Magnetic Ordering-Induced Multiferroic Behavior in [CH3NH3][Co(HCOO)3] Metal-Organic Framework
We present the first example of magnetic ordering-induced multiferroic behavior in a metal-organic framework magnet. This compound is [CH3NH3][Co(HCOO)3] with a perovskite-like structure. The A-site [CH3NH3](+) cation strongly distorts the framework, allowing anisotropic magnetic and electric behavi...
Uložené v:
| Vydané v: | Journal of the American Chemical Society Ročník 138; číslo 4; s. 1122 |
|---|---|
| Hlavní autori: | , , , , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
United States
03.02.2016
|
| ISSN: | 1520-5126 |
| On-line prístup: | Zistit podrobnosti o prístupe |
| Tagy: |
Pridať tag
Žiadne tagy, Buďte prvý, kto otaguje tento záznam!
|
| Abstract | We present the first example of magnetic ordering-induced multiferroic behavior in a metal-organic framework magnet. This compound is [CH3NH3][Co(HCOO)3] with a perovskite-like structure. The A-site [CH3NH3](+) cation strongly distorts the framework, allowing anisotropic magnetic and electric behavior and coupling between them to occur. This material is a spin canted antiferromagnet below 15.9 K with a weak ferromagnetic component attributable to Dzyaloshinskii-Moriya (DM) interactions and experiences a discontinuous hysteretic magnetic-field-induced switching along [010] and a more continuous hysteresis along [101]. Coupling between the magnetic and electric order is resolved when the field is applied along this [101]: a spin rearrangement occurs at a critical magnetic field in the ac plane that induces a change in the electric polarization along [101] and [10-1]. The electric polarization exhibits an unusual memory effect, as it remembers the direction of the previous two magnetic-field pulses applied. The data are consistent with an inverse-DM mechanism for multiferroic behavior. |
|---|---|
| AbstractList | We present the first example of magnetic ordering-induced multiferroic behavior in a metal-organic framework magnet. This compound is [CH3NH3][Co(HCOO)3] with a perovskite-like structure. The A-site [CH3NH3](+) cation strongly distorts the framework, allowing anisotropic magnetic and electric behavior and coupling between them to occur. This material is a spin canted antiferromagnet below 15.9 K with a weak ferromagnetic component attributable to Dzyaloshinskii-Moriya (DM) interactions and experiences a discontinuous hysteretic magnetic-field-induced switching along [010] and a more continuous hysteresis along [101]. Coupling between the magnetic and electric order is resolved when the field is applied along this [101]: a spin rearrangement occurs at a critical magnetic field in the ac plane that induces a change in the electric polarization along [101] and [10-1]. The electric polarization exhibits an unusual memory effect, as it remembers the direction of the previous two magnetic-field pulses applied. The data are consistent with an inverse-DM mechanism for multiferroic behavior. |
| Author | Pato-Doldán, Breogán Mira, J Castro-García, Socorro Sánchez-Andújar, Manuel Zapf, Vivien S Singleton, John Gómez-Aguirre, L Claudia Señarís-Rodríguez, María Antonia |
