Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites

This work reports on the capability of the O2-activated Cu-ZSM-5 and Cu-MOR zeolites to selectively convert methane into methanol at a temperature of 398 K. A strong correlation between (i) the activity and (ii) the intensity of the 22 700 cm-1 UV-vis band, assigned to the bis(mu-oxo)dicopper core,...

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Veröffentlicht in:	Journal of the American Chemical Society Jg. 127; H. 5; S. 1394
Hauptverfasser:	Groothaert, Marijke H, Smeets, Pieter J, Sels, Bert F, Jacobs, Pierre A, Schoonheydt, Robert A
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	United States 09.02.2005
Schlagworte:	Aluminum Silicates - chemistry Biomimetic Materials - chemistry Copper - chemistry Kinetics Methane - chemistry Monophenol Monooxygenase - chemistry Organometallic Compounds Oxidation-Reduction Oxygen - chemistry Oxygenases - chemistry Oxyquinoline - analogs & derivatives Zeolites - chemistry
ISSN:	0002-7863
Online-Zugang:	Weitere Angaben
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