A Nonheme Thiolate-Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity

The synthesis and characterization of a Co(II) dithiolato complex Co(Me TACN)(S SiMe ) (1) are reported. Reaction of 1 with O generates a rare thiolate-ligated cobalt-superoxo species Co(O )(Me TACN)(S SiMe ) (2) that was characterized spectroscopically and structurally by resonance Raman, EPR, and...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 141; no. 8; p. 3641
Main Authors:	Gordon, Jesse B, Vilbert, Avery C, Siegler, Maxime A, Lancaster, Kyle M, Moënne-Loccoz, Pierre, Goldberg, David P
Format:	Journal Article
Language:	English
Published:	United States 27.02.2019
ISSN:	1520-5126, 1520-5126
Online Access:	Get more information
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