| Author_xml | – sequence: 1 givenname: L Claudia surname: Gómez-Aguirre fullname: Gómez-Aguirre, L Claudia organization: Department of Fundamental Chemistry, Faculty of Sciences, University of A Coruña , 15071 A Coruña, Spain – sequence: 2 givenname: Breogán surname: Pato-Doldán fullname: Pato-Doldán, Breogán organization: Department of Fundamental Chemistry, Faculty of Sciences, University of A Coruña , 15071 A Coruña, Spain – sequence: 3 givenname: J surname: Mira fullname: Mira, J organization: Department of Applied Physics, University of Santiago de Compostela , 15782 Santiago de Compostela, Spain – sequence: 4 givenname: Socorro surname: Castro-García fullname: Castro-García, Socorro organization: Department of Fundamental Chemistry, Faculty of Sciences, University of A Coruña , 15071 A Coruña, Spain – sequence: 5 givenname: María Antonia surname: Señarís-Rodríguez fullname: Señarís-Rodríguez, María Antonia organization: Department of Fundamental Chemistry, Faculty of Sciences, University of A Coruña , 15071 A Coruña, Spain – sequence: 6 givenname: Manuel surname: Sánchez-Andújar fullname: Sánchez-Andújar, Manuel organization: Department of Fundamental Chemistry, Faculty of Sciences, University of A Coruña , 15071 A Coruña, Spain – sequence: 7 givenname: John surname: Singleton fullname: Singleton, John organization: National High Magnetic Field Laboratory, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States – sequence: 8 givenname: Vivien S surname: Zapf fullname: Zapf, Vivien S organization: National High Magnetic Field Laboratory, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26717023$$D View this record in MEDLINE/PubMed |
| BookMark | eNo1jztPwzAYRS0Eog_YmFFGGFL8-RVnhIiSSg1ZYKpK5Th2SEmdyklA_HsiAdMZ7tGVzgydutYZhK4ALwATuNsr3S14ASCkPEFT4ASHHIiYoFnX7THGjEg4RxMiIogwoVP0lqnKmb7WQe5L42tXhStXDtqUQTY0fW2N9-24Pph39Vm3PqhdsElS-pzS7SZpb9Ikz2_pNshMr5ow95Vyo7306mC-Wv9xgc6sajpz-cc5el0-viRpuM6fVsn9OlRM8D60VpQc8yiGglERU8koZ5KVBjRIQbEoCqZsBAIIV1ICsTSOhbBajz6NCzJH17-_x6E4mHJ39PVB-e_dfyj5AWj_UuI |
| CitedBy_id | crossref_primary_10_1016_j_mtchem_2018_12_004 crossref_primary_10_1002_adfm_201901878 crossref_primary_10_1002_adma_202004542 crossref_primary_10_1016_j_ccr_2021_214337 crossref_primary_10_1038_s41467_021_23917_z crossref_primary_10_1021_jacs_6b05208 crossref_primary_10_1088_2058_6272_abeed9 crossref_primary_10_1021_jacs_7b03633 crossref_primary_10_1002_smll_202409564 crossref_primary_10_1002_chem_201703140 crossref_primary_10_1063_1_5086978 crossref_primary_10_1039_C9QI01197H crossref_primary_10_1038_s41535_019_0180_1 crossref_primary_10_1515_znb_2016_0267 crossref_primary_10_1088_1361_648X_aadc80 crossref_primary_10_1002_admi_202300123 crossref_primary_10_1063_9_0000147 crossref_primary_10_1016_j_ccr_2021_214180 crossref_primary_10_1038_s41598_017_14388_8 crossref_primary_10_1007_s40242_022_1457_7 crossref_primary_10_1016_j_rinp_2025_108162 crossref_primary_10_3390_molecules25204754 crossref_primary_10_1021_jacs_0c06048 crossref_primary_10_1038_s41467_023_43815_w crossref_primary_10_1039_D0RA03397A crossref_primary_10_1021_jacs_9b09358 crossref_primary_10_1002_chem_201901655 crossref_primary_10_1063_1_5040688 crossref_primary_10_1107_S2052252518015026 crossref_primary_10_1002_chem_202300598 crossref_primary_10_1088_1361_6463_ab6bed