Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization

Herein we discuss band gap modification of MIL-125, a TiO2/1,4-benzenedicarboxylate (bdc) metal–organic framework (MOF). Through a combination of synthesis and computation, we elucidated the electronic structure of MIL-125 with aminated linkers. The band gap decrease observed when the monoaminated b...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 135; no. 30; pp. 10942 - 10945
Main Authors:	Hendon, Christopher H, Tiana, Davide, Fontecave, Marc, Sanchez, Clément, D’arras, Loïc, Sassoye, Capucine, Rozes, Laurence, Mellot-Draznieks, Caroline, Walsh, Aron
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 31.07.2013
Subjects:	Engineering Ligands Models, Molecular Molecular Conformation Optical Phenomena Organometallic Compounds - chemistry Phthalic Acids - chemistry Titanium - chemistry
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get full text
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