Importance of Axial Symmetry in Elucidating Lanthanide-Transition Metal Interactions

In this paper, we experimentally study and model the electron donating character of an axial diamagnetic Pd ion in four metalloligated lanthanide complexes of formula [PPh ][Ln{Pd(SAc) } ] (SAc = thioacetate, Ln = Tb, Dy, Ho, and Er). A global model encompassing inelastic neutron scattering, torque...

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Bibliographic Details

Published in:	Inorganic chemistry Vol. 59; no. 1; p. 235
Main Authors:	Bonde, Niels A, Petersen, Jonatan B, Sørensen, Mikkel A, Nielsen, Ulla G, Fåk, Björn, Rols, Stéphane, Ollivier, Jacques, Weihe, Høgni, Bendix, Jesper, Perfetti, Mauro
Format:	Journal Article
Language:	English
Published:	United States 06.01.2020
ISSN:	1520-510X, 1520-510X
Online Access:	Get more information
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