crossref_primary_10_1039_D5CC03844H crossref_primary_10_1021_acsapm_5c00600 crossref_primary_10_1002_jrs_5154 crossref_primary_10_1016_j_nanoen_2023_108733 crossref_primary_10_1016_j_orgel_2018_01_027 crossref_primary_10_1002_chem_201900771 crossref_primary_10_1103_cj9g_qk9l crossref_primary_10_1039_C6CP06648H crossref_primary_10_1088_2053_1591_ac95ff crossref_primary_10_1515_znb_2016_0087 crossref_primary_10_1016_j_jallcom_2021_163288 crossref_primary_10_1016_j_jssc_2020_121423 crossref_primary_10_1002_anie_202007813 crossref_primary_10_1021_jacs_7b04911 crossref_primary_10_1039_C9RA09224B crossref_primary_10_1021_jacs_4c07759 crossref_primary_10_1021_acs_jpclett_5c00330 crossref_primary_10_1039_C8CP03761B crossref_primary_10_1002_advs_202202979 crossref_primary_10_1038_s41467_024_49053_y crossref_primary_10_3390_cryst10121129 crossref_primary_10_1038_s41427_023_00485_w crossref_primary_10_1002_jrs_5285 crossref_primary_10_1038_s41467_019_11967_3 crossref_primary_10_1063_5_0052975 crossref_primary_10_1016_j_jmmm_2019_165715 crossref_primary_10_1063_1_5137819 crossref_primary_10_1002_cssc_201801585 crossref_primary_10_1002_chem_201503445 crossref_primary_10_1063_1_4983169 crossref_primary_10_1103_PhysRevApplied_9_044011 crossref_primary_10_1021_acs_inorgchem_5c00147 crossref_primary_10_1038_s41557_018_0107_7 crossref_primary_10_1063_1_4989783 crossref_primary_10_1107_S2052252524008583 crossref_primary_10_1002_ange_202007813 crossref_primary_10_1002_chem_201600689 crossref_primary_10_1016_j_cej_2022_140865 crossref_primary_10_1002_cphc_202400297 crossref_primary_10_1088_2515_7655_ab5eee crossref_primary_10_1021_jacs_6b02485 crossref_primary_10_1002_smll_202505333 crossref_primary_10_1016_j_inoche_2016_11_026 crossref_primary_10_1016_j_ica_2020_119600 crossref_primary_10_1063_1_4993508 crossref_primary_10_1016_j_jssc_2019_04_040 crossref_primary_10_1002_anie_201703898 crossref_primary_10_1038_ncomms15715 crossref_primary_10_1002_chem_201701099 crossref_primary_10_1021_jacs_0c05845 crossref_primary_10_1021_jacs_1c00601 crossref_primary_10_3390_solids2020011 crossref_primary_10_1209_0295_5075_aca42d crossref_primary_10_1016_j_molstruc_2021_132143 crossref_primary_10_1039_D1SC01871J crossref_primary_10_1016_j_jallcom_2017_10_183 crossref_primary_10_1002_ange_201703898 crossref_primary_10_1002_adma_201702512 crossref_primary_10_1016_j_jssc_2017_09_001 crossref_primary_10_1016_j_vibspec_2016_06_003 crossref_primary_10_1016_j_jssc_2022_122907 crossref_primary_10_1088_1361_648X_ad9b61 crossref_primary_10_1063_1_5007317 crossref_primary_10_1088_1361_648X_ab03ef crossref_primary_10_1002_adma_201604604 crossref_primary_10_1016_j_jallcom_2019_153464 crossref_primary_10_1038_natrevmats_2016_99 crossref_primary_10_1021_jacs_8b04818 |
| ContentType | Journal Article |
| DBID | NPM |
| DOI | 10.1021/jacs.5b11688 |
| DatabaseName | PubMed |
| DatabaseTitle | PubMed |
| DatabaseTitleList | PubMed |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | no_fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5126 |
| ExternalDocumentID | 26717023 |
| Genre | Research Support, U.S. Gov't, Non-P.H.S Research Support, Non-U.S. Gov't Journal Article |
