Contra-Thermodynamic Positional Isomerization of Olefins

A light-driven method for the contra-thermodynamic positional isomerization of olefins is described. In this work, stepwise PCET activation of a more substituted and more thermodynamically stable olefin substrate is mediated by an excited-state oxidant and a Bronsted base to afford an allylic radica...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 144; no. 1; pp. 137 - 144
Main Authors:	Zhao, Kuo, Knowles, Robert R.
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 12.01.2022
Subjects:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology FUNCTIONALIZATION ALKENE ISOMERIZATION DECONJUGATION MECHANISM CIS-TRANS ISOMERIZATION RADICAL IONS ELECTRON-TRANSFER TAUTOMERIZATION DERACEMIZATION PHOTOCHEMISTRY MOLECULES
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
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