X-ray spectroscopic observation of an interstitial carbide in NifEN-bound FeMoco precursor

The iron-molybdenum cofactor (FeMoco) of nitrogenase contains a biologically unprecedented μ(6)-coordinated C(4-) ion. Although the role of this interstitial atom in nitrogenase catalysis is unknown, progress in understanding its biosynthetic origins has been made. Here we report valence-to-core Fe...

Celý popis

Podrobná bibliografia

Vydané v:	Journal of the American Chemical Society Ročník 135; číslo 2; s. 610
Hlavní autori:	Lancaster, Kyle M, Hu, Yilin, Bergmann, Uwe, Ribbe, Markus W, DeBeer, Serena
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 16.01.2013
Predmet:	Iron Compounds - chemistry Iron Compounds - metabolism Molecular Structure Molybdoferredoxin - chemistry Molybdoferredoxin - metabolism Spectrometry, X-Ray Emission Tricarboxylic Acids - chemistry
ISSN:	1520-5126, 1520-5126
On-line prístup:	Zistit podrobnosti o prístupe
Tagy:	Pridať tag Žiadne tagy, Buďte prvý, kto otaguje tento záznam!