Direct Comparison of C-H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl

Reduction of previously reported iminyl radical (L-Ar)FeC1(center dot N(C6H4-p-Bu-t)) (2) with potassium graphite furnished the corresponding high-spin (S = 5/2) imido (L-Ar) F e (N(C6H4-p-Bu-t)) (3) (L-Ar = 5-m esityl-1,9-(2,4,6-Ph3C6H2)dipyrrin). Oxidation of the three-coordinate imido (L-Ar)Fe(NA...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 139; no. 41; pp. 14757 - 14766
Main Authors:	Wilding, Matthew J. T., Iovan, Diana A., Wrobel, Alexandra T., Lukens, James T., MacMillan, Samantha N., Lancaster, Kyle M., Betley, Theodore A.
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 18.10.2017
Subjects:	Amination Carbon - chemistry Chemistry Chemistry, Multidisciplinary Hydrogen - chemistry Kinetics Nitrogen - chemistry Oxidation-Reduction Physical Sciences Science & Technology Thermodynamics Toluene - chemistry X-Ray Absorption Spectroscopy GROUP TRANSFER CHEMISTRY ELECTRON-TRANSFER NON-INNOCENT HYDROGEN-ATOM TRANSFER DENSITY-FUNCTIONAL CALCULATIONS COMPLEXES SPECIES RELEVANT IRON IMIDES TRIPLE ZETA VALENCE GAUSSIAN-BASIS SETS
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
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