Rare-Earth Doping in Nanostructured Inorganic Materials

Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter th...

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Veröffentlicht in:Chemical reviews Jg. 122; H. 6; S. 5519
Hauptverfasser: Zheng, Bingzhu, Fan, Jingyue, Chen, Bing, Qin, Xian, Wang, Juan, Wang, Feng, Deng, Renren, Liu, Xiaogang
Format: Journal Article
Sprache:Englisch
Veröffentlicht: United States 23.03.2022
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ISSN:1520-6890, 1520-6890
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Abstract Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications.
AbstractList Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications.
Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications.Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications.
Author Fan, Jingyue
Liu, Xiaogang
Chen, Bing
Deng, Renren
Zheng, Bingzhu
Qin, Xian
Wang, Juan
Wang, Feng
Author_xml – sequence: 1
  givenname: Bingzhu
  surname: Zheng
  fullname: Zheng, Bingzhu
  organization: State Key Laboratory of Silicon Materials, Institute for Composites Science Innovation, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
– sequence: 2
  givenname: Jingyue
  orcidid: 0000-0003-4987-7025
  surname: Fan
  fullname: Fan, Jingyue
  organization: Department of Chemistry, National University of Singapore, Singapore 117543, Singapore
– sequence: 3
  givenname: Bing
  orcidid: 0000-0002-0663-1343
  surname: Chen
  fullname: Chen, Bing
  organization: Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR 999077, China
– sequence: 4
  givenname: Xian
  surname: Qin
  fullname: Qin, Xian
  organization: Department of Chemistry, National University of Singapore, Singapore 117543, Singapore
– sequence: 5
  givenname: Juan
  orcidid: 0000-0002-1340-9011
  surname: Wang
  fullname: Wang, Juan
  organization: Institute of Environmental Health, MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental & Resource Sciences, Zhejiang University, Hangzhou 310058, China
– sequence: 6
  givenname: Feng
  orcidid: 0000-0001-9471-4386
  surname: Wang
  fullname: Wang, Feng
  organization: Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR 999077, China
– sequence: 7
  givenname: Renren
  orcidid: 0000-0001-8213-6304
  surname: Deng
  fullname: Deng, Renren
  organization: State Key Laboratory of Silicon Materials, Institute for Composites Science Innovation, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
– sequence: 8
  givenname: Xiaogang
  orcidid: 0000-0003-2517-5790
  surname: Liu
  fullname: Liu, Xiaogang
  organization: Department of Chemistry, National University of Singapore, Singapore 117543, Singapore
BackLink https://www.ncbi.nlm.nih.gov/pubmed/34989556$$D View this record in MEDLINE/PubMed
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Volume 122
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