| GroupedDBID | --- -DZ -ET -~X .DC .K2 4.4 53G 55A 5GY 5RE 5VS 7~N 85S AABXI AAHBH ABJNI ABMVS ABPPZ ABQRX ABUCX ACBEA ACGFO ACGFS ACJ ACNCT ACS ADHLV AEESW AENEX AFEFF AGXLV AHGAQ ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH BKOMP CS3 CUPRZ DU5 EBS ED~ EJD F5P GGK GNL IH2 IH9 JG~ LG6 NPM P2P ROL RXW TAE TN5 UHB UI2 UKR UPT VF5 VG9 VQA W1F WH7 XSW YIN YQT YZZ ZCA ~02 |
| ID | FETCH-LOGICAL-a465t-ff6d505791b436938435484de1c186306bb4af716125a8812f39966fccb4339b2 |
| ISICitedReferencesCount | 188 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000369558000007&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| IngestDate | Wed Feb 19 02:00:24 EST 2025 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 4 |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-a465t-ff6d505791b436938435484de1c186306bb4af716125a8812f39966fccb4339b2 |
| OpenAccessLink | https://www.osti.gov/biblio/1296677 |
| PMID | 26717023 |
| ParticipantIDs | pubmed_primary_26717023 |
| PublicationCentury | 2000 |
| PublicationDate | 2016-02-03 |
| PublicationDateYYYYMMDD | 2016-02-03 |
| PublicationDate_xml | – month: 02 year: 2016 text: 2016-02-03 day: 03 |
| PublicationDecade | 2010 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | Journal of the American Chemical Society |
| PublicationTitleAlternate | J Am Chem Soc |
| PublicationYear | 2016 |
| SSID | ssj0004281 |
| Score | 2.5848272 |
| Snippet | We present the first example of magnetic ordering-induced multiferroic behavior in a metal-organic framework magnet. This compound is [CH3NH3][Co(HCOO)3] with... |
| SourceID | pubmed |
| SourceType | Index Database |
| StartPage | 1122 |
| Title | Magnetic Ordering-Induced Multiferroic Behavior in [CH3NH3][Co(HCOO)3] Metal-Organic Framework |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/26717023 |
| Volume | 138 |
| WOSCitedRecordID | wos000369558000007&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1bb9MwFLa6gQQvaNxvQ3mgEqgyxLHjOI9bCvRha_cwpEnTmOzYqSKxpEq7adof5e9wHCchrRiCB16i1E4jJ-eLz3fsc0HordDGV4IzLEOVYaaAwykeahxpnWmfKT90KfMPoulUnJzER4PBjzYW5up7VBTi-jpe_FdRQxsI24bO_oO4u5tCA5yD0OEIYofjXwn-UM4LG5k4mtmsmqCZsC3PYbf562DbzFRVCb1NYkTrjT4ahvvJhE4ndBiO7XkJtHOSzGZD0NLQNDo0QNGxC9tMLdd1_ly3ENtesEox6hISNO6hnb-P3aHfpxfmBu_NL_PKLYUf2CKdlzrvdMWRXJV4bCtb2w194mrLV6acN787vOSVXNvkSuRyVZX4Cwi3vnRcd8MgSnj8_lIHcd7RbvozzfQMxi5QFL42f1PRAyrrzcbAJYPfqgkgNnV5gnT5IVSEcFdZsAeOxUWNjoCDteu7gOg_924k7W67ttBWxK2-mNpFpDZcNxCkicGAgXzsD8Pmpm7-umHn1HzneAc9aOTp7TmAPUQDUzxC95K2PuBj9K0FmrcJNK8PNK8FmpcX3qmD2dlpUr6zAHtPz7w1cHkduJ6gr58_HScT3FTrwJLxcIWzjGtr7cZEMcpjKoCIM8G0ISkRHCxTpZjMwDwHSi0F8MqMWls7S1O4nsYqeIq2i7Iwz5EXxaFSBLiw4JxpJYBTCy0jGknK_dQPXqBn7tWcL1xKlvP2pb28tecVuv8LUq_RnQw-d7OL7qZXq3xZvakl9BPHP3GD |
| linkProvider | National Library of Medicine |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Magnetic+Ordering-Induced+Multiferroic+Behavior+in+%5BCH3NH3%5D%5BCo%28HCOO%293%5D+Metal-Organic+Framework&rft.jtitle=Journal+of+the+American+Chemical+Society&rft.au=G%C3%B3mez-Aguirre%2C+L+Claudia&rft.au=Pato-Dold%C3%A1n%2C+Breog%C3%A1n&rft.au=Mira%2C+J&rft.au=Castro-Garc%C3%ADa%2C+Socorro&rft.date=2016-02-03&rft.eissn=1520-5126&rft.volume=138&rft.issue=4&rft.spage=1122&rft_id=info:doi/10.1021%2Fjacs.5b11688&rft_id=info%3Apmid%2F26717023&rft_id=info%3Apmid%2F26717023&rft.externalDocID=26717023 |