Chemical Modification of Starch Nanoparticles -- 9.5 Conclusions and Prospects -- References -- CHAPTER 10: Starch-Based Bionanocomposite: Processing Techniques -- 10.1 Introduction -- 10.2 Microstructures of Starch -- 10.3 Starch-Based Bionanocomposite -- 10.3.1 Starch Silicate Nanocomposites -- 10.3.2 Starch Cellulose Nanocomposites -- 10.3.3 Starch Synthetic Polymer-Based Nanocomposite -- 10.4 Conventional Nanocomposites Manufacturing Techniques -- 10.5 Processing Techniques of Starch-Based Bionanocomposites -- 10.5.1 Solution Casting Method |
| Title | Biopolymer Nanocomposites |
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